Operando monitoring of thermal runaway in commercial lithium-ion cells via advanced lab-on-fiber technologies.

Operando monitoring of complex physical and chemical activities inside rechargeable lithium-ion batteries during thermal runaway is critical to understanding thermal runaway mechanisms and giving early warning of safety-related failure. However, most existing sensors cannot survive during such extremely hazardous thermal runaway processes (temperature up to 500 °C accompanied by fire and explosion). To address this, we develop a compact and multifunctional optical fiber sensor (12 mm in length and 125 µm in diameter) capable of insertion into commercial 18650 cells to continuously monitor internal temperature and pressure effects during cell thermal runaway. We observe a stable and reproducible correlation between the cell thermal runaway and the optical response. The sensor's signal shows two internal pressure peaks corresponding to safety venting and initiation of thermal runaway. Further analysis reveals that a scalable solution for predicting imminent thermal runaway is the detection of the abrupt turning range of the differential curves of cell temperature and pressure, which corresponds to an internal transformation between the cell reversible and irreversible reactions. By raising an alert even before safety venting, this new operando measurement tool can provide crucial capabilities in cell safety assessment and warning of thermal runaway.

Recovery of a highly reflective Bragg grating in DPDS-doped polymer optical fiber by thermal annealing.

We report fiber Bragg grating manufacturing in poly(methyl methacrylate) (PMMA)-based polymer optical fibers (POFs) with a diphenyl disulfide (DPDS)-doped core by means of a 266 nm pulsed laser and the phase mask technique. Gratings were inscribed with different pulse energies ranging from 2.2 mJ to 2.7 mJ. For the latter, the grating reflectivity reached 91% upon 18-pulse illumination. Though the as-fabricated gratings decayed, they were recovered by post-annealing at 80°C for 1 day, after which they showed an even higher reflectivity of up to 98%. This methodology for the fabrication of highly reflective gratings could be applied for the production of high-quality tilted fiber Bragg gratings (TFBGs) in POFs for biochemical applications.

Polymeric fiber sensors for insertion forces and trajectory determination of cochlear implants in hearing preservation.

The level of hearing restoration in patients with severe to profound sensorineural hearing loss by means of cochlear implants (CIs) has drastically risen since the introduction of these neuroprosthetics. The proposed CI integrated with polymer optical fiber Bragg gratings (POFBGs) enables real-time evaluation of insertion forces and trajectory determination during implantation irrespective of the speed of insertion, as well as provides high signal quality, low stiffness levels, minimum induced stress even under forces of high magnitudes and exhibits significant reduction of the risk of fiber breakage inside the constricted cochlear geometry. As such, the proposed device opens new avenues towards atraumatic cochlear implantations and provides a direct route for the next generation of CIs with intraoperative insertion force assessment and path planning capacity crucial for surgical navigation. Hence, adaptation of this technology to clinical reality holds promising prospects for the hearing impaired.

Ultraminiature optical fiber-tip directly-printed plasmonic biosensors for label-free biodetection.

Miniaturization of biosensors has become an imperative demand because of its great potential in in vivo biomarker detection and disease diagnostics as well as the point-of-care testing for coping with public health crisis, such as the coronavirus disease 2019 pandemic. Here, we present an ultraminiature optical fiber-tip biosensor based on the plasmonic gold nanoparticles (AuNPs) directly printed upon the end face of a standard multimode optical fiber at visible light range. An in-situ precision photoreduction technology is developed to additively print the micropatterns of size-controlled AuNPs. The AuNPs reveal distinct localized surface plasmon resonance, whose peak wavelength provides an ideal spectral signal for label-free biodetection. The fabricated optical fiber-tip plasmonic biosensor can not only detect antibody, but also test SARS-CoV-2 mimetic DNA sequence at the concentration level of 0.8 pM. Such an ultraminiature fiber-tip plasmonic biosensor offers a cost-effective biodetection technology for a myriad of applications ranging from point-of-care testing to in vivo diagnosis of stubborn diseases.

Accelerated pyro-catalytic hydrogen production enabled by plasmonic local heating of Au on pyroelectric BaTiO3 nanoparticles.

The greatest challenge that limits the application of pyro-catalytic materials is the lack of highly frequent thermal cycling due to the enormous heat capacity of ambient environment, resulting in low pyro-catalytic efficiency. Here, we introduce localized plasmonic heat sources to rapidly yet efficiently heat up pyro-catalytic material itself without wasting energy to raise the surrounding temperature, triggering a significantly expedited pyro-catalytic reaction and enabling multiple pyro-catalytic cycling per unit time. In our work, plasmonic metal/pyro-catalyst composite is fabricated by in situ grown gold nanoparticles on three-dimensional structured coral-like BaTiO3 nanoparticles, which achieves a high hydrogen production rate of 133.1 ± 4.4 µmol·g-1·h-1 under pulsed laser irradiation. We also use theoretical analysis to study the effect of plasmonic local heating on pyro-catalysis. The synergy between plasmonic local heating and pyro-catalysis will bring new opportunities in pyro-catalysis for pollutant treatment, clean energy production, and biological applications.

Femtosecond laser point-by-point Bragg grating inscription in BDK-doped step-index PMMA optical fibers: erratum.

An erratum is presented to correct the laser pulse energy applied on the fiber during grating fabrication in Opt. Lett.47(2), 249 (2022)10.1364/OL.450047.

PCF based modal interferometer for lead ion detection.

A compact, reliable, and fast responsive PCF (photonic crystal fiber) based modal interferometric sensor for lead ion detection is proposed and experimentally demonstrated. The sensor has been fabricated by splicing a small section of PCF with SMF (single mode fiber) followed by collapsing the air holes of PCF at its tip. The interferometer is dip coated with chitosan-PVA (polyvinyl alcohol) and glutathione functionalized gold nanoparticles. Three probes have been fabricated, and the maximum sensitivity has been found to be 0.031 nm/ppb for lead ions whereas the detection range has been considered from 0 ppb to 50 ppb. The probe has been found to have a faster response time of ∼ 10 s. Furthermore, the sensor has been found to be less responsive towards other heavy metal ions, thereby demonstrating its selectivity towards lead ions. Besides, a section of FBG (fiber Bragg grating) has been embedded into the interferometer and the temperature response of FBG peak along with interference spectra has been investigated for better accuracy.

Femtosecond laser point-by-point Bragg grating inscription in BDK-doped step-index PMMA optical fibers.

In this paper, the inscription of 2-mm-long fiber Bragg gratings (FBGs) on benzyl dimethyl ketal (BDK)-doped poly(methyl methacrylate) (PMMA) optical fibers by means of a femtosecond laser and a point-by-point FBG inscription technique is reported. The highest reflectivity of approximately 99% is obtained with a pulse energy of 68.5 nJ, showing a large refractive index modulation amplitude of 7.2 × 10-4. Afterwards, grating stabilities at room and higher temperatures of up to 80°C are investigated.

Large refractive index modulation based on a BDK-doped step-index PMMA optical fiber for highly reflective Bragg grating inscription.

We experimentally report high reflectivity on the poly(methyl methacrylate) (PMMA)-based polymer optical fiber Bragg gratings by means of a 266 nm pulsed laser and phase mask technique. In the first recipe, fiber Bragg gratings (FBGs) were manufactured with a single pulse up to 3.7 mJ. After post-annealing, a stable refractive index change up to 4.2×10-4 was obtained. In the second recipe, FBGs were inscribed by 22 pulses with a lower pulse energy of 1.4 mJ, showing a stable refractive index change of 6.2×10-4. Both behaviors may mainly be attributed to the movement of initiating radicals arising from benzyl dimethyl ketal (BDK) under UV irradiation. The high refractive index change in step-index fibers paves the way to tilted FBG manufacturing with large tilt angles potentially for biomedical applications.

Random forest assisted vector displacement sensor based on a multicore fiber.

We proposed a two-dimensional vector displacement sensor with the capability of distinguishing the direction and amplitude of the displacement simultaneously, with improved performance assisted by random forest, a powerful machine learning algorithm. The sensor was designed based on a seven-core multi-core fiber inscribed with Bragg gratings, with a displacement direction range of 0-360° and the amplitude range related to the length of the sensor body. The displacement information was obtained under a random circumstance, where the performances with theoretical model and random forest model were studied. With the theoretical model, the sensor performed well over a shorter linear range (from 0 to 9 mm). Whereas the sensor assisted with random forest algorithm exhibits better performance in two aspects, a wider measurement range (from 0 to 45 mm) and a reduced measurement error of displacement. Mean absolute errors of direction and amplitude reconstruction were decreased by 60% and 98%, respectively. The proposed displacement sensor shows the possibility of machine learning methods to be applied in point-based optical systems for multi-parameter sensing.

Low gas pressure sensor based on a polymer optical fiber grating.

A fiber Bragg grating (FBG) inscribed Zeonex-based novel, to the best of our knowledge, side hole polymer optical fiber (SHPOF) is proposed and demonstrated for low gas pressure measurement above and below the atmospheric pressure. Two different grades of Zeonex have been used to fabricate the core and cladding of this fiber, thereby making it dopant free. The side hole introduced in the cladding is parallel to the fiber core. A few ultrashort pulses with nanosecond duration have been used to write the FBG in the core of this fiber. The incorporation of the side hole leads to enhancement of pressure sensitivity as well as low hysteresis and performance repeatability compared to Zeonex-based conventional polymer optical fiber (CPOF). Above the atmospheric pressure, the proposed probe shows a pressure sensitivity of 0.47 pm/kPa, which is 80% more compared to the Zeonex-based CPOF and 0.48 pm/kPa for regime below atmospheric pressure. The sensor has a resolution of 2.12 kPa and exhibited very low hysteresis.

Pattern recognition in distributed fiber-optic acoustic sensor using an intensity and phase stacked convolutional neural network with data augmentation.

Distributed acoustic sensors (DASs) have the capability of registering faint vibrations with high spatial resolution along the sensing fiber. Advanced algorithms are important for DAS in many applications since they can help extract and classify the unique signatures of different types of vibration events. Deep convolutional neural networks (CNNs), which have powerful spectro-temporal feature learning capability, are well suited for event classification in DAS. Generally, these data-driven methods are highly dependent on the availability of large quantities of training data for learning a mapping from input to output. In this work, to fully utilize the collected information and maximize the power of CNNs, we propose a method to enlarge the useful dataset for CNNs from two aspects. First, we propose an intensity and phase stacked CNN (IP-CNN) to utilize both the intensity and phase information from a DAS with coherent detection. Second, we propose to use data augmentation to further increase the training dataset size. The influence of different data augmentation methods on the performance of the proposed CNN architecture is thoroughly investigated. The experimental results show that the proposed IP-CNN with data augmentation produces a classification accuracy of 88.2% on our DAS dataset with 1km sensing length. This indicates that the usage of both intensity and phase information together with the enlarged training dataset after data augmentation can greatly improve the classification accuracy, which is useful for DAS pattern recognition in real applications.

Hydrogel based Fabry-Pérot cavity for a pH sensor.

A simple, reliable, and quick reactive Fabry-Pérot (FP) structure-based fiber optic pH sensor is presented. The pH-sensitive hydrogel and single-mode fiber (SMF) are placed inside a fused silica capillary to form the FP cavity. The gel thickness is characterized by the spin coating method with respect to different spin speeds. The proposed sensor shows a pH sensitivity of 0.30 nm/pH along with a fast response time of 15 s to 20 s for different pH solvents in the acidic range. Also, the temperature sensitivity of the FPI sensor is found to be -0.56 nm/°C.

Two semicircular-hole fiber in a Sagnac loop for simultaneous discrimination of torsion, strain and temperature.

We report a highly sensitive twist sensor based on a Sagnac interferometer constructed with a new type of optical fiber which contains an elliptical core and two large semicircular-holes, where the slow axis of the core orthogonal to the air-holes has a large sensitivity towards twist-induced birefringent changes. The novel fiber structure results in a highest twist sensitivity of 5.01 nm/° at a chosen dip over the range from 370°-400°. The resonance dips in the interference pattern respond with different rates in the wavelength shifts in the presence of physical parameters permitting to experimentally distinguish directional torsion, axial strain and temperature.

Simultaneous measurement of temperature and strain based on a hollow core Bragg fiber.

A novel, to the best of our knowledge, reflective sensor fabricated by simply sandwiching a homemade hollow core Bragg fiber (HCBF) between two single-mode fibers is proposed and demonstrated for the simultaneous measurement of the temperature and the strain. Different from traditional Fabry-Perot interferometer (FPI) sensors that can achieve only one-parameter sensing with inevitable cross-correspondence to other parameters, the proposed sensor based on the HCBF, which functions as an FPI-inducing FPI spectrum pattern and a weak waveguide confining light-inducing periodic envelope in reflection spectrum, ensures double-parameter sensing. For the HCBF-based reflective sensor, different sensing mechanisms lead to the various sensitivity values of temperature and strain (2.98 pm/°C, 19.4 pm/°C, 2.02 pm/µÎµ, -0.36pm/µÎµ), resulting in a different shift of the confining spectrum envelope and the FPI spectrum fringe. Experimental results indicate that our proposed sensor can measure temperature and strain simultaneously by utilizing a 2×2 matrix. Taking advantage of the compact size, easy fabrication, and low cost, this sensor has an applicable value in harsh environment for simultaneous strain and temperature sensing.

Single nanosecond-pulse production of polymeric fiber Bragg gratings for biomedical applications.

In this study, we present first-time fabrication of FBGs in all ZEONEX-based SMPOFs with a single 25 ns pulse of 248 nm UV irradiation over a 12-month period, which opens up new frontiers in optics and photonics for the effective fabrication of polymer optical fiber Bragg gratings (POFBGs), permitting mass producibility of them. POFBGs were characterized by subjecting them to various physical parameters including temperature and tensile strain. Strain responses of FBGs with similar grating strengths fabricated with 248 nm and 325 nm He-Cd laser irradiations were explored over a year to demonstrate their long-term stability and applicability. Owing to the unique features of the proposed sensing device fabricated by embedding POFBGs in silicone rubber, a good performance in the detection of human heart rate with an amplitude of 4 pm, which is 4 times higher compared to that of silica single mode fiber (SMF) was demonstrated. The response of the sensing device during a human respiration process was also explored where exhalation and inhalation were monitored and distinguished while the breath was held. These revelations signify the importance of ZEONEX-based POFBGs, which allow consistent and effective grating fabrication and are highly promising in the foreseeable future for biomedical applications.

Silicone Rubber Based Highly Sensitive Fiber-Optic Fabry-Perot Interferometric Gas Pressure Sensor.

A simple, compact, and highly sensitive gas pressure sensor based on a Fabry-Perot interferometer (FPI) with a silicone rubber (SR) diaphragm is demonstrated. The SR diaphragm is fabricated on the tip of a silica tube using capillary action followed by spin coating. This process ensures uniformity of its inner surface along with reproducibility. A segment of single mode fiber (SMF) inserted into this tube forms the FPI which produces an interference pattern with good contrast. The sensor exhibits a high gas pressure sensitivity of -0.68 nm/kPa along with a low temperature cross-sensitivity of ≈ 1.1 kPa/°C.

All-optical fiber filter based on an FBG inscribed in a silica/silicone composite fiber.

An all-optical tunable filter based on a fiber Bragg grating (FBG) inscribed in a self-heated silica/silicone composite fiber is demonstrated. A thin silicone film is coated inside the suspended core fiber), which acts as the silicone cladding. A periodic refractive index modulation is inscribed in the silicone cladding by UV irradiation. Silicone is an organic material whose optical properties are different than silica, which leads to interesting applications. The high thermo-optic properties are studied and applied here. A 1550 nm pump laser is utilized to heat the silicone grating where a wavelength shift is observed for the gratings when subjected to different pump powers. Experimental results indicate a wavelength tuning coefficient of -0.128nm/mW with a response time of 0.5 s to obtain a wavelength shift of 1 nm under periodic pump light. The new design of this miniature all-optical filter is cost-effective and can potentially be adhered in optical fiber sensing and communication systems.

Sensitive Mach-Zehnder interferometric sensor based on a grapefruit microstructured fiber by lateral offset splicing.

A novel inline Mach-Zehnder interferometric (MZI) sensor based on a homemade grapefruit microstructured fiber (GMF) was proposed and experimentally demonstrated. The sensing unit consists of a short segment of a GMF sandwiched between two single mode fibers using lateral offset splicing. The fabrication of the GMF and the GMF-based MZI sensor was introduced. Mode analysis of the GMF and theoretical simulation of the proposed MZI sensor were investigated and matched well with experimental results. The sensing performance of the MZI sensor for temperature and strain was tested. The strain and temperature sensitivity are 1.97pm/µÉ› and 37pm/°C, respectively. The compact size, low cost and high sensitivity makes the MZI sensor a good candidate for sensing application.

Application of Fibre Bragg Grating Sensors in Strain Monitoring and Fracture Recovery of Human Femur Bone.

Fibre Bragg Grating (FBG) sensors are gaining popularity in biomedical engineering. However, specific standards for in vivo testing for their use are absolutely limited. In this study, in vitro experimental tests were performed to investigate the behaviors and applications of gratings attached to intact and fractured thighbone for a range of compression loading (<300 N) based around some usual daily activities. The wavelength shifts and the corresponding strain sensitivities of the FBG sensors were measured to determine their effectiveness in monitoring the femoral fracture healing process. Four different arrangements of FBG sensors were selected to measure strains at different critical locations on the femoral sawbones surface. Data obtained for intact and plated sawbones were compared using both embedded longitudinal and coiled FBG arrays. Strains were measured close to the fracture, posterior linea aspera and popliteal surface areas, as well as at the proximal and distal ends of the synthetic femur; their responses are discussed herein. The gratings on the longitudinally secured FBG arrays were found to provide high levels of sensitivity and precise measurements, even for relatively small loads (<100 N). Nevertheless, embedding angled FBG sensors is essential to measure the strain generated by applied torque on the femur bone. The maximum recorded strain of the plated femur was 503.97 µÎµ for longitudinal and -274.97 µÎµ for coiled FBG arrays, respectively. These project results are important to configure effective arrangements and orientations of FBG sensors with respect to fracture position and fixation implant for future in vivo experiments.