Sugar-Derived Nanocrystalline Graphite Matrix C/C Composites with Excellent Ablative Resistance at 3000 °C.

Sugars are renewable resources essential to human life, but they are rarely used as raw materials for the industrial production of carbon-based materials, especially for the preparation of carbon fiber-reinforced carbon-matrix (C/C) composites, which are extremely useful for the semiconductor and aerospace sectors. Herein, a method utilizing sugar-derived carbon to replace petrochemicals as dense matrix to preparing C/C composites is reported. The matrix from sugar-derived C/C (S-C/C) composites has a nanocrystalline graphite structure that is highly thermally stable and effectively bonded to the carbon fibers. The mechanical properties of the S-C/C composite are comparable to those prepared from petrochemical sources; significantly, it exhibits a linear ablation rate of 0.03 mm s-1 after 200 s of ablation at 3000 °C in 10 MW m-2 heat flux. This new class of S-C/C is promising for use in a broad range of fields, ranging from semiconductor to aerospace.

Conductive and antibacterial dual-network hydrogel for soft bioelectronics.

Conductive hydrogels have shown significant potential for use in soft bioelectronics due to their unique similarities to biological tissue, including high water content, low modulus, and conductivity. However, their high water content makes them susceptible to absorbing microorganisms and promoting bacterial growth, which can trigger an immune response. Besides, the adhesion and biocompatibility of the hydrogel are not satisfactory, seriously limiting the conductive hydrogel's high-performance applications in human healthcare monitoring. Herein, the problem is addressed by introducing borax through a swelling and a semi-dehydration method into the interpenetrated network of a polyvinyl alcohol and poly(acrylic acid) hydrogel. The hydrogel exhibits both outstanding antibacterial (>99.99% toward E. coli and S. aureus) activity and high ionic conductivity, in addition to tissue-like softness, strong wet-tissue adhesion (600 J m-2 for skin), environmental stability, and excellent biocompatibility. Furthermore, the as-prepared hydrogel can serve as a biosensing conductor, showing high-quality recording and monitoring of real-time tiny yet complex muscle movements during speaking and realizing neuromodulation through low-current electronic stimulation (40 µA) of a rat's nerve. Simultaneously, the hydrogel also exhibits the capacity to accelerate wound healing. Therefore, the proposed antibacterial conductive hydrogel is a safer option for next-generation bioelectronic materials in human healthcare.

Sugar-Derived Isotropic Nanoscale Polycrystalline Graphite Capable of Considerable Plastic Deformation.

Obtaining large plastic deformation in polycrystalline van der Waals (vdW) materials is challenging. Achieving such deformation is especially difficult in graphite because it is highly anisotropic. The development of sugar-derived isotropic nanostructured polycrystalline graphite (SINPG) is discussed herein. The structure of this material preserves the high in-plane rigidity and out-of-plane flexibility of graphene layers and enables prominent plasticity by activating the rotation of nanoscale (5-10 nm) grains. Thus, micrometer-sized SINPG samples demonstrate enhanced compressive strengths of up to 3.0 GPa and plastic strains of 30-50%. These findings suggest a new pathway for enabling plastic deformation in otherwise brittle vdW materials. This new class of nanostructured carbon materials is suitable for use in a broad range of fields, from semiconductor to aerospace applications.

Performance Investigation on Different Designs of Superhydrophobic Surface Texture for Composite Insulator.

To investigate the superhydrophobic properties of different surface textures, nine designs of textures with micro-nanostructures were produced successfully using the laser engraving technique on the surfaces of composite insulator umbrella skirt samples made of silicon rubber. The optimal parameters of the texture designs to give rise to the best hydrophobicity were determined. The surface morphology, abrasion resistance, corrosion resistance, self-cleaning and antifouling property of the different textured surfaces as well as water droplets rolling on the textured surfaces were studied experimentally using a contact angle meter, scanning electron microscope, three-dimensional topography meter and high-speed camera system. It was found that the diamond column design with optimal parameters has the best superhydrophobicity and overall performance. The most remarkable advantage of the optimal diamond column design is its robustness and long-term superhydrophobicity after repeated de-icing in harsh conditions. The reported work is an important step towards achieving superhydrophobic surface without coating for outdoor composite insulator in practical applications.

A Simulation Model of Periarterial Clearance of Amyloid-ß from the Brain.

The accumulation of soluble and insoluble amyloid-ß (Aß) in the brain indicates failure of elimination of Aß from the brain with age and Alzheimer's disease (AD). There is a variety of mechanisms for elimination of Aß from the brain. They include the action of microglia and enzymes together with receptor-mediated absorption of Aß into the blood and periarterial lymphatic drainage of Aß. Although the brain possesses no conventional lymphatics, experimental studies have shown that fluid and solutes, such as Aß, are eliminated from the brain along 100 nm wide basement membranes in the walls of cerebral capillaries and arteries. This lymphatic drainage pathway is reflected in the deposition of Aß in the walls of human arteries with age and AD as cerebral amyloid angiopathy (CAA). Initially, Aß diffuses through the extracellular spaces of gray matter in the brain and then enters basement membranes in capillaries and arteries to flow out of the brain. Although diffusion through the extracellular spaces of the brain has been well characterized, the exact mechanism whereby perivascular elimination of Aß occurs has not been resolved. Here we use a computational model to describe the process of periarterial drainage in the context of diffusion in the brain, demonstrating that periarterial drainage along basement membranes is very rapid compared with diffusion. Our results are a validation of experimental data and are significant in the context of failure of periarterial drainage as a mechanism underlying the pathogenesis of AD as well as complications associated with its immunotherapy.