1.
Chem Commun (Camb)
; 55(53): 7679-7682, 2019 Jul 07.
Artigo
em Inglês
| MEDLINE
| ID: mdl-31204737
RESUMO
Main-group metals are inherently labile, hindering their use in catalysis. We exploit this lability in the synthesis of isocyanurates. For the first time we report a highly active catalyst that trimerizes alkyl, allyl and aryl isocyanates, and di-isocyanates, with low catalyst loadings under mild conditions, using a hemi-labile aluminium-pyridyl-bis(iminophenolate) complex.