Electrooxidation of coragen-contaminated wastewater using graphite electrodes and sorbent nano-hydroxyapatite.

The degradation of coragen (C18H14N5O2BrCl2) was tested by the electrooxidation process using graphite electrodes. Further, the advantage of nano-hydroxyapatite (n-Hap), as a cost-effective nano sorbent, in the removal of bromide from coragen was examined. Three different variables such as initial pH, electrolysis time and the current density were used to analyse the effects of the electrolytic process on the degradation of coragen. During electrolysis, under various stages, the parameters such as chemical oxygen demand (COD), chloride and bromide were analysed. The maximum COD, chloride and bromide removal efficiency of 96%, 50% and 99%, respectively, at pH 5, the maximum current density of 7.5 mA cm-2 and 120 min electrolysis time were achieved. Based on the final output of this study, it can be concluded that the electrolysis process can effectively reduce COD, chloride and bromide from coragen in an aqueous medium. Further, the degradation efficiency of the coragen was confirmed through different analyses such as UV spectra, Fourier transform infrared spectroscopy and gas chromotography-mass spectrometry analyses.

An integrated anaerobic digestion and microbial electrolysis system for the enhancement of methane production from organic waste: Fundamentals, innovative design and scale-up deliberation.

In the foreseeable future, renewable energy generation from electromethanogenesis to be more cost-effective energy. Electromethanogenesis system is a recent and efficient CO2 to methane technology to upgrade biogas to 100% methane for power generation. And this can be attained through by integrating anaerobic digestion with microbial electrolysis system. Microbial electrolysis system can able to support carbon reduction on cathode and oxidation on anode by CO2 capture thereby provides more CH4 production from an integrated anaerobic digestion system. Scale-up the recent advance technique of microbial electrolysis system in the anaerobic digestion process for 100% methane production for power generation is need of the hour. The overall objective of this review is to facilitate the recent technology of microbial electrolysis system in the anaerobic digestion process. At first, the function of electromethanogenesis system and innovative integrated design method are outlined. Secondly, different external parameters such as applied voltage, operating temperature, pH etc are examined for the significance on process optimization. Eventually, electrode selections, electrode spacing, surface chemistry and surface area are critically reviewed for the scale-up considerations of integration process.

Feasibility of biodiesel production from waste cooking oil: lab-scale to pilot-scale analysis.

In the last few decades, consciousness of fossil fuel resources and increased environmental concerns have given the need for emergence of alternative fuel. Biodiesel is one of the potential renewable energies produced from edible and non-edible biomass which could be a potential alternative for petrol-derived diesel. In this work, initially the process of biodiesel production from waste cooking oil using potassium hydroxide as catalyst and the process parameters were studied in laboratory. The maximum biodiesel yield of 97% was attained at 75 °C with 1 wt% catalyst concentration and oil-methanol molar ratio of 1:06 at 350 rpm and 90 min. Also, these process conditions were used for biodiesel production in the pilot plant and obtained 97% yield. Overall, mass balance for the pilot plant was studied to analyze the product yield loss. The fatty acid methyl ester formation in the plant was confirmed by characterization with FTIR and 1H NMR. Further, the quality of biodiesel produced was compared for its physiochemical properties with the ASTM standards.

Biodegradation of Remazol Brilliant Blue R using isolated bacterial culture (Staphylococcus sp. K2204).

Staphylococcus sp. K2204, a bacterial isolate, was employed in this work to decolorize Remazol Brilliant Blue R (RBBR), which belongs to the anthraquinone class of textile dye. Staphylococcus sp. K2204 biodegraded 100 mg/L RBBR at 37°C under static condition with the help of extracellular laccase and peroxidases. The products of RBBR degradation were characterized using analytical tools including mass spectral technique. The phytotoxicity tests evaluated the toxicity of RBBR and the products of biodegradation. The research outlined here is the first attempt to utilize Staphylococcus sp. K2204 for remediating the wastewater containing anthraquinone textile dye.