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1.
Phys Rev Lett ; 114(21): 217602, 2015 May 29.
Artigo em Inglês | MEDLINE | ID: mdl-26066458

RESUMO

We report on the magnetic structure and ordering of hexagonal LuFeO_{3} films of variable thickness grown by molecular-beam epitaxy on YSZ (111) and Al_{2}O_{3} (0001) substrates. These crystalline films exhibit long-range structural uniformity dominated by the polar P6_{3}cm phase, which is responsible for the paraelectric to ferroelectric transition that occurs above 1000 K. Using bulk magnetometry and neutron diffraction, we find that the system orders into a ferromagnetically canted antiferromagnetic state via a single transition below 155 K regardless of film thickness, which is substantially lower than that previously reported in hexagonal LuFeO_{3} films. The symmetry of the magnetic structure in the ferroelectric state implies that this material is a strong candidate for linear magnetoelectric coupling and control of the ferromagnetic moment directly by an electric field.

2.
Adv Mater ; 27(19): 3032-7, 2015 May 20.
Artigo em Inglês | MEDLINE | ID: mdl-25856781

RESUMO

A large enhancement of the thermoelectric figure of merit is reported in single-crystalline films of CrN. The mechanism of the reduction of the lattice thermal conductivity in cubic CrN is similar to the resonant bonding in IV-VI compounds. Therefore, useful ideas from classic thermo-electrics can be applied to tune functionalities in transition metal nitrides and oxides.

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