Laser-Constructed Bionic Composite Fog-Collecting Surfaces with Efficient Nucleation Sites and Enhanced Water Transport.

Fog collection effectively alleviates the current freshwater shortage; thus, enhancing its efficiency is crucial. Here, we report a novel bionic fog collection surface (Al@B-V) comprising composite superhydrophobic bumps integrated with superhydrophilic V-channel grooves. This surface, which has efficient fog nucleation points and enhanced water transport capabilities, effectively balances fog capture and water transport during the collection process, thereby achieving high-efficiency fog collection. Compared to ordinary aluminum-based surfaces, Al@B-V achieves a fog collection efficiency of up to 3.08 g·cm-2·h-1, three times higher than the original aluminum-based surface. Furthermore, the V-channel groove proposed in this study exhibits a water transport speed of up to 165 mm·s-1, which is remarkably approximately 80 times faster than the commonly used U-channel groove. Additionally, this V-channel groove can overcome gravity, transporting approximately 10 µL of liquid to the top even when placed at 90° inclination. It can directionally transport 10 µL of liquid over a distance of up to 151 mm on a plane. This novel microgroove design can be effectively applied in various fields, including liquid collection, directional transport, seawater desalination, microfluidics, and drug delivery.

Fluid-Solid Interfacial Properties and Drag-Reducing Characterization of the Flexible Conical Microstructured Film Inspired by the Streamlined Body Surface of the Pufferfish.

Given the challenges in accurately replicating the surface of the pufferfish, this study employed three-dimensional (3D) printing to create a model based on inverse modeling. The morphology of the pufferfish exhibits a streamlined configuration, characterized by a gradual widening from the anterior oral region to the central ocular area, followed by a progressive narrowing from the midabdominal region toward the caudal extremity. The RNG k-ε turbulence simulation results demonstrate that the streamlined body surface of the pufferfish diminishes differential pressure resistance. This enhancement promotes laminar flow formation, delays fluid separation, minimizes turbulence-induced vortices, and reduces frictional resistance. Moreover, the pufferfish's supple and uneven outer epidermis was simplified into a flexible, nonsmooth planar film to conduct fluid-solid coupling simulations. These revealed that the pufferfish's unique skin can absorb turbulent energy and minimize momentum transfer between the fluid and the solid film, lowering the fluid resistance during swimming. In summary, The high-efficiency swimming capacity of pufferfish stems not only from their streamlined body surface but also significantly from the unique structural characteristics and mechanical properties of their flexible skin. This research provides critical theoretical underpinnings for the design of functional bionic surfaces aimed at drag reduction.

Hierarchical Structure with Microcrater Covered with Nanograss Enhancing Condensation and Its Antifrosting/Anti-Icing Performance Inspired by Euphorbia helioscopia L.

Over an extended period of evolution and natural selection, a multitude of species developed a diverse array of biological interface features with specific functions. These biological structures provide a rich source of inspiration for the design of bionic structures on superhydrophobic surfaces. Understanding the functional mechanism of plant leaves is of paramount importance for the advancement of new engineering materials and the further promotion of engineering applications of bionic research. The hierarchical structure of microcrater-covered nanograss (MCNG) on the surface of E. helioscopia L. leaf provided the inspiration for the bionic MCNG surface, which was successfully prepared on a copper substrate by hybrid laser micromachining technology and chemical etching. The combined action of texture structure and surface chemistry resulted in a contact angle of 169° ± 1° for MCNG surface droplets and a rolling angle of less than 1°. Notably, the condensation-induced adhesion force does not augment with the increase of the temperature difference, which facilitated the shedding of hot droplets from the surface. The microscope observation revealed a high density of condensed droplets on the MCNG surface and the tangible jumping behavior of the droplets. The fabricated MCNG also demonstrated excellent antifrost/anti-icing abilities in low-temperature and high-humidity environments. Finally, the study confirmed the exceptional mechanical durability and reusability of the MCNG surface through various tests, including scratch damage, sandpaper wear, water flow impact and flushing, and condensation-drying cycle tests. The nanograss can be effectively protected within the microcrater structure. This research presents a promising approach for preventing and/or removing unwanted droplets in numerous engineering applications.

Superhydrophobic Surfaces with Excellent Ice Prevention and Drag Reduction Properties Inspired by Iridaceae Leaf.

The anti-icing and drag-reduction properties of diverse microstructured surfaces have undergone extensive study over the past decade. Nonetheless, tough environments enforce stringent demands on the composite characteristics of superhydrophobic surfaces (SHS). In this study, fresh composite structures were fabricated on a metal substrate by nanosecond laser machining technology, drawing inspiration from the hardy plant Iridaceae. The prepared sample surface mainly consists of a periodic microrhombus array and irregular nanosheets. To comprehensively investigate the effect of its special structure on surface properties, three surfaces with different sizes of rhombic structures were used for comparative analysis, and the results show that the SH-S2 sample is optimal. This can significantly delay the freezing time by an impressive 1404 s at -10 °C while revealing the sample surface anti-icing strategy. In addition, the rheological experiments determined over 300 µm of slip length for the SH-S2 sample, and the drag reduction rate of the surface reaches nearly 40%, which is well aligned with the results of the delayed icing experiments. Finally, the mechanical durability of the SH-S2 surface was investigated through scratch damage, sandpaper abrasion, reparability trials, and icing and melting cycle tests. This research presents a new approach and methodology for the application of SHS on polar ship surfaces.

Passive microfluidic devices for cell separation.

The separation of specific cell populations is instrumental in gaining insights into cellular processes, elucidating disease mechanisms, and advancing applications in tissue engineering, regenerative medicine, diagnostics, and cell therapies. Microfluidic methods for cell separation have propelled the field forward, benefitting from miniaturization, advanced fabrication technologies, a profound understanding of fluid dynamics governing particle separation mechanisms, and a surge in interdisciplinary investigations focused on diverse applications. Cell separation methodologies can be categorized according to their underlying separation mechanisms. Passive microfluidic separation systems rely on channel structures and fluidic rheology, obviating the necessity for external force fields to facilitate label-free cell separation. These passive approaches offer a compelling combination of cost-effectiveness and scalability when compared to active methods that depend on external fields to manipulate cells. This review delves into the extensive utilization of passive microfluidic techniques for cell separation, encompassing various strategies such as filtration, sedimentation, adhesion-based techniques, pinched flow fractionation (PFF), deterministic lateral displacement (DLD), inertial microfluidics, hydrophoresis, viscoelastic microfluidics, and hybrid microfluidics. Besides, the review provides an in-depth discussion concerning cell types, separation markers, and the commercialization of these technologies. Subsequently, it outlines the current challenges faced in the field and presents a forward-looking perspective on potential future developments. This work hopes to aid in facilitating the dissemination of knowledge in cell separation, guiding future research, and informing practical applications across diverse scientific disciplines.

Phyllostachys Viridis-Leaf-like MLMN Surfaces Constructed by Nanosecond Laser Hybridization for Superhydrophobic Antifogging and Anti-Icing.

In nature, many species commonly evolve specific functional surfaces to withstand harsh external environments. In particular, structured wettability of surfaces has attracted tremendous interest due to its great potential in antifogging and anti-icing properties. Phyllostachys Viridis is a resistant low-temperature (-18 °C) plant with superhydrophobicity and ice resistivity behaviors. In this work, with inspiration from the representative cold-tolerant plants leaves, a unique multilevel micronano (MLMN) surface was fabricated on copper substrate by ultrafast laser process, which exhibited superior superhydrophobic characteristics with the water contact angle > 165° and rolling angle< 2°. In the dynamic wettability experiment, the rebound efficiency of the droplet on the MLMN surface reached 20.6%, and the contact time was only 10.6 ms. In the condensation experiment, the nucleation, growth, merging, and bouncing of fog drops on the surface was distinctly observed, indicating that rational texture structures can improve the antifogging performance of the surface. In the anti-icing experiment, the freezing time was delayed to 921 s at -10 °C, and the freezing time of salt water reached a staggering 1214 s. Moreover, the mechanical durability of MLMN surfaces was confirmed by scratch damage, sandpaper abrasion, and icing and melting cycle tests, and their repairability was evaluated for product applications in practice. Finally, the underlying antifogging/anti-icing strategy of the MLMN surface was also revealed. We anticipate that the investigations offer a promising way to handily design and fabricate multiscale hierarchical structures with reliable antifogging and anti-icing performance, especially in saltwater-related applications.

Recent advances in prevailing antifogging surfaces: structures, materials, durability, and beyond.

In past decades, antifogging surfaces have drawn more and more attention owing to their promising and wide applications such as in aerospace, traffic transportation, optical devices, the food industry, and medical and other fields. Therefore, the potential hazards caused by fogging need to be solved urgently. At present, the up-and-coming antifogging surfaces have been developing swiftly, and can effectively achieve antifogging effects primarily by preventing fog formation and rapid defogging. This review analyzes and summarizes current progress in antifogging surfaces. Firstly, some bionic and typical antifogging structures are described in detail. Then, the antifogging materials explored thus far, mainly focusing on substrates and coatings, are extensively introduced. After that, the solutions for improving the durability of antifogging surfaces are explicitly classified in four aspects. Finally, the remaining big challenges and future development trends of the ascendant antifogging surfaces are also presented.

Preparation and Evaluation of PDMS/Carbon Soot Particles Superhydrophobic Biomimetic Composite Coating with Self-Cleaning and Durability.

In this paper, a superhydrophobic biomimetic composite coating was fabricated on brass by electrochemical etching, brushing PDMS adhesive layer, and depositing carbon soot particles. Due to the microstructure and the optimized ratio of PDMS, the contact angle of the superhydrophobic coating is up to 164° and the sliding angle is only 5°. The results of optical microscopy and morphometric laser confocal microscopy show that the prepared coating surface has a rough hierarchical structure. A high-speed digital camera recorded the droplet bouncing process on the surface of the superhydrophobic coating. The self-cleaning property of the coatings was evaluated by applying chalk dust particles as simulated solid contaminants and different kinds of liquids (including grape juice, beer, cola, and blue ink) as liquid contaminants. The coating remained superhydrophobic after physical and chemical damage tests. This work presents a strategy for fabricating superhydrophobic biomimetic composite coatings with significant self-cleaning properties, durability, and shows great potential for practical engineering applications.

Ultrafast Self-Healing Superhydrophobic Surface for Underwater Drag Reduction.

The self-healing superhydrophobic surfaces have attracted great interest owing to restoring superhydrophobicity without preparation crafts. However, the self-healing superhydrophobic surface still faces the dilemma of long repairing time. Especially in aqueous environments, superhydrophobic surfaces are highly susceptible to contamination and damage. In the current study, a superhydrophobic surface with ultrafast repairability was developed, which apply for drag reduction in aqueous medium. The prepared superhydrophobic surface can recover superhydrophobicity in only 30 s after severe physical and chemical damage. In addition, this research pioneered the combination of superhydrophobicity and porous structures for underwater drag reduction. The study of drag reduction confirms that the superhydrophobic surface can reduce the frictional drag by about 43% in the water. However, the drag reduction rate of the superhydrophobic surface with the porous structure can be improved to 76% due to increased stability of the air layer. More importantly, the porous structure with the average pore size of 50 µm has the most excellent stability through further experiments on the underwater air layer. This is attributed to the proper size of the pore to effectively balance the capillary force and resist wetting in the marginal region. This study will bring inspiration for the large-scale application of superhydrophobic surfaces and long-term drag reduction.

Coupled Bionic Drag-Reducing Surface Covered by Conical Protrusions and Elastic Layer Inspired from Pufferfish Skin.

Inspired by the drag-reducing properties of the cone-like spines and elastic layer covering the pufferfish skin, important efforts are underway to establish rational multiple drag-reducing strategies for the development of new marine engineering materials. In the present work, a new drag-reducing surface (CPES) covered by conical protrusions (sparse "k-type" with rough height k+ = 13-15) and an elastic layer are constructed on copper substrate via a hybrid method, combining the sintering and coating processes. The drag-reducing feature of the prepared CPES biomimetic surface is achieved by rheometer and particle image velocimetry (PIV) experiments. To comprehensively investigate its drag reduction mechanism, the porous copper substrate (PCS), copper substrate (CS), conical protrusion resin substrate (CPRS), and conical protrusion porous copper substrate (CPPCS) were used for a comparative analysis. In laminar flow, we discovered that the conical protrusion structure and wettability of the elastic surface coupling affect the CPES sample's drag-reducing performance (7-8%) and that the interface produced slip to reduce the viscous drag. In turbulent flow, the CPES biomimetic surface exhibits an 11.5-17.5% drag-reducing performance. Such behavior was enabled by two concurrent mechanisms: (i) The conical protrusions as vortex generators enhance the number of vortices and the wake effect, enabling faster movement of downstream strips, reducing viscous drag; (ii) The conical protrusion elements break and lift large-scale vortices to produce numerous small-scale vortices with low energy, effectively weakening perturbations and momentum exchange. Additionally, the elastic layer shows high adhesion and stability on copper substrate after sandpaper abrasion and water-flow erosion tests. The copper substrate surface formed by the sintering method is also covered with dense porous structures, which gives the elastic layer and conical protrusions excellent combined robustness. Our findings not only shed new light on the design of robust drag-reducing surfaces but also provide new avenues for underwater drag reduction in the field of marine applications.

Recent advances in bioinspired superhydrophobic ice-proof surfaces: challenges and prospects.

Bionic superhydrophobic ice-proof surfaces inspired by natural biology show great potential in daily life. They have attracted wide research interest due to their promising and wide applications in offshore equipment, transportation, power transmission, communication, energy, etc. The flourishing development of superhydrophobic ice-proof surfaces has been witnessed due to the availability of various fabrication methods. These surfaces can effectively inhibit the accumulation of ice, thereby ensuring the safety of human life and property. This review highlights the latest advances in bio-inspired superhydrophobic ice-proof materials. Firstly, several familiar cold-resistant creatures with well-organized texture structures are listed briefly, which provide an excellent template for the design of bioinspired ice-proof surfaces. Next, the advantages and disadvantages of the current techniques for the preparation of superhydrophobic ice-proof surfaces are also analyzed in depth. Subsequently, the theoretical knowledge on icing formation and three passive ice-proof strategies are introduced in detail. Afterward, the recent progress in improving the durability of ice-proof surfaces is emphasized. Finally, the remaining challenges and promising breakthroughs in this field are briefly discussed.

Rheological Properties and Drag Reduction Performance of Puffer Epidermal Mucus.

Most species of fish are covered with mucus, which provides the effect of reduction in swimming drag. In this paper, three concentrations of puffer epidermal mucus were obtained from the epidermal mucosa of puffer. The rheological properties and the drag reduction performance of the puffer epidermal mucus were characterized via a rheometer experimental and numerical simulation method. The relationship between the rheological properties and the drag reduction performance was analyzed and discussed, and the drag reduction mechanism of the puffer epidermal mucus was further explored. The results showed that the best drag reduction rate was 6.2% when the inflow velocity and concentration of puffer epidermal mucus were 0.1 m/s and 18.2 g/L, respectively. The rheological properties of puffer epidermal mucus are viscoelastic, and the mucus forms a sliding surface, which reduces the frictional drag of the fluid. In conclusion, this paper may provide a reference for the development of drag-reducing agents and drag-reducing research studies on other fish mucus.

Experimental Investigations of the Turbulent Boundary Layer for Biomimetic Protrusive Surfaces Inspired by Pufferfish Skin: Effects of Spinal Density and Diameter.

Pufferfish is known for its extension of tiny spine-covered skin that appears to increase skin drag and may act as turbulisors, reducing overall drag while serving a protective function. Therefore, the present study addresses a neglected aspect of how spines affect the turbulent boundary layer (TBL) for drag reduction in the pufferfish skin. Particle image velocimetry (PIV) was utilized to investigate the TBL structure on the biomimetic spine-covered protrusion samples inspired by the back skin of the pufferfish. The comparison samples of two sparse "k-type" arrangements (hexagon and staggered) for three types of rough element sizes with roughness heights k+ = 5.5-6.5 (nearly hydraulically smooth) and smooth case in bulk Reynolds numbers (Reb = 37,129 and 44,554) were tested. The results of turbulence statistics of these samples indicate that both the sample (type hexagon) for large rough density (λ = 0.0215) with small roughness elements and the sample (type staggered) for small rough density (λ = 0.0148) with large roughness elements have a drag reduction rate of 5-11%. These two kinds of bionic surfaces have a similar morphology to that seen in the distribution of pufferfish spines and probably serve a similar hydrodynamic function. Vortex identification shows that the spines in the front section for large density with small rough elements stabilize the TBL and generate many small-scale vortices and the dense spines with large rough elements at the back section have the effect of separating the vortices. The retrograde vortex generated by them is beneficial to increasing the driving force of the pufferfish. In addition, these two rough surfaces may effectively delay the separation of the TBL. These results will provide a preliminary research foundation for the development of a more practical prototype of the bionic drag-reducing surfaces and strengthen the theoretical investigation concerning drag reduction exploration.

Investigation of the Turbulent Boundary Layer Structure over a Sparsely Spaced Biomimetic Spine-Covered Protrusion Surface.

Multiperspective particle image velocimetry was used to investigate the turbulent boundary layer structure over biomimetic spine-covered protrusion (BSCP) samples inspired by dorsal skin of pufferfish. The comparison of BSCP samples of two sparse "k-type" arrangements (aligned and staggered) with roughness height k + = 5-7 (nearly hydraulically smooth) and smooth case were manufactured in bulk Reynolds number Re b = 37,091, 44,510. The negative value of the roughness function ΔU + shows a downward shift of the mean velocity profile of BSCP samples, which shows a drag reduction effect. The results of turbulent statistics present strong fluctuation over the aligned case in the streamwise direction, while little influence is observed in the wall-normal and spanwise direction, which promotes turbulence stability. The same phenomenon was found based on the probability density function of fluctuation velocity that the suppression of turbulent flow is better over the staggered case. It is obvious that the shear stress induced is governed by the streamwise fluctuations. Furthermore, the Q-criterion and the λci-criterion improved with vorticity ω were introduced for vortex identification, which indicates less prograde vortex population and weaker swirling strength over BSCP samples than over the smooth one. Finally, the spatial coherent structure appeared similar and more orderly over the staggered case in the streamwise and wall-normal direction based on the analysis of two-point correlations R uu. These results provide further guidance to reveal the mechanism of drag reduction on the BSCP surface.

Numerical Analysis of Drag Reduction Characteristics of Biomimetic Puffer Skin: Effect of Spinal Height and Tilt Angle.

Based on the migratory phenomenon of the puffer and the cone-shaped structures on its skin, the effects of spinal height and tilt angle on the drag reduction characteristics is presented by numerical simulation in this paper. The results show that the trend of total drag reduction efficiency changes from slow growth to a remarkable decline, while the viscous drag reduction efficiency changes from an obvious increase to steady growth. The total and viscous drag reduction efficiencies are 19.5% and 31.8%, respectively. In addition, with the increase in tilt angle, the total drag reduction efficiency decreases gradually; the viscous drag reduction efficiency first increases and then decreases, finally tending to be stable; and the total and viscous drag reduction efficiency reaches 20.7% and 26.7%, respectively. The flow field results indicate that the pressure drag mainly originates at the front row of the spines and that the total pressure drag can be effectively controlled by reducing the former pressure drag. With the increase in low-speed fluid and the reduction in the near-wall fluid velocity gradient, the viscous drag can be weakened. Nevertheless, the drag reduction effect is achieved only when the decrement of viscous drag is greater than the increment of pressure drag. This work can serve as a theoretical basis for optimizing the structure and distribution parameters of spines on bionic non-smooth surfaces.

Thriving artificial underwater drag-reduction materials inspired from aquatic animals: progresses and challenges.

In the past decades, drag-reduction surfaces have attracted more and more attention due to their potentiality and wide applications in various fields such as traffic, energy transportation, agriculture, textile industry, and military. However, there are still some drag-reduction materials that need to be deeply explored. Fortunately, natural creatures always have the best properties after long-term evolution; aquatic organisms have diversified surface microstructures and drag-reducing materials, which provide design templates for the development of thriving artificial underwater drag-reduction materials. Aquatic animals are tamed by the current while fighting against the water, and thus have excellent drag reduction that is unparalleled in water. Inspired by biological principles, using aquatic animals as a bionic object to develop and reduce frictional resistance in fluids has attracted more attention in the past few years. More and more aquatic animals bring new inspiration for drag-reduction surfaces and a tremendous amount of research effort has been put into the study of surface drag-reduction, with an aim to seek the surface structure with the best drag-reduction effect and explore the drag-reduction mechanism. This present paper reviews the research on drag-reduction surfaces inspired by aquatic animals, including sharks, dolphins, and other aquatic animals. Aquatic animals as bionic objects are described in detail, with a discussion on the drag-reduction mechanism and drag-reduction effect to understand the development of underwater drag-reduction fully. In bionic manufacturing, the effective combination of various preparation methods is summarized. Moreover, bionic surfaces are briefly explained in terms of traffic, energy sources, sports, and agriculture. In the end, both existing problems in bionic research and future research prospects are proposed. This paper may provide a better and more comprehensive understanding of the current research status of aquatic animals-inspired drag reduction.

Research on the drag reduction property of puffer (Takifugu flavidus) spinal nonsmooth structure surface.

Puffers show good drag reduction performance during migration. It is worth noting that spines which are different from ordinary fish scales are densely distributed on the puffer skin. Here, the special morphological structure of puffer spines was observed using microscopy techniques, accurate contour models were established based on image processing techniques and curve fitting, then feature sizes were obtained. Based on the results, the nonsmooth surface was established by orthogonal test to simulate the flow field. In addition, the influence of spinal structure on boundary layer flow field and the drag reduction property of nonsmooth surface were further analyzed. The nonsmooth surface formed by spinal structure elements can effectively reduce the wall shear stress and Reynolds stress, and there was a special "climbing vortex" phenomenon, so as to reduce the surface viscous friction resistance and achieve drag reduction. Compared with the smooth surface, the drag reduction rate of the nonsmooth surface was 12.94% when the inflow velocity was 5 m/s, which revealed and verified the drag reduction performance of the spines of puffer skin. The results lay a foundation for further research and optimization of drag reduction ability of nonsmooth surface of bionic spines. HIGHLIGHTS: The contour of the spinous process was accurately reflected by the Fourier function. The spines of puffer skin have good drag reduction effect. There was a special "climbing vortex" phenomenon to explain the drag reduction property.