Classical-quantum crossover in magnetic stochastic resonance in uniaxial superparamagnets.

It is shown that the signal-to-noise ratio of the magnetic moment fluctuations in the magnetic stochastic resonance of a quantum uniaxial paramagnet of arbitrary spin value S subjected to a weak probing ac field H(t) = H cos Ωt and a dc bias magnetic field H(0) displays a pronounced dependence on S. The dependence arises from the quantum dynamics of spins which differs markedly from the magnetization dynamics of classical superparamagnets. In the large spin limit, S --> ∞, the quantum solutions reduce to those for a classical uniaxial superparamagnet.

Quantum effects in the Brownian motion of a particle in a double well potential in the overdamped limit.

Quantum effects in the noninertial Brownian motion of a particle in a double well potential are treated via a semiclassical Smoluchowski equation for the time evolution of the reduced Wigner distribution function in configuration space allowing one to evaluate the position correlation function, its characteristic relaxation times, and dynamic susceptibility using matrix continued fractions and finite integral representations in the manner of the classical Smoluchowski equation treatment. Reliable approximate analytic solutions based on the exponential separation of the time scales of the fast intrawell and slow overbarrier relaxation processes are given. Moreover, the effective and the longest relaxation times of the position correlation function yield accurate predictions of both the low and high frequency relaxation behavior. The low frequency part of the dynamic susceptibility associated with the Kramers escape rate behaves as a single Lorentzian with characteristic frequency given by the quantum-mechanical reaction rate solution of the Kramers problem. As a particular example, quantum effects in the stochastic resonance are estimated.

Inertial effects in the orientational relaxation of rodlike molecules in a uniaxial potential.

The inertial rotational Brownian motion and dielectric relaxation of an assembly of noninteracting rodlike polar molecules in a uniaxial potential are studied. The infinite hierarchy of differential-recurrence relations for the equilibrium correlation functions is generated by averaging the governing inertial Langevin equation over its realizations in phase space. The solution of this hierarchy for the one-sided Fourier transforms of the relevant correlation functions is obtained using matrix continued fractions yielding the longitudinal dipole correlation function, the correlation time, and the complex polarizability, which are calculated for typical values of the model parameters. Pronounced inertial effects appear in these characteristics in the high-frequency region for low damping. The exact longitudinal correlation time is compared with the predictions of the Kramers theory of the escape rate of a Brownian particle from a potential well as extended by Mel'nikov and Meshkov [J. Chem. Phys. 85, 1018 (1986)]. In the low temperature limit, the universal Mel'nikov and Meshkov formula for the inverse of the escape rate provides a good estimate of the longitudinal correlation time for all values of the dissipation including the very low damping, very high damping, and Kramers turnover regimes. Moreover, the low-frequency part of the spectra of the longitudinal correlation function may be approximated by a single Lorentzian with a halfwidth determined by this universal escape rate formula.

Semiclassical treatment of a Brownian ratchet using the quantum Smoluchowski equation.

Quantum effects in the noninertial Brownian motion of a particle in a one-dimensional ratchet potential are treated in the high temperature and weak bath-particle coupling limit by solving a quantum Smoluchowski equation for the time evolution of the Wigner function in configuration space. In particular, an analytical expression for the stationary average drift velocity for constant driving forces is presented including quantum corrections to any order in Planck's constant. The corresponding frequency response is determined using continued fractions in both the linear approximation holding for small ac driving amplitude and in the nonlinear regime for arbitrary driving amplitude exhibiting pronounced ac induced frequency dependence of the dc component of the average drift velocity. Moreover, Shapiro steps are apparent in the dc characteristics for strong ac driving just as in the dc current-voltage characteristics of a point Josephson junction.

Inertial effects in the nonlinear transient relaxation of rigid rodlike molecules in a strong dc electric field.

A method of calculation of nonlinear transient responses of an assembly of noninteracting polar linear molecules due to sudden changes in a strong external dc electric field is presented. The infinite hierarchy of differential-recurrence relations for the decay functions describing the relaxation of the system is derived by averaging the underlying inertial Langevin equation. The solution of this hierarchy is obtained in terms of matrix continued fractions. The integral relaxation time and the spectrum of the electric polarization for various nonlinear transient responses (step-on, step-off, and rapidly rotating field) are calculated for typical values of the model parameters. The nonlinear transient responses exhibit pronounced nonlinear effects due to the strong dc field. Analytical equations for the quantities of interest are presented in the overdamped limit. Furthermore, the linear response relaxation function and linear dynamic susceptibility are obtained as a particular case of a general nonlinear theory.

Anisotropic rotational diffusion and dielectric relaxation of rigid dipolar particles in a strong external dc field.

Dielectric response functions of polar particles (macromolecules) diluted in a nonpolar solvent subjected to a strong external dc electric field are evaluated using the anisotropic noninertial rotational diffusion model. Simple analytic formulas for the longitudinal and transverse components of the dielectric susceptibility and relaxation times are given using the effective relaxation time method. These formulas are tested against numerical solutions of the underlying infinite hierarchy of differential-recurrence equations for statistical moments (ensemble averages of the Wigner D functions) which are obtained by averaging the governing Langevin equation for noninertial rotational Brownian motion over its realizations. The calculations, involving matrix continued fractions, ultimately yield the exact solution of the infinite hierarchy of differential-recurrence relations for the dielectric response functions. In the isotropic rotational diffusion limit, the solution reduces to the known results.

Smoluchowski equation approach for quantum Brownian motion in a tilted periodic potential.

Quantum corrections to the noninertial Brownian motion of a particle in a one-dimensional tilted cosine periodic potential are treated in the high-temperature and weak bath-particle coupling limit by solving a quantum Smoluchowski equation for the time evolution of the distribution function in configuration space. The theoretical predictions from two different forms of the quantum Smoluchowski equation already proposed-viz., J. Ankerhold [Phys. Rev. Lett. 87, 086802 (2001)] and W. T. Coffey [J. Phys. A 40, F91 (2007)]-are compared in detail in a particular application to the dynamics of a point Josephson junction. Various characteristics (stationary distribution, current-voltage characteristics, mean first passage time, linear ac response) are evaluated via continued fractions and finite integral representations in the manner customarily used for the classical Smoluchowski equation. The deviations from the classical behavior, discernible in the dc current-voltage characteristics as enhanced current for a given voltage and in the resonant peak in the impedance curve as an enhancement of the Q factor, are, respectively, a manifestation of relatively high-temperature nondissipative tunneling (reducing the barrier height) and dissipative tunneling (reducing the damping of the Josephson oscillations) near the top of a barrier.

Solution of the master equation for Wigner's quasiprobability distribution in phase space for the Brownian motion of a particle in a double well potential.

Quantum effects in the Brownian motion of a particle in the symmetric double well potential V(x)=ax(2)2+bx(4)4 are treated using the semiclassical master equation for the time evolution of the Wigner distribution function W(x,p,t) in phase space (x,p). The equilibrium position autocorrelation function, dynamic susceptibility, and escape rate are evaluated via matrix continued fractions in the manner customarily used for the classical Fokker-Planck equation. The escape rate so yielded has a quantum correction depending strongly on the barrier height and is compared with that given analytically by the quantum mechanical reaction rate solution of the Kramers turnover problem. The matrix continued fraction solution substantially agrees with the analytic solution. Moreover, the low-frequency part of the spectrum associated with noise assisted Kramers transitions across the potential barrier may be accurately described by a single Lorentzian with characteristic frequency given by the quantum mechanical reaction rate.

Phase-space formulation of the nonlinear longitudinal relaxation of the magnetization in quantum spin systems.

Nonlinear longitudinal relaxation of a spin in a uniform external dc magnetic field is treated using a master equation for the quasiprobability distribution function of spin orientations in the configuration space of polar and azimuthal angles (analogous to the Wigner phase space distribution for translational motion). The solution of the corresponding classical problem of the rotational Brownian motion of a magnetic moment in an external magnetic field essentially carries over to the quantum regime yielding in closed form the dependence of the longitudinal spin relaxation on the spin size S as well as an expression for the integral relaxation time, which in linear response reduces to that previously given by D. A. Garanin [Phys. Rev. E 55, 2569 (1997)] using the density matrix approach. The nonlinear relaxation is dominated by a single exponential having as time constant the integral relaxation time. Thus a simple description in terms of a Bloch equation holds even for the nonlinear response of a giant spin.

Fractional translational diffusion of a Brownian particle in a double well potential.

The fractional translational diffusion of a particle in a double-well potential (excluding inertial effects) is considered. The position correlation function and its spectrum are evaluated using a fractional probability density diffusion equation (based on the diffusion limit of a fractal time random walk). Exact and approximate solutions for the dynamic susceptibility describing the position response to a small external field are obtained. The exact solution is given by matrix continued fractions while the approximate solution relies on the exponential separation of the time scales of the fast "intrawell" and low overbarrier relaxation processes associated with the bistable potential. It is shown that knowledge of the characteristic relaxation times for normal diffusion allows one to predict accurately the anomalous relaxation behavior of the system for all relevant time scales.