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1.
J Chem Educ ; 100(11): 4530-4535, 2023 Nov 14.
Artigo em Inglês | MEDLINE | ID: mdl-38028752

RESUMO

Summative lab assessments probe student mastery over concepts, but conventional ones often result in decreased student engagement and confidence. If conventional summative lab assessments are replaced by accessible gamified evaluations, such as online escape rooms, this leads to improved student engagement and confidence. In this work, we adapted two sustainability themed online escape room activities to increase student engagement and confidence in data analyses in Integrated Chemistry I (CHEM 381) over three semesters at CSU, Chico. Over 89.7% of students earned full credit. Further, 80.0% of the written comments included positive feedback. After the online escape room assessments, 60.0% of the students rated their confidence as "high" or "very high" in all categories assessed, compared to 25.6% before the experience. Students found that the online escape room assessments were more engaging than the traditional assessment and increased their confidence as they worked toward solving two sustainability crises and competed for the quickest time to complete the escape rooms.

2.
J Phys Chem Lett ; 14(47): 10630-10633, 2023 Nov 30.
Artigo em Inglês | MEDLINE | ID: mdl-37983016

RESUMO

We have synthesized inherently chiral cesium lead halide perovskite magic-sized clusters (PMSCs) and ligand-assisted metal halide molecular clusters (MHMCs) using the achiral ligands octanoic acid (OCA) and octylamine (OCAm). UV-vis electronic absorption was used to confirm characteristic absorption bands while circular dichroism (CD) spectroscopy was utilized to determine their chiroptical activity in the 412-419 and 395-405 nm regions, respectively. In contrast, the larger sized counterpart of PMSCs, namely, perovskite quantum dots (PQDs), do not show chirality. The inherent chirality of the clusters is tentatively attributed to a twisted chiral layered structure, defect-induced chiral structure, or twisted Pb-Br octahedra.

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