Transfer-printed micro-LED and polymer-based transceiver for visible light communications.

Visible light communications (VLC) is an emerging technology that uses LEDs, such as found in lighting fixtures and displays, to transmit data wirelessly. Research has so far focused on LED transmitters and on photoreceivers as separate, discrete components. Combining both types of devices into a single transceiver format will enable bi-directional VLC and offer flexibility for the development of future advanced VLC systems. Here, a proof of concept for an integrated optical transceiver is demonstrated by transfer printing a microsize LED, the transmitter, directly onto a fluorescent optical concentrator edge-coupled to a photodiode, the receiver. This integrated device can simultaneously receive (downlink) and transmit (uplink) data at rates of 416 Mbps and 165 Mbps, respectively. Its capability to operate in optical relay mode at 337 Mbps is experimentally demonstrated.

Green Perovskite Distributed Feedback Lasers.

A visible perovskite distributed feedback laser is fabricated for the first time. Through the use of nanocrystal pinning, highly luminescent methylammonium lead bromide films are used to produce stable lasers emitting at 550 nm, with a low threshold of 6 µJcm-2. The lasers were able to support multiple polarisations, and could be switched between transverse magnetic and transverse electric mode operation through simple tuning of the distributed feedback grating period.

Probing the energy levels of perovskite solar cells via Kelvin probe and UV ambient pressure photoemission spectroscopy.

The field of organo-lead halide perovskite solar cells has been rapidly growing since their discovery in 2009. State of the art devices are now achieving efficiencies comparable to much older technologies like silicon, while utilising simple manufacturing processes and starting materials. A key parameter to consider when optimising solar cell devices or when designing new materials is the position and effects of the energy levels in the materials. We present here a comprehensive study of the energy levels present in a common structure of perovskite solar cell using an advanced macroscopic Kelvin probe and UV air photoemission setup. By constructing a detailed map of the energy levels in the system we are able to predict the importance of each layer to the open circuit voltage of the solar cell, which we then back up through measurements of the surface photovoltage of the cell under white illumination. Our results demonstrate the effectiveness of air photoemission and Kelvin probe contact potential difference measurements as a method of identifying the factors contributing to the open circuit voltage in a solar cell, as well as being an excellent way of probing the physics of new materials.

Fluidic fibre dye lasers.

We report the demonstration of compact fluidic fibre lasers based on capillary tubes and photonic crystal fibres, featuring single channel and multiple laterally integrated fluidic lasers respectively. Their preparation was based on capillary action and lasing occurred without the need for external mirrors or lithographically defined microstructures. The fibre lasers were found to be tunable by varying the chromophore density in the liquid core and a functional wavelength selectivity mechanism inherent in both types of lasers provided a long free spectral range that does not correspond to the length of the fibres. The enhanced mode spacing is attributed to a Vernier resonant effect.

Diode pumped distributed Bragg reflector lasers based on a dye-to-polymer energy transfer blend.

We report the demonstration of a compact, all-solid-state polymer laser system comprising of a Gallium Nitride (GaN) semiconductor diode laser as the pump source. The polymer laser was configured as a surface emitting, distributed Bragg reflector laser (DBR), based on a novel energy transfer blend of Coumarin 102 and the conjugated polymer poly(2-methoxy-5-(2'-ethylhexyloxy)-1,4-phenylene vinylene). In this configuration, diode pumping was possible both due to the improved quality of the resonators and the improved harvesting of the diode laser light.

The role of bacterial motility in the survival and spread of Pseudomonas fluorescens in soil and in the attachment and colonisation of wheat roots.

Motile and non-motile strains of Pseudomonas fluorescens SBW25 were constructed using different combinations of the lacZY, xylE and aph marker genes which allowed their detection and differentiation in soil, root and seed samples. The survival of motile and non-motile strains was investigated in both non-competitive and competitive assays in water and non-sterile soil. Although there was no difference between strains in water, the motile strain survived in significantly greater numbers than the non-motile strain after 21 days in soil. There was no significant difference between competitive assays, where motile and non-motile cells were co-inoculated into soil, and non-competitive assays where strains were inoculated separately. Bacterial survival decreased as matric potential increased from -224 to -17 kPa but matric potential had no significant effect on motile compared to non-motile strains. Vertical spread of both motile and non-motile strains was detected 6.4 mm from the inoculum zone after 14 days in the absence of percolating water. There was no significant difference, for either strain, in distance moved from the inoculum zone after 14, 26 or 40 days. The motile strain had a significant advantage in attachment to sterile wheat roots in both non-competitive and competitive studies. When the spatial colonisation of wheat root systems was assessed in non-sterile soil, there was no significant difference between the motile and non-motile strain from either seed or soil inoculum. However, when the whole root system was assessed as one sample unit, differences could be detected. Bacterial motility could contribute to survival in soil and the initial phase of colonisation, where attachment and movement onto the root surface are important.

Degradation of substituted phenylurea herbicides by Arthrobacter globiformis strain D47 and characterization of a plasmid-associated hydrolase gene, puhA.

Arthrobacter globiformis D47 was shown to degrade a range of substituted phenylurea herbicides in soil. This strain contained two plasmids of approximately 47 kb (pHRIM620) and 34 kb (pHRIM621). Plasmid-curing experiments produced plasmid-free strains as well as strains containing either the 47- or the 34-kb plasmid. The strains were tested for their ability to degrade diuron, which demonstrated that the degradative genes were located on the 47-kb plasmid. Studies on the growth of these strains indicated that the ability to degrade diuron did not offer a selective advantage to A. globiformis D47 on minimal medium designed to contain the herbicide as a sole carbon source. The location of the genes on a plasmid and a lack of selection would explain why the degradative phenotype, as with many other pesticide-degrading bacteria, can be lost on subculture. A 22-kb EcoRI fragment of plasmid pHRIM620 was expressed in Escherichia coli and enabled cells to degrade diuron. Transposon mutagenesis of this fragment identified one open reading frame that was essential for enzyme activity. A smaller subclone of this gene (2.5 kb) expressed in E. coli coded for the protein that degraded diuron. This gene and its predicted protein sequence showed only a low level of protein identity (25% over ca. 440 amino acids) to other database sequences and was named after the enzyme it encoded, phenylurea hydrolase (puhA gene).

The role of motility in the in vitro attachment of Pseudomonas putida PaW8 to wheat roots.

The attachment of motile and non-motile strains of Pseudomonas putida PaW8 to sterile wheat roots was assessed in both non-competitive and intra-specific competitive assays. The motile strain showed significantly greater attachment to wheat roots than non-motile strains in phosphate buffer. Overall, the motile strain attached better than the non-motile strain at 10(6), 10(7) and 10(8) cfu ml(-1) in competitive assays and at 10(6) and 10(7) cfu ml(-1) in non-competitive assays. When attachment was studied in Luria broth no significant difference between motile and non-motile strains was detected. P. putida PaW8 cells marked with the luxAB genes were used to compare direct detection of attached cells by luminometry with indirect detection by dilution plate counts following extraction from root material. Although direct detection permitted a rapid assessment (60 s) of attachment to surfaces, dilution plate counts provided a more sensitive method for quantification of bacteria. The detection limits were approximately 10 cfu root(-1) using dilution plate counts compared with 1000 cfu root(-1) using luminometry. All results highlighted the importance of motility for the attachment of P. putida to plant roots in simple model systems. To take this work further, studies to assess the role of motility using complex non-sterile systems are needed.

Extended mode-hop-free tuning by use of a dual-cavity, pump-enhanced optical parametric oscillator.

We report extended mode-hop-free tuning in a continuous-wave, pump-enhanced optical parametric oscillator (PE-OPO). We employ a dual-cavity configuration to allow independent control of the resonant pump and signal fields, and so we can suppress frequent mode hops in the signal as the pump is tuned in frequency. With the signal field clamped in frequency by an uncoated etalon, the idler field can be scanned smoothly through a range of 10.8 GHz. The PE-OPO outputs can also be tuned coarsely from 1.01 to 1.18 mum in the signal and from 2.71 to 3.26 mum and 4.07 to 5.26 mum in the idler. We find that increased idler absorption only slightly increases the oscillation threshold.

Continuous-wave singly resonant optical parametric oscillator based on periodically poled RbTiOAsO(4).

We report a continuous-wave optical parametric oscillator (OPO) based on periodically poled RbTiOAsO(4) (PPRTA). The singly resonant OPO, which is located within a Ti:sapphire laser, has a high-finesse signal cavity and delivers a maximum output power of 270 mW to the nonresonant idler wave at 2.92mum , through a 4.5-mm PPRTA crystal. For room-temperature operation and a crystal with a 30-mu;m grating period, pump tuning over 838-848 nm results in OPO tuning over 1.13-1.27mum (signal) and 2.53-3.26mum (idler), limited by the bandwidth of optical coatings. PPRTA exhibits thermal properties superior to those of periodically poled LiNbO(3) .

Doubly resonant continuous-wave optical parametric oscillator pumped by a single-mode diode laser.

The performance characteristics of a doubly (signal and idler) resonant continuous-wave optical parametric oscillator based on periodically poled lithium niobate and pumped by a 100-mW single-mode laser diode at 810 nm are reported. Pump power thresholds as low as 16 mW and wavelength tuning over the range 1.15-1.25 microm at the signal and 2.31-2.66 microm at the idler were achieved through variation of crystal temperature, pump wavelength, and grating period. Up to 5 mW of signal output was obtained with the single-mode diode pump, and signal powers of up to 39 mW were obtained when pumping with a 400-mW injection-locked broad-area diode laser.