Fate and Transport of 17ß-Estradiol beneath Animal Waste Holding Ponds.

Concentrated animal feeding operations typically store livestock waste in clay-lined ponds. Although these ponds are regulated to include a liner with a small hydraulic conductivity to limit leaching, previous studies have traced surface and groundwater contamination from such regulated animal waste ponds. This research examined the transport of 17ß-estradiol (E2) and its primary metabolite, estrone (E1), through soil liners using field- and laboratory-based studies. Additionally, a potential engineering solution to limit hormone transport-applying biochar to new pond liners to act as a retardant-was studied. Soil cores 80 cm in length were collected beneath a mature dairy waste pond and analyzed for moisture content and hormone concentrations. Unsaturated conditions and E2 concentrations of 4 to 250 ng g were detected beneath the waste pond. In the laboratory portion of the study, hand-packed columns of sand or clay were subjected to infiltration by a 2.3-m head of dairy waste. A subset of the hand-packed sand columns was amended with powdered biochar to test its ability to retard E2 and E1. For 3 mo, column leachate was analyzed for hormone concentrations, and at the conclusion of the study E2 and E1 concentrations in the soil were measured. In the 44 d after sealing, the clay, sand, sand with a thin layer of biochar, and sand mixed with a biochar amendment leached a total of 0.54, 1.3, 0.09, and 0.45 µg of E2, respectively. The biochar amendments to the hand-packed columns considerably minimized E2 in the leachate.

Using risk analysis to predict design flow exceedance of decentralized wastewater management systems.

In small communities, the number of residential units is a more stable indicator of wastewater volume than population. Large communities benefit from averaging because the likelihood of having concurrent large flows from all users is small. In contrast, a single septic system connected to a single residence must be designed to accommodate large flow variations. The objective of this study was to determine the risk of assigning various daily wastewater volumes to residential units. Risk was based on the probability of underestimating daily volume and, therefore, exceeding the capacity of the system. This study concluded that assigning a value of 950 L/d per residence (250 gpd per residence) is appropriate for communities with 15 or more residences, and that assigning a value of 850 L/d per residence (225 gpd per residence) is appropriate for communities with 30 or more residential connections.

In situ colloid mobilization in Hanford sediments under unsaturated transient flow conditions: effect of irrigation pattern.

Colloid transport may facilitate off-site transport of radioactive wastes at the Hanford site, Washington State. In this study, column experiments were conducted to examine the effect of irrigation schedule on releases of in situ colloids from two Hanford sediments during saturated and unsaturated transientflow and its dependence on solution ionic strength, irrigation rate, and sediment texture. Results show that transient flow mobilized more colloids than steady-state flow. The number of short-term hydrological pulses was more important than total irrigation volume for increasing the amount of mobilized colloids. This effect increased with decreasing ionic strength. At an irrigation rate equal to 5% of the saturated hydraulic conductivity, a transient multipulse flow in 100 mM NaNO3 was equivalent to a 50-fold reduction of ionic strength (from 100 mM to 2 mM) with a single-pulse flow in terms of their positive effects on colloid mobilization. Irrigation rate was more important for the initial release of colloids. In addition to water velocity, mechanical straining of colloids was partly responsible for the smaller colloid mobilization in the fine than in the coarse sands, although the fine sand contained much larger concentrations of colloids than the coarse sand.