RESUMO
The reorientational dynamics of Y(BH4)3·xNH3 (x = 0, 3, and 7) was studied using quasielastic neutron scattering (QENS) and neutron spin echo (NSE). The results showed that changing the number of NH3 ligands drastically alters the reorientational mobility of the BH4- anion. From the QENS experiments, it was determined that the BH4- anion performs 2-fold reorientations around the C2 axis in Y(BH4)3, 3-fold reorientations around the C3 axis in Y(BH4)3·3NH3, and either 2-fold reorientations around the C2 axis or 3-fold reorientations around the C3 axis in Y(BH4)3·7NH3. The relaxation time of the BH4- anion at 300 K decreases from 2 × 10-7 s for x = 0 to 1 × 10-12 s for x = 3 and to 7 × 10-13 s for x = 7. In addition to the reorientational dynamics of the BH4- anion, it was shown that the NH3 ligands exhibit 3-fold reorientations around the C3 axis in Y(BH4)3·3NH3 and Y(BH4)3·7NH3 as well as 3-fold quantum mechanical rotational tunneling around the same axis at 5 K. The new insights constitute a significant step toward understanding the relationship between the addition of ligands and the enhanced ionic conductivity observed in systems such as LiBH4·xNH3 and Mg(BH4)2·xCH3NH2.
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The structure and reorientational dynamics of KB3H8 were studied by using quasielastic and inelastic neutron scattering, Raman spectroscopy, first-principles calculations, differential scanning calorimetry, and in situ synchrotron radiation powder X-ray diffraction. The results reveal the existence of a previously unknown polymorph in between the α'- and ß-polymorphs. Furthermore, it was found that the [B3H8]- anion undergoes different reorientational motions in the three polymorphs α, α', and ß. In α-KB3H8, the [B3H8]- anion performs 3-fold rotations in the plane created by the three boron atoms, which changes to a 2-fold rotation around the C 2 symmetry axis of the [B3H8]- anion upon transitioning to α'-KB3H8. After transitioning to ß-KB3H8, the [B3H8]- anion performs 4-fold rotations in the plane created by the three boron atoms, which indicates that the local structure of ß-KB3H8 deviates from the global cubic NaCl-type structure. The results also indicate that the high reorientational mobility of the [B3H8]- anion facilitates the K+ cation conductivity, since the 2-orders-of-magnitude increase in the anion reorientational mobility observed between 297 and 311 K coincides with a large increase in K+ conductivity.
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The hexagonal mixed-anion solid solution Na2(CB9H10)(CB11H12) shows the highest room-temperature ionic conductivity among all known Na-ion conductors. To study the dynamical properties of this compound, we have measured the 1H and 23Na nuclear magnetic resonance (NMR) spectra and spin-lattice relaxation rates in Na2(CB9H10)(CB11H12) over the temperature range of 80-435 K. It is found that the diffusive motion of Na+ ions can be described in terms of two jump processes: the fast localized motion within the pairs of tetrahedral interstitial sites of the hexagonal close-packed lattice formed by large anions and the slower jump process via octahedral sites leading to long-range diffusion. Below 350 K, the slower Na+ jump process is characterized by the activation energy of 353(11) meV. Although Na+ mobility in Na2(CB9H10)(CB11H12) found from our NMR experiments is higher than in other ionic conductors, it appears to be an order-of-magnitude lower than that expected on the basis of the conductivity measurements. This result suggests that the complex diffusion mechanism and/or correlations between Na+ jumps should be taken into account. The measured 1H spin-lattice relaxation rates for Na2(CB9H10)(CB11H12) are consistent with a coexistence of at least two anion reorientational jump processes occurring at different frequency scales. Near room temperature, both reorientational processes are found to be faster than the Na+ jump process responsible for the long-range diffusion.
RESUMO
The vibrational spectrum of hydrogen and the parameters of H jump motion in the rhombohedral Th(2)Zn(17)-type compound Ce(2)Fe(17)H(5) have been studied by means of inelastic and quasielastic neutron scattering. It is found that hydrogen atoms occupying interstitial Ce(2)Fe(2) sites participate in the fast localized jump motion over the hexagons formed by these tetrahedral sites. The H jump rate τ(-1) of this localized motion is found to change from 3.9 × 10(9) s(-1) at T = 140 K to 4.9 × 10(11) s(-1) at T = 350 K, and the temperature dependence of τ(-1) in the range 140-350 K is well described by the Arrhenius law with the activation energy of 103±3 meV. Our results suggest that the hydrogen jump rate in Th(2)Zn(17)-type compounds strongly increases with decreasing nearest-neighbor distance between the tetrahedral sites within the hexagons. Since each such hexagon in Ce(2)Fe(17)H(5) is populated by two hydrogen atoms, the jump motions of H atoms on the same hexagon should be correlated.
RESUMO
The vibrational spectra of hydrogen and parameters of H diffusion in the coarse-grained C15-type system ZrCr(2)H(3) and in nanostructured ZrCr(2)H(3) have been studied by means of inelastic and quasielastic neutron scattering. It is found that the diffusive motion of hydrogen in coarse-grained ZrCr(2)H(3) can be described in terms of at least two jump processes: a fast localized H motion with the jump rate τ(l)( - 1) over the hexagons formed by interstitial Zr(2)Cr(2) sites and a slower process with the rate τ(d)( - 1) associated with H jumps leading to long-range diffusion. While τ(d)( - 1)(T) in the range 250-380 K follows the Arrhenius law with the activation energy of 142 ± 4 meV, the temperature dependence of τ(l)( - 1) deviates from Arrhenius behavior. The nanostructured ZrCr(2)H(3) samples prepared by ball milling consist of C15-type grains and strongly distorted (amorphous-like) regions. H atoms in the strongly distorted regions are found to be immobile on the time scale of our experiments. The microscopic picture of H jump motion in the C15-type grains of the nanostructured samples is similar to that in coarse-grained ZrCr(2)H(3); however, the ball milling leads to a considerable decrease in the jump rate τ(d)( - 1).
RESUMO
In order to study the mechanism and parameters of H jump motion in the nonstoichiometric Nb carbides, we have performed quasielastic neutron scattering (QENS) measurements for NbC(0.71)H(0.28) over the temperature range 11- 475 K. Our results indicate that about 30% of H atoms in this system participate in a fast diffusive motion. The temperature dependence of the corresponding H jump rate in the range 298-475 K follows the Arrhenius law with an activation energy of 328 ± 9 meV. The Q dependence of the QENS data suggests that the observed jump motion corresponds to long-range diffusion of H atoms along chains of the off-centre sites in carbon vacancies.
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Protein powders that are dehydrated or mixed with a glassy compound are known to have improved thermal stability. We present elastic and quasielastic neutron scattering measurements of the global dynamics of lysozyme and ribonuclease A powders. In the absence of solvation water, both protein powders exhibit largely harmonic motions on the timescale of the measurements. Upon partial hydration, quasielastic scattering indicative of relaxational processes appears at sufficiently high temperature. When the scattering spectrum are analyzed with the Kohlrausch-Williams-Watts formalism, the exponent beta decreases with increasing temperature, suggesting that multiple relaxation modes are emerging. When lysozyme was mixed with glycerol, its beta values were higher than the hydrated sample at comparable temperatures, reflecting the viscosity and stabilizing effects of glycerol.
Assuntos
Glicerol/química , Temperatura Alta , Muramidase/química , Ribonuclease Pancreático/química , Água/química , Animais , Bovinos , Galinhas , Estabilidade Enzimática/efeitos dos fármacos , Estabilidade Enzimática/efeitos da radiação , Glicerol/farmacologia , Nêutrons , Conformação Proteica , Desnaturação Proteica/efeitos dos fármacos , Desnaturação Proteica/efeitos da radiação , Proteínas/química , Espalhamento de Radiação , Termodinâmica , Água/farmacologiaRESUMO
First-principles calculations of the electronic band structure and lattice dynamics for the new superconductor MgB (2) are carried out and found to be in excellent agreement with our inelastic neutron scattering measurements. The numerical results reveal that the E(2g) in-plane boron phonons near the zone center are very anharmonic and strongly coupled to the planar B sigma bands near the Fermi level. This giant anharmonicity and nonlinear electron-phonon coupling is key to quantitatively explaining the observed high T(c) and boron isotope effect in MgB (2).
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The NIST Materials Science and Engineering Laboratory works with industry, standards bodies, universities, and other government laboratories to improve the nation's measurements and standards infrastructure for materials. An increasingly important component of this effort is carried out at the NIST Center for Neutron Research (NCNR), at present the most productive center of its kind in the United States. This article gives a brief historical account of the growth and activities of the Center with examples of its work in major materials research areas and describes the key role the Center can expect to play in future developments.