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1.
Nanomaterials (Basel) ; 12(19)2022 Oct 10.
Artigo em Inglês | MEDLINE | ID: mdl-36234663

RESUMO

This article explores the industrial application of an Al-based nanocomposite reinforced with 0.5 wt.% of multiwalled carbon nanotubes with a Zn mechanical plating applied to fulfill the field requirements of electrical devices. The performance of electric devices made from this nanocomposite material and with a Zn plating was compared with that of MCCB devices using a normal Cu compound. MCCB devices with the Al-based nanocomposites compound showed a better performance, with less heat generated due to a flow of electrical charge passing through the device. The presence of MWCNTs in the Al nanocomposite dissipates heat, maintaining a stable electrical resistance in the MCCB, in contrast to what happens with Cu compound, which increases its electrical resistance as the temperature in the device increases.

2.
Nanomaterials (Basel) ; 11(5)2021 Apr 28.
Artigo em Inglês | MEDLINE | ID: mdl-33925115

RESUMO

This article focuses on exploring how the electrical conductivity and densification properties of metallic samples made from aluminum (Al) powders reinforced with 0.5 wt % concentration of multi-walled carbon nanotubes (MWCNTs) and consolidated through spark plasma sintering (SPS) process are affected by the carbon nanotubes dispersion and the Al particles morphology. Experimental characterization tests performed by scanning electron microscopy (SEM) and by energy dispersive spectroscopy (EDS) show that the MWCNTs were uniformly ball-milled and dispersed in the Al surface particles, and undesirable phases were not observed in X-ray diffraction measurements. Furthermore, high densification parts and an improvement of about 40% in the electrical conductivity values were confirmed via experimental tests performed on the produced sintered samples. These results elucidate that modifying the powder morphology using the ball-milling technique to bond carbon nanotubes into the Al surface particles aids the ability to obtain highly dense parts with increasing electrical conductivity properties.

3.
Materials (Basel) ; 14(2)2021 Jan 14.
Artigo em Inglês | MEDLINE | ID: mdl-33466693

RESUMO

This paper focuses on reporting results obtained by the spark plasma sintering (SPS) consolidation and characterization of aluminum-based nanocomposites reinforced with concentrations of 0.5 wt%, 1 wt% and 2 wt% of single-walled carbon nanotubes (SWCNTs) and multi-walled carbon nanotubes (MWCNTs). Experimental characterization performed by SEM shows uniform carbon nanotube (CNT) dispersion as well as carbon clusters located in the grain boundary of the Al matrix. The structural analysis and crystallite size calculation were performed by X-ray diffraction tests, detecting the characteristic CNT diffraction peak only for the composites reinforced with MWCNTs. Furthermore, a considerable increment in the crystallite size value for those Al samples reinforced and sintered with 1 wt% of CNTs was observed. Hardness tests show an improvement in the composite surface hardness of about 11% and 18% for those samples reinforced with 2 wt% of SWNCTs and MWCNTs, respectively. Conductivity measurements show that the Al samples reinforced with 2 wt% of MWCNTs and with 0.5 wt% SWCNTs reach the highest IACS values of 50% and 34%, respectively.

4.
Polymers (Basel) ; 11(12)2019 Dec 06.
Artigo em Inglês | MEDLINE | ID: mdl-31817694

RESUMO

This research focuses on developing a novel ultra high molecular weight polyethylene (UHMWPE) material reinforced with titanium dioxide (TiO 2 ) nanoparticles for producing craniofacial prostheses via an incremental sheet forming process (SPIF). First, UHMWPE-TiO 2 nanocomposite sheets were produced using incipient wetting and the compression molding process by considering different concentrations of TiO 2 nanoparticles. Then, the influence that the compression molding fabrication process has on the crystallinity and structural properties of the produced sample sheets was investigated. Experimental characterizations via scanning electron microscopy (SEM), differential scanning calorimetry (DSC), X-ray diffraction (XRD), Fourier transform infrared (FT-IR), tensile mechanical testing, and live/dead cell viability assays provided data that show an enhancement of the physical, mechanical, and biological properties. Finally, modifications on the nanocomposite material properties due to the SPIF manufacturing processes of a craniofacial prosthesis are addressed.

5.
Polymers (Basel) ; 11(12)2019 Nov 28.
Artigo em Inglês | MEDLINE | ID: mdl-31795142

RESUMO

This paper focuses on developing, fabricating, and characterizing composite polycaprolactone (PCL) membranes reinforced with titanium dioxide nanoparticles (NPs) elaborated by using two solvents; acetic acid and a mixture of chloroform and N,N-dimethylformamide (DMF). The resulting physical, chemical, and mechanical properties of the composite materials are studied by using experimental characterization techniques such as scanning electron microscopy (SEM), differential scanning calorimetry (DSC), X-Ray diffraction (XRD), Fourier-transform infrared (FTIR) analysis, contact angle (CA), uniaxial and biaxial tensile tests, and surface roughness measurements. Experimental results show that the composite material synthesized by sol-gel and chloroform-DMF has a better performance than the one obtained by using acetic acid as a solvent.

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