Characterisation of thermally treated beech and birch by means of quasi-static tests and ultrasonic waves.

Wood, being renewable and highly abundant material, with excellent high specific strength and stiffness, has received increasing attention to be used in high performance applications such as the structural element of a battery case in an electric vehicle. For a successful implementation of wood in the automotive sector, it is, therefore, crucial to understand the behaviour of wood during and after temperature exposure and in the event of fire with the presence/absence of oxygen. In this study, the mechanical properties of thermally modified and unmodified European beech and birch in air and nitrogen environments at six different treatment intensities were characterised using compression tests, tensile tests, shear tests and Poisson's ratio tests. Further, the elastic properties of these wood species were quantified using the ultrasound measurements. The obtained strength and stiffness exhibited mild improvement upon moderate temperature treatment (200 °C), followed by a decrease at elevated temperature levels. This improvement was somewhat more pronounced under nitrogen treatment than under air treatment conditions. Nevertheless, a more noticeable decrease in the material performance was observed in beech compared to birch, occurring at earlier stages of modifications. This study confirms the tension-compression asymmetry of beech and birch where higher Young's moduli were obtained from tensile than from compression tests for reference and thermally treated beech and birch. The shear moduli obtained from ultrasound for birch were comparable to those obtained from quasi-static tests, whereas there was an overestimation of approximately 11-59% for the shear modulus of beech compared to quasi-static tests. Poisson's ratios from ultrasound tests corresponded well with those from quasi-static tests for untreated beech and birch, but not for thermally modified samples. The Saint-Venant model can satisfactorily predict the shear moduli of untreated and treated beech wood.

Chemical and physical interactions of regenerated cellulose yarns and isocyanate-based matrix systems.

In the development of structural composites based on regenerated cellulose filaments, the physical and chemical interactions at the fibre-matrix interphase need to be fully understood. In the present study, continuous yarns and filaments of viscose (rayon) were treated with either polymeric diphenylmethane diisocyanate (pMDI) or a pMDI-based hardener for polyurethane resins. The effect of isocyanate treatment on mechanical yarn properties was evaluated in tensile tests. A significant decrease in tensile modulus, tensile force and elongation at break was found for treated samples. As revealed by size exclusion chromatography, isocyanate treatment resulted in a significantly reduced molecular weight of cellulose, presumably owing to hydrolytic cleavage caused by hydrochloric acid occurring as an impurity in pMDI. Yarn twist, fibre moisture content and, most significantly, the chemical composition of the isocyanate matrix were identified as critical process parameters strongly affecting the extent of reduction in mechanical performance. To cope with the problem of degradative reactions an additional step using calcium carbonate to trap hydrogen ions is proposed.