Investigating the viability of sulfur polymers for the fabrication of photoactive, antimicrobial, water repellent coatings.

Elemental sulfur (S8), a by-product of the petroleum refining industries, possesses many favourable properties including photocatalytic activity and antibacterial activity, in addition to being intrinsically hydrophobic. Despite this, there is a relative lack of research employing elemental sulfur and/or sulfur copolymers within superhydrophobic materials design. In this work, we present the use of sulfur copolymers to produce superhydrophobic materials with advanced functionalities. Using inverse vulcanization and the use of a natural organic crosslinker, perillyl alcohol (PER), stable S8-PER copolymers were synthesised and later combined with silica (SiO2) nanoparticles, to achieve highly water repellent composites that displayed both antimicrobial and photocatalytic properties, in the absence of carcinogenic and/or expensive materials. Here, we investigated the antibacterial performance of coatings against the Staphylococcus aureus bacterial strain, where coatings displayed great promise for use in antifouling applications, as they were found to limit surface adhesion by more than 99%, when compared to uncoated glass samples. Furthermore, UV dye degradation tests were performed, utilizing the commercially available dye resazurin, and it was shown that coatings had the potential to simultaneously exhibit surface hydrophobicity and photoactivity, demonstrating a great advancement in the field of superhydrophobic materials.

The challenges, achievements and applications of submersible superhydrophobic materials.

Superhydrophobic materials have been widely reported throughout the scientific literature. Their properties originate from a highly rough morphology and inherently water repellent surface chemistry. Despite promising an array of functionalities, these materials have seen limited commercial development. This could be attributed to many factors, like material compatibility, low physical resilience, scaling-up complications, etc. In applications where persistent water contact is required, another limitation arises as a major concern, which is the stability of the air layer trapped at the surface when submerged or impacted by water. This review is aimed at examining the diverse array of research focused on monitoring/improving air layer stability, and highlighting the most successful approaches. The reported complexity of monitoring and enhancing air layer stability, in conjunction with the variety of approaches adopted, results in an assortment of suggested routes to achieving success. The review is addressing the challenge of finding a balance between maximising water repulsion and incorporating structures that protect air pockets from removal, along with challenges related to the variant approaches to testing air-layer stability across the research field, and the gap between the achieved progress and the required performance in real-life applications.