Analysis and structural characterization of pigments and materials used in Nicolae Grigorescu heritage paintings.

The combination of various mobile, non-invasive techniques (IR reflectography technique, optical microscopy, XRF, Raman and NIR spectroscopies) and lab-based devices (FTIR and XPS spectroscopies, SEM-EDX microscopy) lead to the first exhaustive investigation of pigments and materials used by the famous Romanian painter Nicolae Grigorescu in three cultural heritage paintings. The study of a large number of spots and samples allowed a rigorous analysis and a far-reaching insight into his work.