High-Resolution Mapping of Material Stocks in Belgian Road Infrastructure: Material Efficiency Patterns, Material Recycling Potentials, and Greenhouse Gas Emissions Reduction Opportunities.

Road infrastructure is an integral part of built environment stocks, as it delivers essential social and economic services. While previous work has assessed material stocks, flows, and embodied emissions, spatially refined mapping of materials accumulated in road infrastructure can highlight hitherto underappreciated synergies between improved spatial planning, material stock efficiency, and urban mining. In this study, we mapped the materials stocked in road infrastructure across Belgium, explored the patterns of material stock efficiency and the recyclability of end-of-life road materials, and examined the greenhouse gas (GHG) emissions reductions of improving stock efficiency and recycling. We assembled data scattered across various governmental sources and crowdsourced platforms and developed a comprehensive database to warehouse locational information on road typology, layer geometry and thickness, material characteristics, traffic volume, climatic conditions, and soil conditions. Our results reveal a strong but nonlinear correlation between material stock efficiency and population density, indicating that spatial planning can reduce the required road stocks and associated GHG emissions. Urban mining potentials in road infrastructure hinge on multiple factors, such as the proximity to recycling facilities and the degradation of pavements during use. Our counterfactual analysis shows that urban road planning and reusing recycled asphalt can cut GHG emissions by up to 53 and 70%, respectively. Therefore, material-efficient road planning and improved material recycling can help realize circular economy potentials and mitigate GHG emissions moving forward.

Correction: Borinelli et al. VOC Emission Analysis of Bitumen Using Proton-Transfer Reaction Time-Of-Flight Mass Spectrometry. Materials 2020, 13, 3659.

The authors wish to make the following corrections to this paper [...].

Coupling AFM and CLSM to investigate the effect of ageing on the bee structures of bitumen.

Bitumen's surface microstructure is in general well-documented and most recent theories postulate the effect of crystalline wax on the so-called bee structures. Although it is widely accepted that ageing has an effect on this unique microstructure yet conflicting literature exists on clear trends. This paper explores the effect of ageing on the bee structures of bitumen, employing two advanced microscopic techniques: an Atomic Force Microscopy (AFM) and a Confocal Laser Scanning Microscopy (CLSM). Four waxy and two wax-free bituminous binders are investigated before and after sequential laboratory short- and long-term ageing. The study demonstrates that the number of bees per µm2 and bee area percentage decrease with ageing, whereas their size is increasing. A systematic analysis of the waveform characteristics is also provided for the peaks and valleys as well as the shape probabilistic values of the bee structures. In conclusion, the results of the two techniques are in good agreement, reporting similar trends upon ageing for the relative bee density. Differences are mainly identified in the waveform calculations. It is believed that this systematic investigation may assist in enhancing the understanding of the effect of ageing on the surface microstructure, the wax distribution as well as on the wax crystallisation.

Fatigue Resistance of Bituminous Mixtures and Mortars Containing High Reclaimed Asphalt Content.

With the increased use of reclaimed asphalt (RA), the ability of bituminous materials to resist fatigue cracking may face a decline mainly due to the aged reclaimed asphalt binder (RAB), especially when RA is used at higher rates and not sufficiently treated. In this study, the bulk scale (asphalt) and its subscale (mortar) were employed to evaluate the effect on fatigue resistance when a RAB is added, by considering three replacement rates: 0%, 40%, and 70% RAB. The fatigue testing of asphalt mixtures was carried out using a four-point bending (4PB) setup, while the mortars were tested using a new column-like geometry utilising a dynamic shear rheometer (DSR). The fatigue properties were further analysed using dissipated energy concepts. The aim of this study was, first, to assess whether the inclusion of a RAB can provide at least similar fatigue properties compared to an all-virgin mix, and second, to evaluate whether the proposed treatment is beneficial for the mixtures with a RAB. The asphalt tests revealed that the inclusion of a 40% RAB led to increased fatigue resistance, whereas the mortar tests showed that the inclusion of RAB has an inverse effect on fatigue life.

VOC Emission Analysis of Bitumen Using Proton-Transfer Reaction Time-Of-Flight Mass Spectrometry.

Bitumen is one of the most important materials used in roads. During asphalt pavement construction, workers can be affected by emissions, such as volatile organic compounds (VOCs), when bitumen is heated. Therefore, it is crucial to correctly identify and measure VOCs. This paper presents a novel, promising method to determine VOC emissions. The proposed method offers a way to standardize routine measurements on a lab scale, enabling reliable comparison across bitumen types and their modifications or additives. A proton-transfer reaction time-of-flight mass spectrometer (PTR-TOF-MS) was used to monitor VOC emissions from commercial unmodified bitumen and crumb rubber modified bitumen (CRMB) with heating of up to 180 °C. Results confirmed that the temperature range of 160-180 °C is a highly influential factor for VOC emissions from heated commercial bitumen and particularly CRMB. A significant increase in alkane and aromatic emission was detected when the binders were heated to 180 °C. Sulfur-containing VOCs were almost nonexistent for the base bitumen fumes, while a significant increase was detected in the fumes when two different types of CR were added to the bitumen, even at 120 °C. The additional CR in the bituminous binder contributed to the potentially harmful VOC emission of benzothiazole, which belongs to the class of sulfur-containing compounds. The concentration of benzothiazole was 65%, 38%, and 35% higher for CR1 in comparison to CR2 at 140, 160, and 180 °C, respectively. It is clear from the results that this method allows different bitumen sources or modifications to be quickly analyzed and their VOC emissions cross-compared. If adopted and confirmed further, the method could offer the asphalt industry a viable solution to monitor VOC emissions by analyzing samples in real time at different steps of the production process.

Characterizing the Complex Modulus of Asphalt Concrete Using a Scanning Laser Doppler Vibrometer.

Asphalt mixtures are the most common types of pavement material used in the world. Characterizing the mechanical behavior of these complex materials is essential in durable, cost-effective, and sustainable pavement design. One of the important properties of asphalt mixtures is the complex modulus of elasticity. This parameter can be determined using different standardized methods, which are often expensive, complex to perform, and sensitive to the experimental setup. Therefore, recently, there has been considerable interest in developing new, easier, and more comprehensive techniques to investigate the mechanical properties of asphalt. The main objective of this research is to develop an alternative method based on an optical measurement technique (laser Doppler vibrometry). To do this, a frequency domain system identification technique based on analytical formulas (Timoshenko's beam theory) is used to determine the complex modulus of asphalt concrete at its natural frequencies and to form their master curve. The master curve plotted by this method is compared with the master curve obtained from the standard four-point bending test, and it is concluded that the proposed method is able to produce a master curve similar to the master curve of the standard method. Therefore, the proposed method has the potential to replace the standard stiffness tests. Furthermore, the standard stiffness methods usually conduct experiments up to the maximum frequency of 30 Hz. However, the proposed method can provide accurate complex modulus at high frequencies. This makes an accurate comparison between the properties of the asphalt mixtures in high frequencies and the development of more accurate theoretical models for simulation of specimens possible.

Lime Treatment of Coal Bottom Ash for Use in Road Pavements: Application to El Jadida Zone in Morocco.

Industrial waste causes environmental, economic, and social problems. In Morocco, the Jorf Lasfar Thermal Power Station produces two types of coal ash with enormous quantities: fly ash (FA) and Bottom ash (BA). FA is recovered in cement while BA is stored in landfills. To reduce the effects of BA disposal in landfills, several experimental studies have tested the possibility of their recovery in the road construction, especially as a subbase. In the first phase of this study, the BA underwent a physicochemical and geotechnical characterization. The results obtained show that the BA should be treated to improve its mechanical properties. The most commonly used materials are lime and cement. In the selected low-cost treatment, which is the subject of the second phase of the study, lime is used to improve the low pozzolanicity of BA while calcarenite sand is used to increase the compactness. Several mixtures containing BA, lime, and calcarenite sand were prepared. Each of these mixtures was compacted in modified Proctor molds and then subjected to a series of tests to study the following characteristics: compressive strength, dry and wet California Bearing Ratio (CBR), dry density and swelling. The composition of each mixture was based on an experimental design approach. The results show that the values of the compressive strength, the dry density, and the CBR index have increased after treatment, potentially leading to a valorization of the treated BA for use in a subbase.

Reuse of bituminous pavements: A mini-review of research, regulations and modelling.

Bituminous pavement can be recycled - even multiple times - by reusing it in new bituminous mixtures. If the mechanical properties of the binder get worse, this reclaimed asphalt is often used in the sub-structure of the road. Apparently, up till now, no end-of-life phase exists for the material. Actually, defining the end-of-life and the end-of-waste stage of a material is important for life cycle assessment modelling. Various standards and scientific studies on modelling life cycle assessment are known, but the crucial stages are not yet defined for reclaimed asphalt pavement. Unlike for iron, steel and aluminium scrap, at this moment, no legislative end-of-waste criteria for aggregates are formulated by the European Commission. More research is necessary in order to develop valuable end-of-life criteria for aggregates. This contribution is a mini-review article of the current regulations, standards and studies concerning end-of-life and end-of-waste of reclaimed asphalt pavement. The existing methodology in order to define end-of-waste criteria, a case study on aggregates and the argumentation used in finished legislative criteria are the basis to clarify some modelling issues for reclaimed asphalt material. Hence, this contribution elucidates the assignment of process environmental impacts to a life cycle stage as defined by EN15804, that is, end-of-life stage (C) and the supplementary information Module D with benefits and loads beyond the system boundary.