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1.
Water Sci Technol ; 81(8): 1749-1756, 2020 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-32644967

RESUMO

Regulatory water quality limits are extended from the wastewater resource recovery facility (WRRF) to the sewer system. It is thus necessary to properly integrate those systems for the evaluation of the overall emissions to the receiving water. The integration of the sewer system and the WRRF, however, leaves us with multiple potential options to reduce these emissions. The proposed approach builds on previous research using global sensitivity analysis (GSA) as a screening method for available control handles. It considers parameter and input uncertainty to select control handles that generate large benefits even if the model differs from reality. Results from a real-life case study indicate that the three top-rated handles are comparably effective for all considered uncertainty and variability scenarios. But the results also showed that this does not apply to lower-rated handles.


Assuntos
Modelos Teóricos , Águas Residuárias , Incerteza , Água , Qualidade da Água
2.
Water Sci Technol ; 78(5-6): 1400-1406, 2018 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-30388096

RESUMO

Grit causes problems in water resource recovery facilities (WRRFs): clogging pipes, damaging pumps, and reducing the active volume of aeration tanks and anaerobic digesters by grit accumulation. Grit chambers are built to remove these particles. However, no standardized methodology exists to characterize grit particles for grit chamber design and operation despite the large observed variability in grit composition. Therefore, this paper proposes a combination and adaptation of existing methods to sample and characterize grit particles in view of proper grit chamber design and its modelling to ultimately optimize the efficiency of this important WRRF unit process. Characteristics evaluated included particle size distribution from sieving after different sample pretreatments, organic/inorganic fractions, and density.


Assuntos
Tamanho da Partícula , Recursos Hídricos , Purificação da Água
3.
Water Res ; 113: 97-110, 2017 04 15.
Artigo em Inglês | MEDLINE | ID: mdl-28199867

RESUMO

The objective of this paper is to report the effects that control/operational strategies may have on plant-wide phosphorus (P) transformations in wastewater treatment plants (WWTP). The development of a new set of biological (activated sludge, anaerobic digestion), physico-chemical (aqueous phase, precipitation, mass transfer) process models and model interfaces (between water and sludge line) were required to describe the required tri-phasic (gas, liquid, solid) compound transformations and the close interlinks between the P and the sulfur (S) and iron (Fe) cycles. A modified version of the Benchmark Simulation Model No. 2 (BSM2) (open loop) is used as test platform upon which three different operational alternatives (A1, A2, A3) are evaluated. Rigorous sensor and actuator models are also included in order to reproduce realistic control actions. Model-based analysis shows that the combination of an ammonium ( [Formula: see text] ) and total suspended solids (XTSS) control strategy (A1) better adapts the system to influent dynamics, improves phosphate [Formula: see text] accumulation by phosphorus accumulating organisms (XPAO) (41%), increases nitrification/denitrification efficiency (18%) and reduces aeration energy (Eaeration) (21%). The addition of iron ( [Formula: see text] ) for chemical P removal (A2) promotes the formation of ferric oxides (XHFO-H, XHFO-L), phosphate adsorption (XHFO-H,P, XHFO-L,P), co-precipitation (XHFO-H,P,old, XHFO-L,P,old) and consequently reduces the P levels in the effluent (from 2.8 to 0.9 g P.m-3). This also has an impact on the sludge line, with hydrogen sulfide production ( [Formula: see text] ) reduced (36%) due to iron sulfide (XFeS) precipitation. As a consequence, there is also a slightly higher energy production (Eproduction) from biogas. Lastly, the inclusion of a stripping and crystallization unit (A3) for P recovery reduces the quantity of P in the anaerobic digester supernatant returning to the water line and allows potential struvite ( [Formula: see text] ) recovery ranging from 69 to 227 kg.day-1 depending on: (1) airflow (Qstripping); and, (2) magnesium ( [Formula: see text] ) addition. All the proposed alternatives are evaluated from an environmental and economical point of view using appropriate performance indices. Finally, some deficiencies and opportunities of the proposed approach when performing (plant-wide) wastewater treatment modelling/engineering projects are discussed.


Assuntos
Fósforo/química , Águas Residuárias , Fosfatos/química , Esgotos/química , Eliminação de Resíduos Líquidos
4.
Water Sci Technol ; 71(5): 700-8, 2015.
Artigo em Inglês | MEDLINE | ID: mdl-25768216

RESUMO

Complete mixing is hard to achieve in large bioreactors in wastewater treatment plants. This often leads to a non-uniform distribution of components such as dissolved oxygen and, hence, the process rates depend on them. Furthermore, when these components are used as input for a controller, the location of the sensor can potentially affect the control action. In this contribution, the effect of sensor location and the choice of setpoint on the controller performance were examined for a non-homogeneously mixed pilot bioreactor described by a compartmental model. The impacts on effluent quality and aeration cost were evaluated. It was shown that a dissolved oxygen controller with a fixed setpoint performs differently as a function of the location of the sensor. When placed in a poorly mixed location, the controller increases the aeration intensity to its maximum capacity leading to higher aeration costs. When placed just above the aerated zone, the controller decreases the aeration rate resulting in lower dissolved oxygen concentrations in the remainder of the system, compromising effluent quality. In addition to the location of the sensor, the selection of an appropriate setpoint also impacts controller behavior. This suggests that mixing behavior of bioreactors should be better quantified for proper sensor location and controller design.


Assuntos
Reatores Biológicos , Modelos Teóricos , Oxigênio/análise , Eliminação de Resíduos Líquidos/métodos , Eliminação de Resíduos Líquidos/instrumentação , Águas Residuárias
5.
Water Sci Technol ; 69(7): 1373-85, 2014.
Artigo em Inglês | MEDLINE | ID: mdl-24718326

RESUMO

Key developments of instrumentation, control and automation (ICA) applications in wastewater systems during the past 40 years are highlighted in this paper. From the first ICA conference in 1973 through to today there has been a tremendous increase in the understanding of the processes, instrumentation, computer systems and control theory. However, many developments have not been addressed here, such as sewer control, drinking water treatment and water distribution control. It is hoped that this review can stimulate new attempts to more effectively apply control and automation in water systems in the coming years.


Assuntos
Automação/história , Gerenciamento de Resíduos/história , História do Século XX , História do Século XXI , Londres , Águas Residuárias
6.
Water Sci Technol ; 68(1): 1-15, 2013.
Artigo em Inglês | MEDLINE | ID: mdl-23823534

RESUMO

As the work of the IWA Task Group on Benchmarking of Control Strategies for wastewater treatment plants (WWTPs) is coming to an end, it is essential to disseminate the knowledge gained. For this reason, all authors of the IWA Scientific and Technical Report on benchmarking have come together to provide their insights, highlighting areas where knowledge may still be deficient and where new opportunities are emerging, and to propose potential avenues for future development and application of the general benchmarking framework and its associated tools. The paper focuses on the topics of temporal and spatial extension, process modifications within the WWTP, the realism of models, control strategy extensions and the potential for new evaluation tools within the existing benchmark system. We find that there are major opportunities for application within all of these areas, either from existing work already being done within the context of the benchmarking simulation models (BSMs) or applicable work in the wider literature. Of key importance is increasing capability, usability and transparency of the BSM package while avoiding unnecessary complexity.


Assuntos
Benchmarking , Modelos Teóricos , Eliminação de Resíduos Líquidos
7.
Water Sci Technol ; 67(1): 1-15, 2013.
Artigo em Inglês | MEDLINE | ID: mdl-23128615

RESUMO

This paper provides a comprehensive summary on modelling of micro-pollutants' (MPs) fate and transport in wastewater. It indicates the motivations of MP modelling and summarises and illustrates the current status. Finally, some recommendations are provided to improve and diffuse the use of such models. In brief, we conclude that, in order to predict the contaminant removal in centralised treatment works, considering the dramatic improvement in monitoring and detecting MPs in wastewater, more mechanistic approaches should be used to complement conventional, heuristic and other fate models. This is crucial, as regional risk assessments and model-based evaluations of pollution discharge from urban areas can potentially be used by decision makers to evaluate effluent quality regulation, and assess upgrading requirements, in the future.


Assuntos
Modelos Teóricos , Eliminação de Resíduos Líquidos/métodos , Poluentes Químicos da Água/química , Anaerobiose , Reatores Biológicos , Cidades , Monitoramento Ambiental , União Europeia , América do Norte , Medição de Risco , Eliminação de Resíduos Líquidos/legislação & jurisprudência , Xenobióticos/química
8.
Biotechnol Bioeng ; 110(1): 24-46, 2013 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-22886494

RESUMO

This work critically reviews modeling concepts for standard activated sludge wastewater treatment processes (e.g., hydrolysis, growth and decay of organisms, etc.) for some of the most commonly used models. Based on a short overview on the theoretical biochemistry knowledge this review should help model users to better understand (i) the model concepts used; (ii) the differences between models, and (iii) the limits of the models. The seven analyzed models are: (1) ASM1; (2) ASM2d; (3) ASM3; (4) ASM3 + BioP; (5) ASM2d + TUD; (6) Barker & Dold model; and (7) UCTPHO+. Nine standard processes are distinguished and discussed in the present work: hydrolysis; fermentation; ordinary heterotrophic organisms (OHO) growth; autotrophic nitrifying organisms (ANO) growth; OHO & ANO decay; poly-hydroxyalkanoates (PHA) storage; polyphosphate (polyP) storage; phosphorus accumulating organisms PAO) growth; and PAO decay. For a structured comparison, a new schematic representation of these processes is proposed. Each process is represented as a reaction with consumed components on the left of the figure and produced components on the right. Standardized icons, based on shapes and color codes, enable the representation of the stoichiometric modeling concepts and kinetics. This representation allows highlighting the conceptual differences of the models, and the level of simplification between the concepts and the theoretical knowledge. The model selection depending on their theoretical limitations and the main research needs to increase the model quality are finally discussed.


Assuntos
Modelos Biológicos , Esgotos , Eliminação de Resíduos Líquidos , Fermentação , Concentração de Íons de Hidrogênio , Hidrólise , Fósforo/química , Purificação da Água
9.
Water Sci Technol ; 66(11): 2483-95, 2012.
Artigo em Inglês | MEDLINE | ID: mdl-23032782

RESUMO

A benchmark simulation model, which includes a wastewater treatment plant (WWTP)-wide model and a rising main sewer model, is proposed for testing mitigation strategies to reduce the system's greenhouse gas (GHG) emissions. The sewer model was run to predict methane emissions, and its output was used as the WWTP model input. An activated sludge model for GHG (ASMG) was used to describe nitrous oxide (N(2)O) generation and release in activated sludge process. N(2)O production through both heterotrophic and autotrophic pathways was included. Other GHG emissions were estimated using empirical relationships. Different scenarios were evaluated comparing GHG emissions, effluent quality and energy consumption. Aeration control played a clear role in N(2)O emissions, through concentrations and distributions of dissolved oxygen (DO) along the length of the bioreactor. The average value of N(2)O emission under dynamic influent cannot be simulated by a steady-state model subjected to a similar influent quality, stressing the importance of dynamic simulation and control. As the GHG models have yet to be validated, these results carry a degree of uncertainty; however, they fulfilled the objective of this study, i.e. to demonstrate the potential of a dynamic system-wide modelling and benchmarking approach for balancing water quality, operational costs and GHG emissions.


Assuntos
Pegada de Carbono , Metano , Modelos Teóricos , Óxido Nitroso , Gerenciamento de Resíduos/normas , Benchmarking , Análise da Demanda Biológica de Oxigênio , Oxigênio
10.
Water Sci Technol ; 65(12): 2148-53, 2012.
Artigo em Inglês | MEDLINE | ID: mdl-22643409

RESUMO

Mass balancing is a widely used tool for data quality control in wastewater treatment. It can effectively detect systematic errors in data. To overcome the limitations of the mean balancing error as a measure of data quality, a well established method for statistical process control (the CUSUM chart) is adopted for application on the error vector of balancing data. Two examples show how time periods with stable low mass balancing errors can be detected by the method. The detectability of such time periods depends on the variability of the balancing error which is an important measure for the precision of the data.


Assuntos
Controle de Qualidade , Poluentes da Água/isolamento & purificação
11.
Water Sci Technol ; 65(9): 1624-31, 2012.
Artigo em Inglês | MEDLINE | ID: mdl-22508125

RESUMO

Life cycle assessment (LCA) allows evaluating the potential environmental impacts of a product or a service in relation to its function and over its life cycle. In past LCAs applied to wastewater treatment plants (WWTPs), the system function definition has received little attention despite its great importance. This has led to some limitations in LCA results interpretation. A new methodology to perform LCA on WWTPs is proposed to avoid those limitations. It is based on net environmental benefit (NEB) evaluation and requires assessing the potential impact of releasing wastewater without and with treatment besides assessing the impact of the WWTP's life cycle. The NEB allows showing the environmental trade-offs between avoided impact due to wastewater treatment and induced impact by the WWTP's life cycle. NEB is compared with a standard LCA through the case study of a small municipal WWTP consisting of facultative aerated lagoons. The NEB and standard LCA show similar results for impact categories solely related to the WWTP's life cycle but differ in categories where wastewater treatment environmental benefit is accounted for as NEB considers influent wastewater quality whereas standard LCA does not.


Assuntos
Monitoramento Ambiental/métodos , Eliminação de Resíduos Líquidos/métodos , Poluentes Atmosféricos/química , Cidades , Meio Ambiente , Efeito Estufa , Metais Pesados/química , Quebeque , Poluentes Químicos da Água
12.
Water Sci Technol ; 65(5): 823-32, 2012.
Artigo em Inglês | MEDLINE | ID: mdl-22339016

RESUMO

Stormwater is polluted by various contaminants affecting the quality of receiving water bodies. Pathogens are one of these contaminants, which have a critical effect on water use in rivers. Increasing the retention time of water in stormwater basins can lead to reduced loads of pathogens released to the rivers. In this paper a model describing the behaviour of pathogens in stormwater basins is presented including different fate processes such as decay, adsorption/desorption, settling and solar disinfection. By considering the settling velocity distribution of particles and a layered approach, this model is able to create a light intensity, and particle and pathogen concentration profile along the water depth in the basin. A strong effect of solar disinfection is discerned. The model has been used to evaluate pathogen removal efficiencies in stormwater basins. It includes a population of particle classes characterized by a distribution of settling velocities in order to be able to reproduce stormwater quality and treatment in a realistic way.


Assuntos
Tempestades Ciclônicas , Modelos Biológicos , Material Particulado/química , Microbiologia da Água , Poluição da Água/análise , Simulação por Computador , Escherichia coli/fisiologia
13.
Water Res ; 46(20): 6857-67, 2012 Dec 15.
Artigo em Inglês | MEDLINE | ID: mdl-22196044

RESUMO

Many authors have observed the influence of the settling velocity distribution on the sedimentation process in retention tanks. However, the pollutants' behaviour in such tanks is not well characterized, especially with respect to their settling velocity distribution. This paper presents a phenomenological modelling study dealing with the way by which the settling velocity distribution of particles in combined sewage changes between entering and leaving an off-line retention tank. The work starts from a previously published model (Lessard and Beck, 1991) which is first implemented in a wastewater management modelling software, to be then tested with full-scale field data for the first time. Next, its performance is improved by integrating the particle settling velocity distribution and adding a description of the resuspension due to pumping for emptying the tank. Finally, the potential of the improved model is demonstrated by comparing the results for one more rain event.


Assuntos
Material Particulado , Eliminação de Resíduos Líquidos/métodos , Poluentes da Água , Simulação por Computador , Modelos Teóricos , Fatores de Tempo
14.
Water Sci Technol ; 64(4): 930-44, 2011.
Artigo em Inglês | MEDLINE | ID: mdl-22097082

RESUMO

Biofilm models are valuable tools for the design and evaluation of biofilm-based processes despite several uncertainties including the dynamics and rate of biofilm detachment, concentration gradients external to the biofilm surface, and undefined biofilm reactor model calibration protocol. The present investigation serves to (1) systematically evaluate critical biofilm model assumptions and components and (2) conduct a sensitivity analysis with the aim of identifying parameter subsets for biofilm reactor model calibration. AQUASIM was used to describe submerged-completely mixed combined carbon oxidation and nitrification IFAS and MBBR systems, and tertiary nitrification and denitrification MBBRs. The influence of uncertainties in model parameters on relevant model outputs was determined for simulated scenarios by means of a local sensitivity analysis. To obtain reasonable simulation results for partially penetrated biofilms that accumulated a substantial thickness in the modelled biofilm reactor (e.g. 1,000 microm), an appropriate biofilm discretization was applied to properly model soluble substrate concentration gradients and, consistent with the assumed mechanism for describing biofilm biomass distribution, biofilm biomass spatial variability. The MTBL thickness had a significant impact on model results for each of the modelled reactor configurations. Further research is needed to develop a mathematical description (empirical or otherwise) of the MTBL thickness that is relevant to modern biofilm reactors. No simple recommendations for a generally applicable calibration protocol are provided, but sensitivity analysis has been proven to be a powerful tool for the identification of highly sensitive parameter subsets for biofilm (reactor) model calibration.


Assuntos
Biofilmes , Modelos Teóricos , Calibragem , Cinética
15.
Water Sci Technol ; 63(10): 2164-82, 2011.
Artigo em Inglês | MEDLINE | ID: mdl-21977635

RESUMO

This study aims at synthesizing experiences in the practical application of ASM type models. The information is made easily accessible to model users by creating a database of modelling projects. This database includes answers to a questionnaire that was sent out to model users in 2008 to provide inputs for a Scientific and Technical Report of the IWA Task Group on Good Modelling Practice - Guidelines for use of activated sludge models, and a literature review on published modelling projects. The database is analysed to determine which biokinetic model parameters are usually changed by modellers, in which ranges, and what values are typically used for seven selected activated sludge models. These results should help model users in the calibration step, by providing typical parameter values as a starting point and ranges as a guide. However, the proposed values should be used with great care since they are the result of averaging practical experience and not taking into account specific parameter correlations.


Assuntos
Bases de Dados como Assunto , Modelos Teóricos , Esgotos/química , Esgotos/microbiologia
16.
Water Sci Technol ; 64(9): 1898-905, 2011.
Artigo em Inglês | MEDLINE | ID: mdl-22020485

RESUMO

Theoretical studies have shown that discharges from retention tanks could have a negative impact on the WWTP's (Wastewater Treatment Plant) effluent. Characterization of such discharges is necessary to better understand these impacts. This study aims at: (1) characterizing water quality during emptying of a tank; and (2) characterizing the temporal variation of settling velocities of the waters released to the WWTP. Two full-scale sampling campaigns (18 rain events) have been realized in Quebec City and laboratory analyses have shown a wide variability of total suspended solids (TSS) and Chemical Oxygen Demand (COD) concentrations in the water released from the tank. Suspended solids seem to settle quickly because they are only found in large amounts during the first 15 min of pumping to the WWTP. These solids are hypothesized to come from the pumping in which solids remained after a previous event. When these solids are evacuated, low TSS containing waters are pumped from the retention tank. A second concentration peak occurs at the end of the emptying period when the tank is cleaned with wash water. Finally, settling velocity studies allowed characterizing combined sewer wastewaters by separating three main fractions of pollutants which correspond to the beginning, middle and end of emptying. In most cases, it is noticed that particle settling velocities increase as the pollutant load increases.


Assuntos
Esgotos/análise , Eliminação de Resíduos Líquidos , Purificação da Água/instrumentação , Purificação da Água/métodos , Análise da Demanda Biológica de Oxigênio , Fracionamento Químico , Cidades , Geografia , Quebeque , Chuva , Qualidade da Água
17.
Biotechnol Prog ; 27(6): 1522-34, 2011.
Artigo em Inglês | MEDLINE | ID: mdl-21916026

RESUMO

An experimental protocol to evaluate the structured biomass model proposed by Lavallée (Lavallée, Lessard, and Vanrolleghem, J Environ Eng Sci 2005;4:517-532) is presented. The protocol was devised to induce transient behavior and characterize the evolution of several internal biomass components. The proposed model is based on biochemical principles, and was fitted to the collected data. In these experiments, it was observed that filling the storage capacity of cells leads to special transient behavior, including a temporarily reduced metabolic activity. The model-based interpretation of the results showed that the observed transient behavior can be explained by cross-regulation of carbon and nitrogen metabolism. Hence, according to an extensive literature review, the cross-regulation of carbon and nitrogen can be used to model some observed transient behaviors and regulation of the storage process in activated sludge.


Assuntos
Bactérias/metabolismo , Carbono/metabolismo , Nitrogênio/metabolismo , Esgotos/microbiologia , Bactérias/genética , Bactérias/crescimento & desenvolvimento , Biomassa , Reatores Biológicos/microbiologia , Modelos Biológicos
18.
Water Sci Technol ; 62(9): 1967-74, 2010.
Artigo em Inglês | MEDLINE | ID: mdl-21045320

RESUMO

The COST/IWA Benchmark Simulation Model No 1 (BSM1) has been available for almost a decade. Its primary purpose has been to create a platform for control strategy benchmarking of activated sludge processes. The fact that the research work related to the benchmark simulation models has resulted in more than 300 publications worldwide demonstrates the interest in and need of such tools within the research community. Recent efforts within the IWA Task Group on "Benchmarking of control strategies for WWTPs" have focused on an extension of the benchmark simulation model. This extension aims at facilitating control strategy development and performance evaluation at a plant-wide level and, consequently, includes both pretreatment of wastewater as well as the processes describing sludge treatment. The motivation for the extension is the increasing interest and need to operate and control wastewater treatment systems not only at an individual process level but also on a plant-wide basis. To facilitate the changes, the evaluation period has been extended to one year. A prolonged evaluation period allows for long-term control strategies to be assessed and enables the use of control handles that cannot be evaluated in a realistic fashion in the one week BSM1 evaluation period. In this paper, the finalised plant layout is summarised and, as was done for BSM1, a default control strategy is proposed. A demonstration of how BSM2 can be used to evaluate control strategies is also given.


Assuntos
Benchmarking , Arquitetura de Instituições de Saúde/métodos , Eliminação de Resíduos Líquidos/métodos , Simulação por Computador , Monitoramento Ambiental
19.
Water Sci Technol ; 62(7): 1614-22, 2010.
Artigo em Inglês | MEDLINE | ID: mdl-20935380

RESUMO

Integrated urban water system (IUWS) modeling aims at assessing the quality of the surface water receiving the urban emissions through sewage treatment plants, combined sewer overflows (CSOs) and stormwater drainage systems. However, some micropollutants tend to appear in more than one environmental medium (air, water, sediment, soil, groundwater, etc.). In this work, a multimedia fate and transport model (MFTM) is "wrapped around" a dynamic IUWS model for organic micropollutants to enable integrated environmental assessment. The combined model was tested on a hypothetical catchment using two scenarios: on the one hand a reference scenario with a combined sewerage system and on the other hand a stormwater infiltration pond scenario, as an example of a sustainable urban drainage system (SUDS). A case for Bis(2-ethylhexyl) phthalate (DEHP) was simulated and resulted in reduced surface water concentrations for the latter scenario. However, the model also showed that this was at the expense of increased fluxes to air, groundwater and infiltration pond soil. The latter effects are generally not included in IUWS models, whereas MTFMs usually do not consider dynamic surface water concentrations,; hence the combined model approach provides a better basis for integrated environmental assessment of micropollutants' fate in urban environments.


Assuntos
Poluição Ambiental , Modelos Teóricos , Poluentes Químicos da Água , Cidades , Dietilexilftalato/química , Drenagem Sanitária
20.
Water Sci Technol ; 61(4): 825-39, 2010.
Artigo em Inglês | MEDLINE | ID: mdl-20182061

RESUMO

The quality of simulation results can be significantly affected by errors in the published model (typing, inconsistencies, gaps or conceptual errors) and/or in the underlying numerical model description. Seven of the most commonly used activated sludge models have been investigated to point out the typing errors, inconsistencies and gaps in the model publications: ASM1; ASM2d; ASM3; ASM3 + Bio-P; ASM2d + TUD; New General; UCTPHO+. A systematic approach to verify models by tracking typing errors and inconsistencies in model development and software implementation is proposed. Then, stoichiometry and kinetic rate expressions are checked for each model and the errors found are reported in detail. An attached spreadsheet (see http://www.iwaponline.com/wst/06104/0898.pdf) provides corrected matrices with the calculations of all stoichiometric coefficients for the discussed biokinetic models and gives an example of proper continuity checks.


Assuntos
Esgotos , Algoritmos , Biodegradação Ambiental , Reatores Biológicos , Simulação por Computador , Cinética , Modelos Teóricos , Reprodutibilidade dos Testes , Software , Temperatura , Eliminação de Resíduos Líquidos/métodos , Microbiologia da Água , Poluentes Químicos da Água/isolamento & purificação , Purificação da Água/métodos
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