RESUMO
We consider an out-of-equilibrium one-dimensional model for two electrical double-layers. With a combination of exact calculations and Brownian dynamics simulations, we compute the relaxation time (τ) for an electroneutral salt-free suspension, made up of two fixed colloids, withNneutralizing mobile counterions. ForNodd, the two double-layers never decouple, irrespective of their separationL; this is the regime of like-charge attraction, whereτexhibits a diffusive scaling inL2for largeL. On the other hand, for evenN,Lno longer is the relevant length scale for setting the relaxation time; this role is played by the Bjerrum length. This leads to distinctly different dynamics: forNeven, thermal effects are detrimental to relaxation, increasingτ, while they accelerate relaxation forNodd. Finally, we also show that the mean-field theory is recovered for largeNand moreover, that it remains an operational treatment down to relatively small values ofN(N> 3).
RESUMO
We study a one-dimensional Coulomb system, where two charged colloids are neutralized by a collection of point counterions, with global neutrality. With temperature being given, two situations are addressed: Either the colloids are kept at fixed positions (canonical ensemble) or the force acting on the colloids is fixed (isobaric-isothermal ensemble). The corresponding partition functions are worked out exactly, in view of determining which arrangement of counterions is optimal. How many counterions should be in the confined segment between the colloids? For the remaining ions outside, is there a left-right symmetry breakdown? We evidence a cascade of transitions as system size is varied in the canonical treatment or as pressure is increased in the isobaric formulation.
RESUMO
The world coffee consumption has been growing for its appreciated taste and its beneficial effects on health. The residual biomass of coffee, originated in the food industry after oil extraction from coffee beans, called coffee beans residual press cake, has attracted interest as a source of compounds with antioxidant activity. This study investigated the chemical composition of aqueous extracts of coffee beans residual press cake (AE), their antioxidant activity, and the effect of topical application on the skin wound healing, in animal model, of hydrogels containing the AE, chlorogenic acid (CGA), allantoin (positive control), and carbopol (negative control). The treatments' performance was compared by measuring the reduction of the wound area, with superior result (p < 0.05) for the green coffee AE (78.20%) with respect to roasted coffee AE (53.71%), allantoin (70.83%), and carbopol (23.56%). CGA hydrogels reduced significantly the wound area size on the inflammatory phase, which may be associated with the well known antioxidant and anti-inflammatory actions of that compound. The topic use of the coffee AE studied improved the skin wound healing and points to an interesting biotechnological application of the coffee bean residual press cake.