Local T1-T2 distribution measurements in porous media.

A novel slice-selective T1-T2 measurement is proposed to measure spatially resolved T1-T2 distributions. An adiabatic inversion pulse is employed for slice-selection. The slice-selective pulse is able to select a quasi-rectangular slice, on the order of 1 mm, at an arbitrary position within the sample.The method does not employ conventional selective excitation in which selective excitation is often accomplished by rotation of the longitudinal magnetization in the slice of interest into the transverse plane, but rather a subtraction based on CPMG data acquired with and without adiabatic inversion slice selection. T1 weighting is introduced during recovery from the inversion associated with slice selection. The local T1-T2 distributions measured are of similar quality to bulk T1-T2 measurements. The new method can be employed to characterize oil-water mixtures and other fluids in porous media. The method is beneficial when a coarse spatial distribution of the components is of interest.

Local diffusion and diffusion-T2 distribution measurements in porous media.

Slice-selective pulsed field gradient (PFG) and PFG-T2 measurements are developed to measure spatially-resolved molecular diffusion and diffusion-T2 distributions. A spatially selective adiabatic inversion pulse was employed for slice-selection. The slice-selective pulse is able to select a coarse slice, on the order of 1cm, at an arbitrary position in the sample. The new method can be employed to characterize oil-water mixtures in porous media. The new technique has an inherent sensitivity advantage over phase encoding imaging based methods due to signal being localized from a thick slice. The method will be advantageous for magnetic resonance of porous media at low field where sensitivity is problematic. Experimental CPMG data, following PFG diffusion measurement, were compromised by a transient ΔB0(t) field offset. The off resonance effects of ΔB0(t) were examined by simulation. The ΔB0 offset artifact in D-T2 distribution measurements may be avoided by employing real data, instead of magnitude data.

A high-pressure metallic core holder for magnetic resonance based on Hastelloy-C.

A metallic core holder, fabricated from non-magnetic Hastelloy-C276, has been designed for Magnetic Resonance (MR) and Magnetic Resonance Imaging (MRI) of core plug samples at high pressures and temperatures. Core plug samples, 1.5″ in diameter and 2″ in length, can be tested in the core holder at elevated pressures and temperatures, up to 5000 psi and 80 °C. These are conditions commonly found in petroleum reservoirs. A radio frequency probe, which excites and detects magnetic resonance signals, was placed inside the metal vessel. Proximity to the sample improves the signal to noise ratio of the resulting measurements. The metallic core holder is positioned between the poles of a 0.2 T permanent magnet and subjected to rapidly switched magnetic field gradients as part of the imaging process. This switching induces eddy currents on the conductive core holder, which degrades the magnetic field gradient waveform in the sample space. The low electrical-conductivity of Hastelloy-C276 minimizes the duration and the magnitude of such eddy currents. A recently developed pre-equalization technique was employed to ensure that magnetic field gradient pulses, required for MRI, are near ideal in the sample space. A representative core flooding experiment was undertaken in conjunction with MR/MRI measurements.

Local T2 measurement employing longitudinal Hadamard encoding and adiabatic inversion pulses in porous media.

Band selective adiabatic inversion radio frequency pulses were employed for multi-slice T2 distribution measurements in porous media samples. Multi-slice T2 measurement employing longitudinal Hadamard encoding has an inherent sensitivity advantage over slice-by-slice local T2 measurements. The slice selection process is rendered largely immune to B1 variation by employing hyperbolic secant adiabatic inversion pulses, which simultaneously invert spins in several well-defined slices. While Hadamard encoding is well established for local spectroscopy, the current work is the first use of Hadamard encoding for local T2 measurement.

Mapping B(1)-induced eddy current effects near metallic structures in MR images: a comparison of simulation and experiment.

Magnetic resonance imaging (MRI) in the presence of metallic structures is very common in medical and non-medical fields. Metallic structures cause MRI image distortions by three mechanisms: (1) static field distortion through magnetic susceptibility mismatch, (2) eddy currents induced by switched magnetic field gradients and (3) radio frequency (RF) induced eddy currents. Single point ramped imaging with T1 enhancement (SPRITE) MRI measurements are largely immune to susceptibility and gradient induced eddy current artifacts. As a result, one can isolate the effects of metal objects on the RF field. The RF field affects both the excitation and detection of the magnetic resonance (MR) signal. This is challenging with conventional MRI methods, which cannot readily separate the three effects. RF induced MRI artifacts were investigated experimentally at 2.4 T by analyzing image distortions surrounding two geometrically identical metallic strips of aluminum and lead. The strips were immersed in agar gel doped with contrast agent and imaged employing the conical SPRITE sequence. B1 mapping with pure phase encode SPRITE was employed to measure the B1 field around the strips of metal. The strip geometry was chosen to mimic metal electrodes employed in electrochemistry studies. Simulations are employed to investigate the RF field induced eddy currents in the two metallic strips. The RF simulation results are in good agreement with experimental results. Experimental and simulation results show that the metal has a pronounced effect on the B1 distribution and B1 amplitude in the surrounding space. The electrical conductivity of the metal has a minimal effect.

B(1) mapping with a pure phase encode approach: quantitative density profiling.

In MRI, it is frequently observed that naturally uniform samples do not have uniform image intensities. In many cases this non-uniform image intensity is due to an inhomogeneous B1 field. The 'principle of reciprocity' states that the received signal is proportional to the local magnitude of the applied B1 field per unit current. Inhomogeneity in the B1 field results in signal intensity variations that limit the ability of MRI to yield quantitative information. In this paper a novel method is described for mapping B1 inhomogeneities based on measurement of the B1 field employing centric-scan pure phase encode MRI measurements. The resultant B1 map may be employed to correct related non-uniformities in MR images. The new method is based on acquiring successive images with systematically incremented low flip angle excitation pulses. The local image intensity variation is proportional to B1(2), which ensures high sensitivity to B1 field variations. Pure phase encoding ensures the resultant B1 field maps are free from distortions caused by susceptibility variation, chemical shift and paramagnetic impurities. Hence, the method works well in regions of space that are not accessible to other methods such as in the vicinity of conductive metallic structures, such as the RF probe itself. Quantitative density images result when the centric scan pure phase encode measurement is corrected with a relative or absolute B1 field map. The new technique is simple, reliable and robust.