Land degradation neutrality (LDN) in Rajasthan, Western India: a combined approach of pressure-state-response model and MODIS data products.

Land degradation has become a key concern worldwide due to changes in meteorological variables and human-caused activities. This study primarily focuses on the rate, impact, and pattern of land degradation in western India. In this instance, we evaluated the effectiveness of land degradation neutrality (LDN) between 2000 and 2020 using an integrative approach based on a PSR (pressure-state-response) model developed by the OECD-UNEP under the UNCCD framework. Here, we mainly used MODIS products (e.g., NDVI, PET, LULC, and NPP). Also, soil organic carbon (SOC) and climatic variables (e.g. precipitation, aridity index and soil moisture) were taken into account. These indicators were analysed using the Google Earth Engine (GEE) code editor platform, and post-processing was done through Q-GIS software. The analysed parameters indicate that the NDVI and NPP values are + 0.20 to + 0.3 and 4.27 × 109 to 7.74 × 109 kg Cm-2, respectively. However, overall precipitation and soil moisture depicted a positive trend, and the aridity index adeptly followed a negative trend. Hence, the land degradation rate has increased in the north-western region besides the Aravalli range and neutrality work in the southwest part of the study area. The overall land degradation trend is negative over the last two decades. Therefore, this study anticipates the policymakers and government bodies to understand about land degradation of western India.

Importance of weak interactions in developing 1,3-bis(4,6-dimethyl-1H-nicotinonitrile-1-yl)1,3-dioxy propane polymorphs.

The structure of 1,3-bis(4,6-dimethyl-1H-nicotinonitrile-1-yl)1,3-dioxy propane polymorphs has been characterized by X-ray diffraction, FT-IR, 1H and 13C NMR spectroscopies. The influence of intra and intermolecular weak interactions is thoroughly studied in solid state using single crystal X-ray diffraction and FT-IR. These polymorphs belong to monoclinic space group 'P2(1/n)' and 'P2(1/c)'. These polymorphs have C-H⋯n (lone pair), hydrogen bonds, C-N⋯π, C-H⋯π and π⋯π intermolecular non-covalent interactions. These polymorphs are the result of weak interactions and solvent used in crystallization. The FT-IR spectra have been recorded in the solid phase and NMR has been recorded in solvent. The optimized geometry has been calculated by B3LYP methods using different basis sets. The FT-IR and NMR spectra of 1st polymorphs has been calculated at B3LYP/6-31G (d) level. The scaled theoretical wave number showed good agreement with the experimental values. These two polymorphs as well as other stereomers are studied by DFT calculations.