RESUMO
The spread of additive manufacturing techniques in the prototyping and realization of high-frequency applications renewed the interest in the characterization of the electromagnetic properties of both dielectric and conductive materials, as well as the design of new versatile measurement techniques. In this framework, a new configuration of a dielectric-loaded resonator is presented. Its optimization, realization, and use are presented. A measurement repeatability of about one order of magnitude lower than the commonly found values (10-3 on the Q-factor and 15×10-6 on the resonance frequency, given in terms of the relative standard deviations of repeated measurements) was reached thanks to the design of a closed resonator in which the samples can be loaded without disassembling the whole measurement fixture. The uncertainty levels, the ease of use, and the versatility of the realized system make its use of potential interest in numerous scenarios.
RESUMO
We present the multifrequency measurements of the surface resistance of spark-plasma-sintered MgB2 performed through a dielectric loaded resonator operating at 16.5 and 26.7 GHz. By normally applying magnetic fields ≤1.2 T to the sample surface, we drove it in the mixed state. By means of data-rooted analysis, we found that the sample vortex dynamics could be fully described within a single-component approach. Pinning phenomena were present and characterized by a depinning frequency smaller than the measurement ones. The multiband nature of the superconductor emerged in the flux-flow resistivity, whose field dependence could be interpreted well within theoretical models. By exploiting them, the upper critical field was extracted in the low-temperature range, which exhibited a consistent temperature trend with the values obtained at the onset of the resistive transition near Tc, and was well in line with literature data on other polycrystalline samples.
RESUMO
The root mean square surface roughness Rq of metals is detrimental in several microwave applications. Rq characterization methods are thus largely used and of great interest. In this work, a new dielectric loaded resonator (DR) design is proposed to evaluate the surface resistance variations of samples with different Rq. The new design is thought to make the measurement accuracy, usually strongly affected by the measurement repeatability, suitable for this study. We analyze the measurement method's sensitivity and accuracy in order to assess the possibility of using this new DR design for highly accurate surface resistance measurements sensitive to Rq variations.
Assuntos
Metais , Micro-OndasRESUMO
A new series of Fischer carbenes have been synthetized and examined as hole-transporting or electron-transporting layers (HTLs or ETLs) in the fabrication of organic solar cells (OSCs). The synthesis of three Fischer aminocarbene complexes with the general formula [Cr(CO)5{C(NHCH2)Ar}] (Ar = 2-pyridyl (3a), 3-pyridyl (3b) and 4-pyridyl (3c)) is reported. The molecular structure of complex 3b has been confirmed by X-ray analysis. In order to study the possible applications of the three Fischer aminocarbenes in OSCs, thin films of these complexes were prepared using a vacuum deposition process. These organometallic films were chemically and morphologically characterized by IR spectroscopy, SEM, AFM and XRD. According to the IR and Tauc analysis, the vacuum deposition process generates thin films free of impurities with an activation energy of 4.0, 2.7 and 2.1 eV for 3a, 3b y 3c, respectively. The UV-vis spectra of the amorphous aminocarbene films show that they are practically transparent to the visible radiation of the electromagnetic spectrum. This is due to the fact that their absorption is located mainly in the ultraviolet range. Two OSCs with bulk-heterojunction configuration were manufactured in order to prove the use of the aminocarbenes as ETL o HTL. The aminocarbene [Cr(CO)5{C(NHCH2) 4-pyridyl}] (3c) proved to be suitable as ETL with a fill factor (FF) of 0.23 and a short circuit current density (JSC) of 1.037 mA/cm².
