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1.
Front Cardiovasc Med ; 10: 1308173, 2023.
Artigo em Inglês | MEDLINE | ID: mdl-38288054

RESUMO

Introduction: Statins remain the first-line treatment for secondary prevention of cardiovascular (CV) events, with lowering of low-density lipoprotein cholesterol (LDL-C) being their therapeutic target. Although LDL-C reduction significantly lowers CV risk, residual risk persists, even in patients with well-controlled LDL-C; thus, statin add-on agents that target pathways other than LDL-C, such as the omega-3 fatty acid eicosapentaenoic acid, may help to further reduce persistent CV risk in patients with established CV disease. Methods: This narrative review examines the contemporary literature assessing intermediate- and long-term event rates in patients with established CV disease treated with statins. Results: CV event rates among patients treated with statins who have established CV disease, including coronary artery disease, cerebrovascular disease, or peripheral arterial disease, accumulate over time, with a cumulative incidence of CV events reaching up to approximately 40% over 10 years. Recurrent stroke occurs in up to 19% of patients seven years after a first cerebrovascular event. Repeat revascularization and CV-related death occurs in up to 38% and 33% of patients with peripheral artery disease after three years, respectively. Discussion: Additional treatment strategies, such as eicosapentaenoic acid, are needed to reduce persistent CV risk in patients with established CV disease treated with statins.

2.
Indian J Med Res ; 148(5): 496-502, 2018 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-30666976

RESUMO

Vitamin A deficiency (VAD) among 1-5 yr old children is reported to be widely prevalent in Southeast Asia and some parts of Africa. It is the leading cause of preventable blindness in young children in the low-income countries in the world. Children even with milder signs of VAD have higher risk of morbidity and mortality. Inadequate dietary intakes of vitamin A with poor bioavailability associated with frequent infections are the primary contributory factors. Currently available approaches to control VAD are ensuring adequate intakes of vitamin A in daily diets, fortification of foods consumed regularly particularly among the low-income communities and periodic administration of massive dose of vitamin A supported by public health interventions and reinforced by behaviour change communication. Under the National Programme in India, six monthly administration of mega dose of vitamin A to 6-59 month old children has been implemented since 1970, to prevent particularly blindness due to VAD and control hypovitaminosis A. Despite inadequate coverage and poor implementation of the programme, blindness due to VAD in children has almost disappeared, though subclinical VAD is still widely prevalent. Based on the results of meta-analysis of eight trials, which indicated that vitamin A supplementation to children aged 6-59 months reduced child mortality rates by about 23 per cent, the World Health Organization made a strong recommendation that in areas with VAD as a public health problem, vitamin A supplementation should be given to infants and children of 6-59 months of age as a public health intervention to reduce child morbidity and improve child survival. At present, in India, there is a need for change in policy with respect to the national programme to opt for targeted instead of universal distribution. However, NITI (National Institution for Transforming India) Aayog, which formulates policies and provides technical support to the Government of India, recommends strengthening of the National Programme for control of VAD through six monthly vitamin A supplementation along with health interventions. Eventually, the goal is to implement food based and horticulture-based interventions harmonizing with public health measures, food fortification and capacity building of functionaries for elimination of VAD.


Assuntos
Cegueira , Programas Nacionais de Saúde/organização & administração , Deficiência de Vitamina A , Vitamina A/farmacologia , Cegueira/etiologia , Cegueira/prevenção & controle , Criança , Suplementos Nutricionais , Humanos , Índia/epidemiologia , Necessidades Nutricionais , Prevalência , Deficiência de Vitamina A/complicações , Deficiência de Vitamina A/epidemiologia , Deficiência de Vitamina A/terapia , Vitaminas/farmacologia
3.
Adv Colloid Interface Sci ; 242: 35-58, 2017 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-28256201

RESUMO

Adsorption is a facile, economic, eco-friendly and low-energy requiring technology that aims to separate diverse compounds (ions and molecules) from one phase to another using a wide variety of adsorbent materials. To date, this technology has been used most often for removal/recovery of pollutants from aqueous solutions; however, emerging post-sorption technologies are now enabling the manufacture of value-added key adsorption products that can subsequently be used for (i) fertilizers, (ii) catalysis, (iii) carbonaceous metal nanoparticle synthesis, (iv) feed additives, and (v) biologically active compounds. These new strategies ensure the sustainable valorisation of post-sorption materials as an economically viable alternative to the engineering of other green chemical products because of the ecological affability, biocompatibility, and widespread accessibility of post-sorption materials. Fertilizers and feed additives manufactured using sorption technology contain elements such as N, P, Cu, Mn, and Zn, which improve soil fertility and provide essential nutrients to animals and humans. This green and effective approach to managing post-sorption materials is an important step in reaching the global goals of sustainability and healthy human nutrition. Post-sorbents have also been utilized for the harvesting of metal nanoparticles via modern catalytic pyrolysis techniques. The resulting materials exhibited a high surface area (>1000m2/g) and are further used as catalysts and adsorbents. Together with the above possibilities, energy production from post-sorbents is under exploration. Many of the vital 3E (energy, environment, and economy) problems can be addressed using post-sorption materials. In this review, we summarize a new generation of applications of post-adsorbents as value-added green chemical products. At the end of each section, scientific challenges, further opportunities, and issues related to toxicity are discussed. We believe this critical evaluation not only delivers essential contextual information to researchers in the field but also stimulates new ideas and applications to further advance post-sorbent applications.

4.
Int J Phytoremediation ; 19(6): 537-544, 2017 Jun 03.
Artigo em Inglês | MEDLINE | ID: mdl-27936895

RESUMO

Finding appropriate rooftop vegetation may improve the quality of runoff from green roofs. Portulaca grandiflora was examined as possible vegetation for green roofs. Green roof substrate was found to have low bulk density (360.7 kg/m3) and high water-holding capacity (49.4%), air-filled porosity (21.1%), and hydraulic conductivity (5270 mm/hour). The optimal substrate also supported the growth of P. grandiflora with biomass multiplication of 450.3% and relative growth rate of 0.038. Phytoextraction potential of P. grandiflora was evaluated using metal-spiked green roof substrate as a function of time and spiked substrate metal concentration. It was identified that P. grandiflora accumulated all metals (Al, Cd, Cr, Cu, Fe, Ni, Pb, and Zn) from metal-spiked green roof substrate. At the end of 40 days, P. grandiflora accumulated 811 ± 26.7, 87.2 ± 3.59, 416 ± 15.8, 459 ± 15.6, 746 ± 20.9, 357 ± 18.5, 565 ± 6.8, and 596 ± 24.4 mg/kg of Al, Cd, Cr, Cu, Fe, Ni, Pb and Zn, respectively. Results also indicated that spiked substrate metal concentration strongly influenced metal accumulation property of P. grandiflora with metal uptake increased and accumulation factor decreased with increase in substrate metal concentration. P. grandiflora also showed potential to translocate all the examined metals with translocation factor greater than 1 for Al, Cu, Fe, and Zn, indicating hyperaccumulation property.


Assuntos
Alumínio/metabolismo , Metais Pesados/metabolismo , Portulaca/metabolismo , Poluentes do Solo/metabolismo , Biodegradação Ambiental , Índia , Portulaca/crescimento & desenvolvimento , Chuva/química
5.
Environ Technol ; 37(9): 1101-9, 2016.
Artigo em Inglês | MEDLINE | ID: mdl-26512973

RESUMO

The purpose of this research was to investigate the efficiency of Dracaena marginata planted biofilters to decontaminate urban runoff. A new biofilter growth substrate was prepared using low-cost and locally available materials such as red soil, fine sand, perlite, vermiculite, coco-peat and Sargassum biomass. The performance of biofilter substrate was compared with local garden soil based on physical and water quality parameters. Preliminary analyses indicated that biofilter substrate exhibited desirable characteristics such as low bulk density (1140 kg/m(3)), high water holding capacity (59.6%), air-filled porosity (7.82%) and hydraulic conductivity (965 mm/h). Four different biofilter assemblies, with vegetated and non-vegetated systems, were examined for several artificial rain events (un-spiked and metal-spiked). Results from un-spiked artificial rain events suggested that concentrations of most of the chemical components in effluent were highest at the beginning of rain events and thereafter subsided during the subsequent rain events. Biofilter growth substrate showed superior potential over garden soil to retain metal ions such as Al, Fe, Cu, Cr, Ni, Zn, Cd and Pb during metal-spiked rain events. Significant differences were also observed between non-vegetated and vegetated biofilter assemblies in runoff quality, with the latter producing better results.


Assuntos
Dracaena/crescimento & desenvolvimento , Metais/química , Chuva/química , Solo/química , Qualidade da Água , Óxido de Alumínio/química , Silicatos de Alumínio/química , Biomassa , Sargassum/química , Dióxido de Silício/química
6.
J Environ Manage ; 160: 283-96, 2015 Sep 01.
Artigo em Inglês | MEDLINE | ID: mdl-26143501

RESUMO

For the past few decades, biosorption has been widely investigated for the removal of different contaminants in aqueous media. A number of biomasses of different genre have been identified to possess good biosorption capacity. Insights into biosorption mechanisms have been provided by various researchers in order to develop a fundamental scientific understanding of the biosorption process. However, biosorption has not been employed widely for its large-scale commercial applications. The key factors that affect the growth and evolution of biosorption as a practical technology for decontamination of wastewaters include, (1) lack of investigations on multi-component solutions and wastewaters with complex matrix effects, (2) incomplete understanding of physico-chemical characteristics of biomasses of different types, (3) lack of studies to improve the performance of biosorbents through surface functionalization, and (4) non-integration of biosorption in wastewater/water treatment plants. This critical review aims to identify and discuss the practical limitations of biosorption and provide future research directions to make biosorption a technologically viable process with emphasis on selection and modification of biomasses to suit desired treatment applications, identify appropriate operation modes for large-scale applications of biosorption, and perform techno-economic evaluation of overall biosorption processes.


Assuntos
Metais Pesados/química , Águas Residuárias/química , Poluentes Químicos da Água/química , Purificação da Água/métodos , Adsorção , Biodegradação Ambiental , Biomassa , Descontaminação , Humanos
7.
Ecotoxicol Environ Saf ; 118: 177-182, 2015 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-25938698

RESUMO

The discarded materials from different sources can be utilized as effective materials in wastewater remediation. This proposed study was aimed mainly to investigate the possibility of Effective Microorganisms based compost (EMKC), which is derived from the kitchen solid waste, as a non-conventional low cost adsorbent for the removal of malachite green from aqueous solution. Batch experiments were carried out to evaluate the optimum operating parameters like pH (2-9), initial dye concentration (50-1000mg/L), adsorbent particle size (0.6-2.36mm) and adsorbent dosage (2-12g/L). EMKC recorded maximum uptake of 136.6mg/g of MG at pH 8, initial dye concentration 1000mg/L, adsorbent particle size 1.18mm and adsorbent dosage 4g/L. Two and three parameter adsorption models were employed to describe experimental biosorption isotherm data. The results revealed that the Sips model resulted in better fit than other models. The pseudo-first and -second order models were applied to describe kinetic data, of which the pseudo-second order described experimental data better with high correlation coefficient. This investigation suggested that EMKC could be an effective and low cost material for the removal of malachite green dye from aqueous solution.


Assuntos
Bactérias/metabolismo , Eliminação de Resíduos/métodos , Corantes de Rosanilina/metabolismo , Resíduos Sólidos/análise , Adsorção , Tamanho da Partícula , Eliminação de Resíduos/instrumentação , Solo/química
8.
Environ Pollut ; 194: 121-129, 2014 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-25106048

RESUMO

The present study examines whether green roofs act as a sink or source of contaminants based on various physico-chemical parameters (pH, conductivity and total dissolved solids) and metals (Na, K, Ca, Mg, Al, Fe, Cr, Cu, Ni, Zn, Cd and Pb). The performance of green roof substrate prepared using perlite, vermiculite, sand, crushed brick, and coco-peat, was compared with local garden soil based on improvement of runoff quality. Portulaca grandiflora was used as green roof vegetation. Four different green roof configurations, with vegetated and non-vegetated systems, were examined for several artificial rain events (un-spiked and metal-spiked). In general, the vegetated green roof assemblies generated better-quality runoff with less conductivity and total metal ion concentration compared to un-vegetated assemblies. Of the different green roof configurations examined, P. grandiflora planted on green roof substrate acted as sink for various metals and showed the potential to generate better runoff.


Assuntos
Conservação dos Recursos Naturais/métodos , Materiais de Construção , Monitoramento Ambiental , Chuva , Poluentes Químicos da Água/análise , Biodegradação Ambiental , Metais/análise , Solo/química
9.
Water Res ; 63: 94-101, 2014 Oct 15.
Artigo em Inglês | MEDLINE | ID: mdl-24981747

RESUMO

Many studies worldwide have investigated the potential benefits achievable by transforming brown roofs of buildings to green roofs. However, little literature examined the runoff quality/sorption ability of green roofs. As the green roof substrate is the main component to alter the quality of runoff, this investigation raises the possibility of using a mixture of low-cost inorganic materials to develop a green roof substrate. The tested materials include exfoliated vermiculite, expanded perlite, crushed brick and sand along with organic component (coco-peat). Detailed physical and chemical analyses revealed that each of these materials possesses different characteristics and hence a mix of these materials was desirable to develop an optimal green roof substrate. Using factorial design, 18 different substrate mixes were prepared and detailed examination indicated that mix-12 exhibited desirable characteristics of green roof substrate with low bulk density (431 kg/m(3)), high water holding capacity (39.4%), air filled porosity (19.5%), and hydraulic conductivity (4570 mm/h). The substrate mix also provided maximum support to Portulaca grandiflora (380% total biomass increment) over one month of growth. To explore the leaching characteristics and sorption capacity of developed green roof substrate, a down-flow packed column arrangement was employed. High conductivity and total dissolved solids along with light metal ions (Na, K, Ca and Mg) were observed in the leachates during initial stages of column operation; however the concentration of ions ceased during the final stages of operation (600 min). Experiments with metal-spiked deionized water revealed that green roof substrate possess high sorption capacity towards various heavy metal ions (Al, Fe, Cr, Cu, Ni, Pb, Zn and Cd). Thus the developed growth substrate possesses desirable characteristics for green roofs along with high sorption capacity.


Assuntos
Conservação dos Recursos Naturais/métodos , Portulaca/crescimento & desenvolvimento , Chuva , Solo/química , Qualidade da Água , Adsorção
10.
Artigo em Inglês | MEDLINE | ID: mdl-24844899

RESUMO

In this study, in situ hybrid sand filters were designed to remove dissolved and suspended contaminants from eutrophic pond. Currently, there are no attempts made to eradicate dissolved as well as suspended contaminants from eutrophic water system in a single step. Monitoring studies revealed that examined pond contain high chlorophyll-a content (101.8 µg L(-1)), turbidity (39.5 NTU) and total dissolved solids concentration (0.04 g L(-1)). Samples were further exposed to extensive water quality analysis, which include examining physicochemical parameters (pH, conductivity, total dissolved solids, salinity, turbidity and chlorophyll-a), metals (Na, K, Ca, Mg, Al, Fe, Cu, Cd, Pb, Zn, Cr, and Ni) and anions (NO3, NO2, PO4, SO4, Cl, F and Br). To tackle pollutants, filtration system was designed to comprise of several components including fine sand, coarse sand/sorbent mix and gravel from top to bottom loaded in fiberglass tanks. All the filters (activated carbon, Sargassum and zeolite) completely removed algal biomass and showed potential to decrease pH during entire operational period of 20 h at 120 L h(-1). To examine the efficiency of filters in adverse conditions, the pond water was spiked with heavy metals (Cu, Cd, Pb, Zn, Cr, and Ni). Of the different filter systems, Sargassum-loaded filter performed exceedingly well with concentrations of heavy metals never exceeded the Environmental protection agency regulations for freshwater limits during total operational period. The total uptake capacities at the end of the fifth event were 24.9, 20.5, 0.58, 5.2, 0.091 and 2.8 mg/kg for Cr, Ni, Cu, Zn, Cd and Pb, respectively.


Assuntos
Recuperação e Remediação Ambiental/métodos , Eutrofização , Poluentes da Água/química , Adsorção , Carbono/química , Clorofila/análise , Clorofila A , Filtração/métodos , Água Doce/análise , Metais/análise , Metais/química , Lagoas , Sargassum/química , Dióxido de Silício/química , Poluentes da Água/análise , Zeolitas/química
11.
Health Care Women Int ; 35(10): 1148-61, 2014.
Artigo em Inglês | MEDLINE | ID: mdl-23611111

RESUMO

Due to high cervical cancer rates and limited research on human papillomavirus (HPV) vaccine acceptability in India, the research team examined parental attitudes toward HPV vaccines. Thirty-six interviews with parents were conducted to assess sexually transmitted infection (STI)-related knowledge and HPV-specific vaccine awareness and acceptability. Despite limited knowledge, parents had positive views toward HPV vaccines. Common barriers included concerns about side effects, vaccine cost, and missing work to receive the vaccine. Parents were strongly influenced by health care providers' recommendations. Our findings suggest that addressing parental concerns, health worker training and polices, and efforts to minimize cost will be central to successful HPV vaccine implementation.


Assuntos
Conhecimentos, Atitudes e Prática em Saúde , Infecções por Papillomavirus/prevenção & controle , Vacinas contra Papillomavirus/administração & dosagem , Pais , Aceitação pelo Paciente de Cuidados de Saúde , Neoplasias do Colo do Útero/prevenção & controle , Adulto , Feminino , Humanos , Entrevistas como Assunto , Masculino , Pessoa de Meia-Idade , Pesquisa Qualitativa , Infecções Sexualmente Transmissíveis/prevenção & controle , Fatores Socioeconômicos , Inquéritos e Questionários , Vacinação/estatística & dados numéricos , Adulto Jovem
12.
Water Sci Technol ; 68(6): 1280-7, 2013.
Artigo em Inglês | MEDLINE | ID: mdl-24056424

RESUMO

One of the most effective mitigative approaches to eutrophication is the reduction of nutrient loading into water bodies. Bioremediation presents an economically viable and ecologically sustainable technology to nutrient pollution control taking advantage of the remarkable ability of plants and their associated microbial community to assimilate and remove nutrients from the environment. In this study, four emergent macrophytes (Cyperus haspan, Pandanus amaryllifolius, Pontederia cordata and Thalia geniculata) and two floating plants (Hygroryza aristata and Pistia stratiotes) were deployed in bank-side treatment beds and comparatively assessed for their remediative capabilities for nutrient control. P. stratiotes exhibited the highest removal efficiency for both nitrate and phosphate among the six plant species studied. Emergent macrophytes, P. amaryllifolius, C. haspan and P. cordata, were also found to be highly effective in nutrient uptake exhibiting removal efficiencies up to 100%. With the exception of T. geniculata, depletion of nutrients as a result of plant uptake significantly impeded the natural colonization of algae invariably leading to improvements in water quality in terms of turbidity and pH. Suppression of algae proliferation by T. geniculata was not preceded by a reduction in nutrient concentrations suggesting that T. geniculata may be directly inhibiting algal growth through allelopathy.


Assuntos
Magnoliopsida/metabolismo , Nitratos/metabolismo , Fosfatos/metabolismo , Poluentes da Água/metabolismo , Biodegradação Ambiental , Clorofila/metabolismo , Clorofila A , Eutrofização
13.
Artigo em Inglês | MEDLINE | ID: mdl-23947707

RESUMO

Laboratory batch and column experiments were carried out to examine the efficiency of algal-based treatment technique to clean-up wastewaters emanating from inductively coupled plasma-optical emission spectrometry (ICP-OES). Chemical characterization revealed the extreme complexity of the wastewater, with the presence of 14 different metals under very low pH (pH = 1.1), high conductivity (6.98 mS/cm), total dissolved solid (4.46 g/L) and salinity (3.77). Batch experiments using Sargassum biomass indicated that it was possible to attain high removal efficiencies at optimum pH of 4.0. Efforts were also made to continuously treat ICP-OES wastewater using up-flow packed column. However, swelling of Sargassum biomass leads to stoppage of column. To address the problem, Sargassum was mixed with sand at a ratio of 40: 60 on volume basis. Remarkably, the hybrid Sargassum-sand sorbent showed very high removal efficiency towards multiple metal ions with the column able to operate for 11 h at a flow rate of 10 mL/min. Metal ions such as Cu, Cd, and Pb were only under trace levels in the treated water until 11 h. The results of the treatment process were compared with trade effluent discharge standards. Further the process evaluation and cost analysis were presented.


Assuntos
Metais Pesados/metabolismo , Sargassum/metabolismo , Espectrofotometria Atômica , Eliminação de Resíduos Líquidos/métodos , Águas Residuárias/química , Poluentes Químicos da Água/química , Adsorção , Biomassa , Dióxido de Silício/química , Eliminação de Resíduos Líquidos/economia , Eliminação de Resíduos Líquidos/instrumentação
14.
J Hazard Mater ; 241-242: 110-7, 2012 Nov 30.
Artigo em Inglês | MEDLINE | ID: mdl-23036702

RESUMO

The performance of polyaniline/extracellular polymeric substances (Pn/EPS) composite as an adsorbent to remove the anionic reactive dyes, Reactive Brilliant Blue R (RBBR) and Reactive Orange 16 (RO), was investigated in single and binary systems. The pH(pzc) of Pn/EPS composite was calculated as 3.7 through potentiometric mass titration method. Electrostatic interaction between the dye anion and the nitrogen present in the polymer was identified as a major mechanism in adsorption process. Single component isotherms followed the Langmuir model with the maximum adsorption capacity of 0.5775 mmol g(-1) for RBBR and 0.4748 mmol g(-1) for RO. In binary system, both the reactive dye anions compete with each other and resulted in lower uptake. Binary adsorption data were interpreted well by the Sheindorf-Rehbun-Sheintuch equation as compared to extended Langmuir model with constant interaction factor. Kinetic analysis of single solute followed pseudo-first order model. Thermodynamic studies computed that RBBR and RO adsorption was endothermic, spontaneous, and feasible process.


Assuntos
Compostos de Anilina/química , Antraquinonas/isolamento & purificação , Compostos Azo/isolamento & purificação , Polímeros/química , Polissacarídeos Bacterianos/química , Águas Residuárias/análise , Purificação da Água/métodos , Adsorção , Concentração de Íons de Hidrogênio , Cinética , Modelos Teóricos , Indústria Têxtil , Águas Residuárias/química
15.
Carbohydr Polym ; 90(4): 1437-44, 2012 Nov 06.
Artigo em Inglês | MEDLINE | ID: mdl-22944400

RESUMO

Starch/polyaniline nanocomposite was synthesized by chemical oxidative polymerization of aniline and was subsequently analyzed for dye removal from aqueous solution. Batch experiment results showed that nanocomposite removed 99% of Reactive Black 5, 98% of Reactive Violet 4, and decolorized 87% of dye bath effluent. The Toth isotherm model better described single component equilibrium adsorption, whereas the modified Freundlich model showed satisfactory fit for dye bath. In kinetic modeling, single system followed pseudo-second-order and dye bath followed the modified pseudo-first-order model. Fourier transform infrared spectroscopy pattern of the nanocomposite showed the participation of aromatic, amino, hydroxyl, and carboxyl groups. The results indicate that starch/polyaniline nanocomposite can be used as an effective adsorbent for removal of dyes from textile effluents.


Assuntos
Compostos de Anilina/química , Corantes/isolamento & purificação , Nanocompostos/química , Amido/química , Poluentes Químicos da Água/química , Purificação da Água/métodos , Adsorção , Cinética , Espectroscopia de Infravermelho com Transformada de Fourier , Termodinâmica , Difração de Raios X
16.
Colloids Surf B Biointerfaces ; 94: 114-7, 2012 Jun 01.
Artigo em Inglês | MEDLINE | ID: mdl-22348989

RESUMO

A novel biosynthesis route for silver nanoparticles (Ag-NPs) was attempted in this present investigation using aqueous extracts of Trachyspermum ammi and Papaver somniferum. The main constituents in T. ammi are thymol, p-cymene and γ-terpinene, while P. somniferum consists of morphine and codeine. The essential oil in T. ammi was found to be a good reducing agent than the alkaloids present in P. somniferum for the formation of biocompatible Ag-NPs. The effectiveness of both the extracts was investigated by using same dosage of extract in the synthesis of silver nanoparticle. The results showed that for the same dosage of extracts the T. ammi synthesized various size triangular shaped nanoparticles measuring from 87 nm, to a fewer nanoparticles having a size of 998 nm diagonally. P. somniferum resulted in almost spherical shaped particle ranging in size between 3.2 and 7.6 µm diagonally. Future research based on synthesis of size specific nanoparticle based on the optimization of reaction condition would be an interesting area.


Assuntos
Apiaceae/química , Materiais Biocompatíveis/síntese química , Nanopartículas Metálicas/química , Papaver/química , Extratos Vegetais/química , Alcaloides/química , Química Verde , Nanopartículas Metálicas/ultraestrutura , Microscopia Eletrônica de Transmissão , Óleos Voláteis/química , Tamanho da Partícula , Substâncias Redutoras/química , Sementes/química , Difração de Raios X
17.
Water Res ; 46(4): 1337-45, 2012 Mar 15.
Artigo em Inglês | MEDLINE | ID: mdl-22244273

RESUMO

Green (vegetated) roofs are emerging as practical strategies to improve the environmental quality of cities. However, the impact of green roofs on the storm water quality remains a topic of concern to city planners and environmental policy makers. This study investigated whether green roofs act as a source or a sink of various metals (Na, K, Ca, Mg, Al, Fe, Cu, Cd, Pb, Zn, Mn, Cr, Ni, Li and Co), inorganic anions (NO3-, NO2-, PO4(3-), SO4(2-), Cl-, F- and Br-) and cation (NH4+). A series of green roof assemblies were constructed. Four different real rain events and several artificial rain events were considered for the study. Results showed that concentrations of most of the chemical components in runoff were highest during the beginning of rain events and subsided in the subsequent rain events. Some of the important components present in the runoff include Na, K, Ca, Mg, Li, Fe, Al, Cu, NO3-, PO4(3-) and SO4(2-). However, the concentration of these chemical components in the roof runoff strongly depends on the nature of substrates used in the green roof and the volume of rain. Based on the USEPA standards for freshwater quality, we conclude that the green roof used in this study is reasonably effective except that the runoff contains significant amounts of NO3- and PO4(3-).


Assuntos
Materiais de Construção , Química Verde , Chuva , Eliminação de Resíduos Líquidos , Qualidade da Água , Ânions/análise , Cátions/análise , Condutividade Elétrica , Concentração de Íons de Hidrogênio , Metais/análise , Salinidade , Singapura , Estados Unidos , United States Environmental Protection Agency
18.
Environ Pollut ; 161: 272-83, 2012 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-21705119

RESUMO

Three sets of model predicted values for speciated mercury concentrations and dry deposition fluxes over the Great Lakes region were assessed using field measurements and model intercomparisons. The model predicted values were produced by the Community Multiscale Air Quality Modeling System for the year 2002 (CMAQ2002) and for the year 2005 (CMAQ2005) and by the Global/Regional Atmospheric Heavy Metals Model for the year 2005 (GRAHM2005). Median values of the surface layer ambient concentration of gaseous elemental mercury (GEM) from all three models were generally within 30% of measurements. However, all three models overpredicted surface-layer concentrations of gaseous oxidized mercury (GOM) and particulate bound mercury (PBM) by a factor of 2-10 at the majority of the 15 monitoring locations. For dry deposition of GOM plus PBM, CMAQ2005 showed a clear gradient with the highest deposition in Pennsylvania and its surrounding areas while GRAHM2005 showed no such gradient in this region; however, GRAHM2005 had more hot spots than those of CMAQ2005. Predicted dry deposition of GOM plus PBM from these models should be treated as upper-end estimates over some land surfaces in this region based on the tendencies of all the models to overpredict GOM and PBM concentrations when compared to field measurements. Model predicted GEM dry deposition was found to be as important as GOM plus PBM dry deposition as a contributor to total dry deposition. Predicted total annual mercury dry deposition were mostly lower than 5 µg m(-2) to the surface of the Great lakes, between 5 and 15 µg m(-2) to the land surface north of the US/Canada border, and between 5 and 40 µg m(-2) to the land surface south of the US/Canada border. Predicted dry deposition from different models differed from each other by as much as a factor of 2 at regional scales and by a greater extent at local scales.


Assuntos
Poluentes Atmosféricos/análise , Mercúrio/análise , Modelos Químicos , Poluição do Ar/estatística & dados numéricos , Atmosfera/química , Monitoramento Ambiental , Great Lakes Region , Ontário , Quebeque
19.
J Health Popul Nutr ; 29(4): 327-38, 2011 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-21957671

RESUMO

The prevalence of chronic energy deficiency (CED) among one-third of the Indian population is attributed to inadequacy of consumption of nutrients. However, considering the complexity of diets among Indians, the relationship between a particular dietary pattern and the nutritional status of the population has not been established so far. A community-based cross-sectional study was undertaken to assess estimates, at district level, of diet and nutritional status in Orissa State, India. Factor analysis was used for exploring the existence of consumption pattern of food and nutrients and their relationship with the nutritional status of rural adult population. Data on 2,864 adult men and 3,525 adult women in Orissa state revealed that there exists six patterns among food-groups explaining 59% of the total variation and three patterns among nutrients that explain 73% of the total variation among both adult men and women. The discriminant function analysis revealed that, overall, 53% of the men were correctly classified as either with chronic energy deficiency (CED) or without CED. Similarly, overall, 54% of the women were correctly classified as either with CED or without CED. The sensitivity of the model was 65% for both men and women, and the specificity was 46% and 41% respectively for men and women. In the case of classification of overweight/obesity, the prediction of the model was about 75% among both men and women, along with high sensitivity. Using factor analysis, the dietary patterns were identified from the food and nutrient intake data. There exists a strong relationship between the dietary patterns and the nutritional status of rural adults. These results will help identify the community people with CED and help planners formulate nutritional interventions accordingly.


Assuntos
Comportamento Alimentar , Estado Nutricional , Saúde da População Rural , Adolescente , Adulto , Idoso , Estudos Transversais , Ingestão de Energia , Análise Fatorial , Feminino , Humanos , Índia/epidemiologia , Masculino , Desnutrição/epidemiologia , Pessoa de Meia-Idade , Sobrepeso/epidemiologia , Análise de Componente Principal , Adulto Jovem
20.
Environ Monit Assess ; 182(1-4): 47-60, 2011 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-21229305

RESUMO

Investigation has been made to identify groundwater vulnerability to pollution by using geoelectric and hydrochemical investigations in an important industrial town Mettur located in Tamilnadu state of India. Schlumberger vertical electric soundings were carried out in 23 locations and groundwater samples collected from bore wells in the same locations. The resistivity value with <20 Ωm up to a depth of 36 m indicate contamination of groundwater in areas influenced by sewages from industries, domestic and agricultural practices in the central and southern part of the study area. The calculated specific conductance was noted higher than EC in central and southern part of the study area with low resistivity indicating the contaminated nature of groundwater. Concentrations of Ca, Na, Mg and K along with Cl, HCO(3), SO(4) and NO(3) were higher in certain locations when compared with WHO and ISI standards. The facies concept demarcated four groups based on the nature of groundwater contamination. The trace elements Fe and Pb were higher in locations confined to industrial zones and Zn and Cu were within the prescribed limit in all the samples.


Assuntos
Monitoramento Ambiental/métodos , Água Subterrânea/química , Indústrias/estatística & dados numéricos , Poluentes Químicos da Água/análise , Sedimentos Geológicos/química , Índia , Medição de Risco
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