Adsorption Kinetics of Cadmium and Lead by Biochars in Single- and Bisolute Brackish Water Systems.

Cd(II) and Pb(II) adsorption from brackish water by activated carbon (AC) and biochars derived from bamboo (BB), palm shell (PSB), and mangrove wood (MB) in single- and bisolute systems was investigated. Physicochemical characterization including SEM, FTIR, pH, pHPZC, elemental analysis, proximate analysis, XRF, iodine number, BET surface area analysis, and TGA was carried out. The adsorption of Cd(II) and Pb(II) was in the following order: AC > BB > MB > PSB and was higher in single-solute than bisolute systems with greater Pb(II) adsorption efficiency than Cd(II). Salinity negatively affected metal sorption, particularly for Cd(II), but higher pH enhanced removal. Upon increasing the salinity from 0 to 25 ppt, the removal efficiency of BB was reduced from 75.9 to 52.2% (Cd) and 91.1 to 80.5% (Pb) in the single-solute system. In addition, the removal efficiency was decreased from 71.6 to 41.3% for Cd(II) and 90.9 to 76.3% for Pb)(II) in the bisolute system. The removal trend of the adsorption system of BB with 0 ppt salinity responded positively upon increasing pH from 5 to 8, and the removal of Cd(II) was increased from 54.4 to 75.8% and that of Pb(II) was increased from 66.3 to 91.0% in the single-solute system. The adsorption kinetic data are well explained by the pseudo-second-order model suggesting that chemisorption is the rate-limiting step. The key results of the present work suggest the applicability of BB as an alternative adsorbent to AC due to its comparable physicochemical properties, such as surface area (191.95 m2/g), pore volume (0.1038 cm3/g), pHPZC (9.27), iodine number (104.2 mg/g), and the presence of hydroxyl (-OH), amine (-NH), and COO- groups necessary for metal bonding. The adsorption performance of BB is promising, and hence, it can be considered to remove the Cd(II) and Pb(II) ions from brackish water as statistically it is the least impacted by change in salinity at a confidence level of P ≤ 0.05 compared to MB and PSB.

Fixed-bed biofilter for polluted surface water treatment using chitosan impregnated-coconut husk biochar.

Pelletizing biochar enables its use as a biofilter medium for polluted canal water treatment. Coconut husk biochar pellets and their modification with chitosan (CHC) were compared with conventional activated carbon pellets and gravel. The biofilter columns with these media were operated with a hydraulic loading rate of 0.1 m3/m2∙h. CHC showed the highest potential to reduce phosphate and nitrogen, via the adsorption process in the first week of filtration and later enhanced by biodegradation, to achieve removal efficiencies of 61.70 and 54.37% for these two key nutrients, respectively, over five weeks of biofilter operation. The predominant bacteria in the biofilter communities were characterized at the end of the experiments by next generation sequencing and quantitative polymerase chain reaction analysis. The biofilter communities included ammonium oxidizing, nitrite oxidizing, denitrifying, polyphosphate accumulating and denitrifying phosphate-accumulating bacteria that benefit nutrient removal. The CHC biofilter also effectively removed micropollutants, including pharmaceuticals.

Investigation of plastic waste management in Thailand using material flow analysis.

This study uses material flow analysis to investigate the amounts and pathways of municipal plastic waste (MPW) in Thailand. The aim is to understand the country's situation and investigate the effects of Thailand's Roadmap on Plastic Waste Management 2018-2030, which sets a goal for recycling 'target plastic waste' at 100% by 2027. The analysis was conducted using waste statistics between 2008 and 2020 and waste forecasts. Two scenarios of plastic waste management, the business-as-usual, and the national roadmap, were constructed for 2025 and 2030. In 2030, the annual MPW generation is projected to reach 2.19 Mt. Under the business-as-usual (BAU) scenario, the recycling and utilisation rate will be 32.3% of waste generated. About 30.3% of waste generated will not be treated properly and possibly leaked into the open environment. Under the roadmap scenario, the recycling and utilisation rate will increase to 98.4%, while 1.6% of waste generated will not be treated properly. The recycling rate for target plastic waste in 2027 could only reach 67.1% because plastic waste is required as fuel for waste incinerators and industries. With the roadmap fully implemented, certain effects can be foreseen for waste-to-energy and plastic industries. Findings from this study stress on the importance of holistic policy planning, efficient prioritising and allocating of waste as a resource, and cooperation from all sectors for sustainable plastic waste management.

Water quality and climate variability of urban and tourism areas in Thailand and northern Vietnam: correlations and possible influences on nearby coastal shrimp farms.

This research explored the long-term relationships of climate parameters and coastal water quality nearby shrimp farms in two countries. In Thailand, two sampling points in canals located in Bangkok and Trang provinces were selected as the urban and tourism areas, respectively. In northern Vietnam, the canals located in Thai Binh and Quang Ninh provinces were used as the urban and tourism areas, respectively. The diurnal monitoring of water quality and weather was performed at each site to evaluate the relationships between climate and water quality, pollution load, and risk analysis. A questionnaire was also used to assess the climate and water exposure, vulnerability, and adaptability of each site. All data were ranked on a scale of 1 to 5 to integrate each factor. It was determined that the main water quality problem was fecal pollution. Notably, aquaculture farming in northern Vietnam is more vulnerable than in Thailand; however, Vietnam farmers were adaptable for climate variability.

Valorisation of agricultural waste derived biochars in aquaculture to remove organic micropollutants from water - experimental study and molecular dynamics simulations.

In this work, we evaluated the valorisation of agricultural waste materials by transforming coconut husks and shells, corncobs and rice straw into biochar for water treatment in aquaculture. We compared the biochars' suitability for removal of organic micropollutants (acetaminophen, oxytetracycline, tetracycline, enrofloxacin, atrazine, diuron and diclofenac) from surface water needed for aquaculture. The biochars were prepared by three methods ranging from inexpensive drum kilns (200 °C) to pyrolysis with biogasfication (350-750 °C). Overall, antibiotics tetracycline and enrofloxacin were the most strongly sorbed micropollutants, and coconut husk biochar prepared at 750 °C was the best sorbent material. Molecular Dynamics simulations indicated that the major sorption mechanism is via π-π stacking interactions and there is a possibility of multilayer sorption for some of the micropollutants. We observed, a strong impact of ionic strength (salinity), which is an important consideration in coastal aquaculture applications. High salinity decreased the sorption for antibiotics oxytetracycline, tetracycline and enrofloxacin but increased diclofenac, atrazine and diuron sorption. We considered coconut husk biochar produced in drum kilns the most practical option for biochar applications in small-scale coastal aquacultures in South Asia. Pilot trials of canal water filtration at an aquaculture farm revealed that micropollutant sorption by coconut husk biochar under real-world conditions might be 10-500 times less than observed in the laboratory studies. Even so, biochar amendment of sand enhanced the micropollutant retention, which may facilitate subsequent biodegradation and improve the quality of brackish surface water used for food production in coastal aquaculture.

Environmental antimicrobial resistance is associated with faecal pollution in Central Thailand's coastal aquaculture region.

We assessed antimicrobial resistance (AMR) potential to seven major classes of antibiotics in Central Thailand's coastal aquaculture region using high-throughput qPCR targeting 295 antibiotic resistance genes (ARGs) and mobile genetic elements (MGEs). In parallel, we used MinION next generation sequencing (NGS) of 16S rRNA gene amplicons, qPCR of faecal pollution makers, and conventional plate count methods for the comprehensive characterization of environmental microbiomes. We tested the hypothesis that aquaculture increases environmental AMR by comparing ARGs and MGEs in water and sediment samples from five aquaculture sites and their associated canals. There was no evidence from the ARG and MGE data that aquaculture is a major driver of environmental AMR in Central Thailand. Instead, the highest relative prevalence of resistance traits was found in Hua Krabue canal water influenced by urban pollution from Bangkok at the inland edge of the coastal aquaculture region. The sum of ARGs and MGEs, relative to 16S rRNA genes used as markers for overall bacterial abundance, was between 0.495 ± 0.011 and 0.498 ± 0.013 in Hua Krabue canal water, compared with at most 0.132 ± 0.005 in all the other environmental samples. Corresponding patterns were observed for most faecal pollution markers, which were also elevated in Hua Krabue canal water.

Coconut husk biochar amendment enhances nutrient retention by suppressing nitrification in agricultural soil following anaerobic digestate application.

Anaerobic digestate and biochar are by-products of the biogasification and pyrolysis of agricultural wastes. This study tested the hypothesis that combined application of anaerobic pig/cattle manure digestate and coconut husk (CH) biochar can improve soil nutrient conditions, whilst minimizing atmospheric and groundwater pollution risks. Microcosms simulated digestate application to agricultural soil with and without CH biochar. Ammonia volatilization and nutrient leaching were quantified after simulated heavy rainfalls. Archaeal and bacterial community and abundance changes in soils were quantified via next generation sequencing and qPCR of 16S rRNA genes. Nitrifying bacteria were additionally quantified by qPCR of functional genes. It was found that CH biochar retarded nitrate leaching via slower nitrification in digestate-amended soil. CH biochar reduced both nitrifying archaea and bacteria abundance in soil by 71-83 percent in the top 4 cm soil layer and 66-80 percent in the deeper soil layer one month after the digestate application. Methanotroph abundances were similarly reduced in the CH biochar amended soils. These findings demonstrate combined benefits of anaerobic digestate and CH biochar application which are relevant for the development of a more circular rural economy with waste minimization, renewable energy production, nutrient recycling and reduced water pollution from agricultural land.

The food-water quality nexus in periurban aquacultures downstream of Bangkok, Thailand.

Peri-urban aquacultures produce nutritious food in proximity to markets, but poor surface water quality in rapidly expanding megacities threatens their success in emerging economies. Our study compared, for a wide range of parameters, water quality downstream of Bangkok with aquaculture regulations and standards. For parameters not meeting those requirements, we sought to establish whether aquaculture practice or external factors were responsible. We applied conventional and advanced methods, including micropollutant analysis, genetic markers, and 16S rRNA amplicon sequencing, to investigate three family-owned aquacultures spanning extensive, semi-intensive and intensive practices. Canals draining the city of Bangkok did not meet quality standards for water to be used in aquaculture, and were sources for faecal coliforms, Bacteriodes, Prevotella, Human E. coli, tetracycline resistance genes, and nitrogen into the aquaculture ponds. Because of these inputs, aquacultures suffered algae blooms, with and without fertilizer and feed addition to the ponds. The aquacultures were sources of salinity and the herbicide diuron into the canals. Diuron was detectable in shrimp, but not at a level of concern to human health. Given the extent and nature of pollution, peri-urban water policy should prioritize charging for urban wastewater treatment over water fees for small-scale agricultural users. The extensive aquaculture attenuated per year an estimated twenty population equivalents of nitrogen pollution and trillions of faecal coliform bacteria inputs from the canal. Extensive aquacultures could thus contribute to peri-urban blue-green infrastructures providing ecosystem services to the urban population such as flood risk management, food production and water pollution attenuation.

Prevalence of Escherichia coli in surface waters of Southeast Asian cities.

Surface water samples were collected from rivers which fed into large urban areas within Vietnam, Indonesia, Cambodia, and Thailand and were processed to enumerate Escherichia coli. Selected isolates were further characterized using PCR to detect the presence of specific virulence genes. Analyzing the four countries together, the approximate mean cfu/100 ml for E. coli counts in the dry season were log 4.3, while counts in the wet season were log 2.8. Of the 564 E. coli isolates screened for the presence of pathogenic genes, 3.9 % possessed at least one virulence gene. The most common pathogenic types found were Shiga toxin-producing E. coli isolates. These results reinforce the importance of monitoring urban surface waters for fecal contamination, that E. coli in these water environments may serve as opportunistic pathogens, and may help in determining the impact water usage from these rivers have on the public health of urban populations in Southeast Asia.

Anaerobic degradation kinetics of reactive dye with different carbon sources.

This study aims to investigate the anaerobic degradation kinetics of reactive dye, C.I. Reactive Red 141 (Evercion Red H-E7B) by partially granulated anaerobic mixed culture using three carbon sources, namely modified starch (MS), polyvinyl alcohol (PVA) and acrylic size (AS) during batch incubation. There is a first-order kinetics reaction in the decolorization processes using MS and PVA as carbon sources, while a zero-order kinetics relationship describes the decolorization process for the AS carbon source. The k values and color removal rate of decolorization with MS carbon source was higher than those of PVA and AS carbon sources. This is because the MS carbon source was well degraded in comparison to AS and PVA, respectively This study also found dye reduction could be enhanced through the addition of MS as a carbon source. The decolorization rates increased with decrease in dye concentrations of RR 141. In contrast, the decolorization rates increased with increase in COD concentration.