Evaluation of protective measures for tropical environments.

Nuclear and radiological accidents have demonstrated the need for prior planning for exposure assessment as well as guidelines for the implementation of protection and remediation measures of contaminated areas. Typically, the description of the efficiency of the measures in the literature is associated with the reduction of the concentration of the environmental media where they are applied. In order to verify the efficiency related to the reduction in doses, some basic scenarios were established, taking into account aspects of a typical tropical climate, such as building materials (urban areas) and types of crops and farming practices, considering the seasonality and soil type typical of the southeastern region of Brazil. The Integrated System for Emergency (SIEM) program was used to perform the simulations. The results indicate that decision-making processes must be made in accordance with the actual conditions of contamination and use of the affected area. For rural areas, the effectiveness of measures depends on many factors specific to each site, such as seasonality, produced crops, diet habits and degree of subsistence on the items in the diet, which make it unfeasible to develop generic predefined scenarios. The criteria for classification of measurements were defined as: (i) the efficiency in reducing the doses in the first year, in which largest dose rates are observed; (ii) the efficiency in reducing the long-term dose, considering 50 y for adults and (iii) the effect of delay in implementation of the measures on the reduction of doses.

Mercury speciation in sediments of a tropical coastal environment.

The speciation of mercury in tropical coastal areas, although scarcely studied, has presented an odd behaviour when compared with the results obtained in temperate environments. In this work, we measured the concentrations of mercury species (mercuric mercury, methyl-mercury and dimethyl-mercury) in the sediments of Sepetiba Bay (Brazil) and compared these with geochemical parameters. Twenty-eight sediment samples were extracted in an open microwave system and mercury speciation was carried out by ethylation, cryogenic focusing, gas chromatography and quartz furnace atomic absorption spectrometry. Fraction < 63 microm, organic carbon and total sulphur contents and redox potential were measured in order to outline the geochemical characteristics of the sediments. While mercuric mercury presented concentrations ranging between 22.65 and 134.61 ng g(-1), methyl-mercury concentrations ranged between < 2.0 and 4.4 ng g(-1). Only a few dimethyl-mercury concentrations were relatively high (up to 14.6 ng g(-1)). The results of mercuric mercury presented an unexpected positive correlation with sulphur contents showing that mercury is forming stable sulphide complexes, even under very reducing conditions. This would render mercury available for t he formation of methyl- or dimethyl-mercury that would be both fixed in the sediments and volatilised.