RESUMO
In order to fully understand the explosion risk of electrostatic spraying powder, corresponding preventive measures are put forward. The explosion characteristics, ignition sensitivity, and flame propagation of three typical electrostatic spraying powders were tested using a 20 L spherical explosion test device, a G-G furnace test device, and a Hartmann tube test device, and the explosion process and mechanism of electrostatic spraying powders were discussed. The results show that the maximum explosion pressure and the maximum explosion pressure rise rate increase first and then decrease with the increase in mass concentration. The maximum explosion pressure and the maximum explosion pressure rise rate of acrylic powder coating are the largest, which are 0.75 and 85.4 MPa/s, respectively. The shortest burning time is 97.5 ms, and the highest explosion danger level is 23.46 MPa·m/s. The flame propagation of electrostatic spraying powder develops slowly; the flame front spreads linearly and the average flame velocity increases first and then decreases. The explosive development process of powder coating particles is concentrated in the three-phase system of solid particles, molten particles, and pyrolytic gasification combustible gas, which goes through the kinetic process of particle heating melting, cross-linking curing, pyrolytic gasification, combustion, and extinction.
RESUMO
A study was conducted on the explosion overpressure and flame propagation law of magnesium-aluminum (Mg-Al) alloy powder, and the suppression mechanism of sodium chloride (NaCl) on the explosion of magnesium-aluminum alloy powder was explored. Adding NaCl powder can effectively reduce the explosion pressure, flame front position, and flame propagation speed. The higher the amount of NaCl powder added, the lower the explosion pressure of magnesium-aluminum alloy powder, the slower the flame propagation speed, and the lower the flame brightness. NaCl adsorbed on Mg-Al alloy powder isolated heat transfer and played a cooling role. The Cl- produced by NaCl decomposition will react with the free radicals H+ and OH- in the reaction system, which will reduce the concentration of H+ and OH- in the combustion process and hinder the propagation and expansion of the flame. The research results provide theoretical guidance for the explosion prevention of Mg-Al alloy powder and the preparation of a physical-chemical compound explosion suppressor in the later stage.
RESUMO
In an effort to effectively control coal dust pollution and thereby reduce the harm of coal dust to human health, we prepared a highly efficient composite dust suppressant. First, dynamic contact angle and zeta potential measurements were used to select sodium dodecyl sulfonate (SDS) over sodium carboxymethyl cellulose and trisodium methyl silicon as the complementary additive to soy protein isolate for the dust suppressant. We employed viscosity and wind erosion resistance tests to compare the performance of the composite dust suppressant with three common, commercially available suppressants. As the concentration of the composite dust suppressant was increased, the viscosity increased, reaching a maximum value of 22.7 mPa·s at a concentration of 5 wt%. The 5 wt% concentration of the composite dust suppressant provided the lowest wind erosion rate (20.62%) at a wind speed of 12 m/s. The composite dust suppressant also had good bonding performance and wind erosion resistance. Scanning electron microscopy, X-ray diffraction, and thermogravimetric analysis were used to characterize the properties of the dust suppressants. The dust suppressant, which had a crystal-like structure, could easily capture coal dust and form an effective package. In addition, the density of the dust suppressant film increased as its crystallinity increased. The increased density was beneficial in that it enabled the dust suppressant to form a hard, solidified shell on the surface of coal dust, which improved dust suppression. The composite dust suppressant also had good thermal stability.
