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J Hazard Mater ; 244-245: 603-12, 2013 Jan 15.
Artigo em Inglês | MEDLINE | ID: mdl-23182246

RESUMO

The aquatic plant, Lemna perpusilla Torr. strain, was dried, pulverized and used for Pb(II) removal from aqueous solution. Batch experiments were conducted to investigate the effects of pH, contact time, initial metal concentration and temperature on Pb(II) adsorption. A dose of 4 g L(-1) of dried L. perpusilla in a solution with an initial pH of 4.6, an initial Pb(II) concentration of 50 mg L(-1) and a contact time of 210 min resulted in the maximum Pb(II) removal efficiency (above 95%). The equilibrium adsorption capacities increased with increasing initial Pb(II) concentration. The adsorption isotherm was better described by a Langmuir model rather than a Freundlich model. Further, the adsorption kinetics followed a pseudo-second-order model. An FTIR examination revealed changes between the natural and Pb(II)-loaded plant material. Scanning electron micrograph (SEM) also revealed changes in the surface morphology of the biomass as a result of lead adsorption. Based on these results, it can be concluded that the dried L. perpusilla is effective in removing lead from aqueous solution and merits consideration for scaled-up trials.


Assuntos
Araceae , Chumbo/química , Preparações de Plantas/química , Poluentes Químicos da Água/química , Adsorção , Biodegradação Ambiental , Concentração de Íons de Hidrogênio , Microscopia Eletrônica de Varredura , Concentração Osmolar , Espectrometria por Raios X , Espectroscopia de Infravermelho com Transformada de Fourier , Fatores de Tempo , Eliminação de Resíduos Líquidos/métodos
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