Enhancement of superconductivity and phase diagram of Ta-doped Kagome superconductor CsV3Sb5.

Kagome superconductors AV3Sb5 (A = K, Rb, and Cs) have attracted enormous interest due to the coexistence of charge density wave (CDW) order, unconventional superconductivity (SC) and anomalous Hall effect (AHE). In this paper, we reported an intensive investigation on Cs(V1-xTax)3Sb5 single crystals with systematic Ta doping. Ta was confirmed to be doped into V-site in the Kagome layer from both single crystal X-ray diffraction structural refinement and scanning transmission electron microscopy observation. The highest Ta doping level was found to be about 16%, which is more than twice as much as 7% in Nb-doped CsV3Sb5. With the increase of Ta doping, CDW order was gradually suppressed and finally vanished when the doping level reached to more than 8%. Meanwhile, superconductivity was enhanced with a maximum critical temperature (Tc) of 5.3 K, which is the highest Tc in the bulk crystal of this Kagome system at ambient pressure so far. The µ0Hc2(T) behavior demonstrates that the system is still a two-band superconductor after Ta doping. Based on the electrical transport measurement, a phase diagram was set up to exhibit the evolution of CDW and SC in the Cs(V1-xTax)3Sb5 system. These findings pave a new way to search for new superconductors with higher Tc in the AV3Sb5 family and establish a new platform for tuning and controlling the multiple orders and superconducting states.

Absence of near-ambient superconductivity in LuH2±xNy.

A recent study demonstrated near-ambient superconductivity in nitrogen-doped lutetium hydride1. This stimulated a worldwide interest in exploring room-temperature superconductivity at low pressures. Here, by using a high-pressure and high-temperature synthesis technique, we have obtained nitrogen-doped lutetium hydride (LuH2±xNy), which has a dark-blue colour and a structure with the space group [Formula: see text] as evidenced by X-ray diffraction. This structure is the same as that reported in ref. 1, with a slight difference in lattice constant. Raman spectroscopy of our samples also showed patterns similar to those observed in ref. 1. Energy-dispersive X-ray spectroscopy confirmed the presence of nitrogen in the samples. We observed a metallic behaviour from 350 K to 2 K at ambient pressure. On applying pressures from 2.1 GPa to 41 GPa, we observed a gradual colour change from dark blue to violet to pink-red. By measuring the resistance at pressures ranging from 0.4 GPa to 40.1 GPa, we observed a progressively improved metallic behaviour; however, superconductivity was not observed above 2 K. Temperature dependence of magnetization at high pressure shows a very weak positive signal between 100 K and 320 K, and the magnetization increases with an increase in magnetic field at 100 K. All of these are not expected for superconductivity above 100 K. Thus, we conclude the absence of near-ambient superconductivity in this nitrogen-doped lutetium hydride at pressures below 40.1 GPa.

Visualizing the Atomic Configuration of Carbonate Groups in a (Cu,C)Ba2 Ca3 Cu4 O11+δ Superconductor.

Carbonates (CO3 2- ) have always been known as impurities to degrade the superconductivity in cuprate high-Tc superconductors. Herein, the atomic arrangement of carbonates is directly visualized in (Cu,C)Ba2 Ca3 Cu4 O11+δ via integrated differential phase contrast (iDPC) combined with state-of-the-art scanning transmission electron microscopy. The carbon atoms replace Cu atoms in the charge-reservoir layers, contributing to the formation of carbonates through strong orbital hybridization with the surrounding oxygen atoms. Using first-principles calculations, the spatial configuration of the carbonate groups is confirmed and their influence on the local crystal lattice and electronic states is further investigated. The carbonates not only accommodate distortions by improving the flatness of the outer CuO2 layers but also reduce the density of states at the Fermi level. These two factors play competitive roles to affect the superconductivity. This study provides direct evidence of the presence of CO3 2- groups and gains an insight into the underlying mechanism of superconductivity in oxycarbonate superconductors.

Bamboo-like Vortex Chains Confined in Canals with Suppressed Superconductivity and Standing Waves of Quasiparticles.

The vortex core can be regarded as a nanoscale confined system for quasiparticles in a type-II superconductor. It is very interesting to investigate the interplay between the vortex core and other microscopic quantum confined systems. We observe band-like canals with the width of about 15 nm on the surface of KCa2(Fe1-xNix)4As4F2 (x = 0.05) by scanning tunneling microscopy. Some canals suppress superconductivity and confine parallel standing waves due to the quasiparticle interference. Upon magnetic fields being applied, some elongated vortices are formed within canals showing bamboo-like one-dimensional vortex chains. Interestingly, the confined vortex cores are elongated roughly along the perpendicular direction of canals, and the local density of states at positive and negative energies shows an in-phase oscillation at zero field; but, it becomes out-of-phase crossing the vortex cores. Our work reveals a new type of vortex patterns in confined canals and its interplay with the quasiparticle interference.

Comparative studies on superconductivity in Cr3Ru compounds with bcc and A15 structures.

Chromium (Cr) is a transition metal element with 3dorbital electrons. In most compounds containing Cr, due to the correlation effect, twofold features, namely localization and itinerancy are expected. The localization gives rise to a magnetic moment, while the latter exhibits as the effective coherent weight for conductivity. Here we report the physical properties of Cr3Ru compounds with body-centered cubic (bcc) and A15 structures by using multiple experimental tools. The resistivity measurements show sharp superconducting transitions atTc= 2.77 K andTc= 3.37 K for the bcc and A15 structures, respectively. A high residual resistivity exists in both phases. Magnetization measurements also show rather narrow superconducting transitions, with a clear hump feature in the intermediate temperature region (about 150 K), which may be ascribed to the remaining antiferromagnetic spin fluctuations. A pronounced second peak effect has been observed in magnetization hysteresis loops in the superconducting state only for samples with bcc structure. The specific heat coefficient reveals a clear jump at critical temperatures (Tc). We find thats-wave gaps can be adopted to fit the low temperature specific heat data of both samples yielding ratios of2Δ/kBTcabout 3.6, indicating a moderate pairing strength. Interestingly, the Wilson ratiosRW=Aχ0/γnare 3.81 and 3.62 for the bcc and A15 phases, suggesting a moderate correlation effect of conducting electrons in the normal state. Besides, for samples with A15 structure, another specific heat anomaly occurs at about 0.85 K and is sensitive to magnetic fields. In addition, by applying high pressures, both systems will exhibit an enhancement ofTcwith a rate of about 0.019 K GPa-1and 0.013 K GPa-1for the bcc and A15 phases, respectively. Our combinatory results point to unusual behavior of both superconducting and normal states in these two Cr based alloys.

Observation of anomalous amplitude modes in the kagome metal CsV3Sb5.

The kagome lattice provides a fertile platform to explore novel symmetry-breaking states. Charge-density wave (CDW) instabilities have been recently discovered in a new kagome metal family, commonly considered to arise from Fermi-surface instabilities. Here we report the observation of Raman-active CDW amplitude modes in CsV3Sb5, which are collective excitations typically thought to emerge out of frozen soft phonons, although phonon softening is elusive experimentally. The amplitude modes strongly hybridize with other superlattice modes, imparting them with clear temperature-dependent frequency shift and broadening, rarely seen in other known CDW materials. Both the mode mixing and the large amplitude mode frequencies suggest that the CDW exhibits the character of strong electron-phonon coupling, a regime in which phonon softening can cease to exist. Our work highlights the importance of the lattice degree of freedom in the CDW formation and points to the complex nature of the mechanism.

Superconductivity in nickel-based 112 systems.

Superconductivity has been discovered recently in infinite-layer nickel-based 112 thin films R 1-x A xNiO2 (R = La, Nd, Pr and A = Sr, Ca). They are isostructural to the infinite-layer cuprate (Ca,Sr)CuO2 and are supposed to have a formal Ni 3d 9 valence, thus providing a new platform to study the unconventional pairing mechanism of high-temperature superconductors. This important discovery immediately triggers a huge amount of innovative scientific curiosity in the field. In this paper, we try to give an overview of the recent research progress on the newly found superconducting nickelate systems, both from experimental and theoretical aspects. We mainly focus on the electronic structures, magnetic excitations, phase diagrams and superconducting gaps, and finally make some open discussions for possible pairing symmetries in Ni-based 112 systems.

Direct visualization of a static incommensurate antiferromagnetic order in Fe-doped Bi2Sr2CaCu2O8+δ.

In cuprate superconductors, due to strong electronic correlations, there are multiple intertwined orders which either coexist or compete with superconductivity. Among them, the antiferromagnetic (AF) order is the most prominent one. In the region where superconductivity sets in, the long-range AF order is destroyed. Yet the residual short-range AF spin fluctuations are present up to a much higher doping, and their role in the emergence of the superconducting phase is still highly debated. Here, by using a spin-polarized scanning tunneling microscope, we directly visualize an emergent incommensurate AF order in the nearby region of Fe impurities embedded in the optimally doped Bi2Sr2CaCu2O8+δ (Bi2212). Remarkably, the Fe impurities suppress the superconducting coherence peaks with the gapped feature intact, but pin down the ubiquitous short-range incommensurate AF order. Our work shows an intimate relation between antiferromagnetism and superconductivity.

Twofold symmetry of c-axis resistivity in topological kagome superconductor CsV3Sb5 with in-plane rotating magnetic field.

In transition metal compounds, due to the interplay of charge, spin, lattice and orbital degrees of freedom, many intertwined orders exist with close energies. One of the commonly observed states is the so-called nematic electron state, which breaks the in-plane rotational symmetry. This nematic state appears in cuprates, iron-based superconductor, etc. Nematicity may coexist, affect, cooperate or compete with other orders. Here we show the anisotropic in-plane electronic state and superconductivity in a recently discovered kagome metal CsV3Sb5 by measuring c-axis resistivity with the in-plane rotation of magnetic field. We observe a twofold symmetry of superconductivity in the superconducting state and a unique in-plane nematic electronic state in normal state when rotating the in-plane magnetic field. Interestingly these two orders are orthogonal to each other in terms of the field direction of the minimum resistivity. Our results shed new light in understanding non-trivial physical properties of CsV3Sb5.

Friedel Oscillations of Vortex Bound States under Extreme Quantum Limit in KCa_{2}Fe_{4}As_{4}F_{2}.

We report the observation of discrete bound states with the energy levels deviating from the widely believed ratio of 1∶3∶5 in the vortices of an iron-based superconductor KCa_{2}Fe_{4}As_{4}F_{2} through scanning tunneling microscopy (STM). Meanwhile Friedel oscillations of vortex bound states are also observed for the first time in related vortices. By doing self-consistent calculations of Bogoliubov-de Gennes equations, we find that at extreme quantum limit, the superconducting order parameter exhibits a Friedel-like oscillation, which modifies the energy levels of the vortex bound states and explains why it deviates from the ratio of 1∶3∶5. The observed Friedel oscillations of the bound states can also be roughly interpreted by the theoretical calculations, however some features at high energies could not be explained. We attribute this discrepancy to the high energy bound states with the influence of nearby impurities. Our combined STM measurement and the self-consistent calculations illustrate a generalized feature of vortex bound states in type-II superconductors.

Synthesis and physical properties of perovskite Sm1-xSrxNiO3(x= 0, 0.2) and infinite-layer Sm0.8Sr0.2NiO2nickelates.

Recently, superconductivity at about 9-15 K was discovered in Nd1-xSrxNiO2(Nd-112,x≈ 0.125-0.25) infinite-layer thin films, which has stimulated enormous interests in related rare-earth nickelates. Usually, the first step to synthesize this 112 phase is to fabricate theRNiO3(R-113,R: rare-earth element) phase, however, it was reported that the 113 phase is very difficult to be synthesized successfully due to the formation of unusual Ni3+oxidation state. And the difficulty of preparation is enhanced as the ionic radius of rare-earth element decreases. In this work, we report the synthesis and investigation on multiple physical properties of polycrystalline perovskites Sm1-xSrxNiO3(x= 0, 0.2) in which the ionic radius of Sm3+is smaller than that of Pr3+and Nd3+in related superconducting thin films. The structural and compositional analyses conducted by x-ray diffraction and energy dispersive x-ray spectrum reveal that the samples mainly contain the perovskite phase of Sm1-xSrxNiO3with small amount of NiO impurities. Magnetization and resistivity measurements indicate that the parent phase SmNiO3undergoes a paramagnetic-antiferromagnetic transition at about 224 K on a global insulating background. In contrast, the Sr-doped sample Sm0.8Sr0.2NiO3shows a metallic behavior from 300 K down to about 12 K, while below 12 K the resistivity exhibits a slight logarithmic increase. Meanwhile, from the magnetization curves, we can see that a possible spin-glass state occurs below 12 K in Sm0.8Sr0.2NiO3. Using a soft chemical reduction method, we also obtain the infinite-layer phase Sm0.8Sr0.2NiO2with square NiO2planes. The compound shows an insulating behavior which can be described by the three-dimensional variable-range-hopping model. And superconductivity is still absent in the polycrystalline Sm0.8Sr0.2NiO2.

Single particle tunneling spectrum of superconducting Nd1-xSrxNiO2 thin films.

The pairing mechanism in cuprates remains as one of the most challenging issues in condensed matter physics. Recently, superconductivity was discovered in thin films of the infinite-layer nickelate Nd1-xSrxNiO2 (x = 0.12-0.25) which is believed to have the similar 3d9 orbital electrons as that in cuprates. Here we report single-particle tunneling measurements on the superconducting nickelate thin films. We find predominantly two types of tunneling spectra, one shows a V-shape feature which can be fitted well by a d-wave gap function with gap maximum of about 3.9 meV, another one exhibits a full gap of about 2.35 meV. Some spectra demonstrate mixed contributions of these two components. Combining with theoretical calculations, we attribute the d-wave gap to the pairing potential of the [Formula: see text] orbital. Several possible reasons are given for explaining the full gap feature. Our results indicate both similarities and distinctions between the newly found Ni-based superconductors and cuprates.

Antiferromagnetism, charge ordering and stretched Ni-O bond in Ln4Ni3O8 (Ln = La, Nd).

Superconductivity was recently observed in Sr-doped NdNiO2 film after a long pursuit, which inspires us to investigate another Ruddlesden-Popper-based nickelate Nd4Ni3O8 which may hold an antiferromagnetic order and a charge stripe order. Through ab initio calculations, we find that the obtained results turn out to be similar to those of La4Ni3O8. However, we propose that Ni1+ ions in the charge stripe order observed in La4Ni3O8 are in fact antiferromagnetically coupled through a twofold double-exchange mediated by the intermediate Ni2+ ion and the stretched Ni1+-O bond. Under high pressure, the extension of the stretched Ni1+-O bond is not favored and the system will be pushed into a meta-stable insulating state. Our picture can successfully explain the temperature dependence of resistivity under high pressure of La4Ni3O8, and shows also consistency with the insulating behavior of Nd4Ni3O8 observed in recent experiment. Considering a +1.33 average valence of Ni in Nd4Ni3O8, which is very close to that of the Sr-doped NdNiO2, our results support the earlier proposal that a possible way leading to metallicity and even superconductivity is to suppress the existing antiferromagnetism and charge ordering.

Decoupling of itinerant and localized d-orbital electrons in the compound Sc0.5Zr0.5Co.

By using the arc-melting method, we successfully synthesize the compound Sc0.5Zr0.5Co with the space group of Pm-3m. Both the resistivity and magnetic susceptibility measurements reveal a phase transition at about 86 K. This transition might be attributed to the establishment of an antiferromagnetic order. The magnetization hysteresis loop measurements in wide temperature region show a weak ferromagnetic feature, which suggests a possible canted arrangement of the magnetic moments. Bounded by the phase transition temperature, the resistivity at ambient pressure shows a change from Fermi liquid behavior to a super-linear behavior as temperature increases. By applying pressure up to 32.1 GPa, the transition temperature does not show a clear change and no superconductivity is observed above 2 K. The density functional theory calculations simulate the antiferromagnetic order and reveal a gap between the spin-up and spin-down d-orbital electrons. This kind of behavior may suggest that the antiferromagnetic order in this compound originates from the localized d-electrons which do not contribute to the electric conduction. Thus the itinerant and localized d-orbital electrons in the compound are decoupled.

Author Correction: Influence of microstructure on superconductivity in KxFe2-ySe2 and evidence for a new parent phase K2Fe7Se8.

An amendment to this paper has been published and can be accessed via a link at the top of the paper.

Robust Zero Energy Modes on Superconducting Bismuth Islands Deposited on Fe(Te,Se).

Topological superconductivity is one of the frontier research directions in condensed matter physics. One of the unique elementary excitations in topological superconducting state is the Majorana Fermion (mode) which is its own antiparticle and obeys the non-Abelian statistics and is thus useful for constructing the fault-tolerant quantum computation. The evidence for Majorana Fermions (mode) in condensed matter is now quickly accumulated. We deposit Bi islands on the iron-based superconductors Fe(Te,Se) and find the easily achievable zero energy modes on the tunneling spectra on some Bi islands. The zero energy mode is robust and appears everywhere on the island. Temperature and magnetic field dependence of the zero energy mode are also investigated. We attribute these zero energy modes to the Majorana modes due to the proximity effect-induced topological superconductivity on the Bi islands with strong spin-orbit coupling effect.

Directly visualizing the sign change of d-wave superconducting gap in Bi2Sr2CaCu2O8+δ by phase-referenced quasiparticle interference.

The superconducting state is formed by the condensation of Cooper pairs and protected by the superconducting gap. The pairing interaction between the two electrons of a Cooper pair determines the gap function. Thus, it is pivotal to detect the gap structure for understanding the mechanism of superconductivity. In cuprate superconductors, it has been well established that the gap may have a d-wave function. This gap function has an alternative sign change in the momentum space. It is however hard to visualize this sign change. Here we report the measurements of scanning tunneling spectroscopy in Bi2Sr2CaCu2O8+δ and conduct the analysis of phase-referenced quasiparticle interference (QPI). We see the seven basic scattering vectors that connect the octet ends of the banana-shaped contour of Fermi surface. The phase-referenced QPI clearly visualizes the sign change of the d-wave gap. Our results illustrate an effective way for determining the sign change of unconventional superconductors.

Comparative study of vortex dynamics in CaKFe4As4 and Ba0.6K0.4Fe2As2 single crystals.

We investigate the vortex dynamics in two typical hole doped iron based superconductors CaKFe4As4 (CaK1144) and Ba0.6K0.4Fe2As2 (BaK122) with similar superconducting transition temperatures. It is found that the magnetization hysteresis loop exhibits a clear second peak effect in BaK122 in wide temperature region while it is absent in CaK1144. However, a second peak effect of critical current density versus temperature is observed in CaK1144, which is however absent in BaK122. The different behaviors of second peak effect in BaK122 and CaK1144 may suggest distinct origins of vortex pinning in different systems. Magnetization and its relaxation have also been measured by using dynamical and conventional relaxation methods for both systems. Analysis and comparison of the two distinct systems show that the vortex pinning is stronger and the critical current density is higher in BaK122 system. It is found that the Maley's method can be used and thus the activation energy can be determined in BaK122 by using the time dependent magnetization in wide temperature region, but this is not applicable in CaK1144 system. Finally we present the different regimes with distinct vortex dynamics in the field-temperature diagram for the two systems.

Unprecedented high irreversibility line in the nontoxic cuprate superconductor (Cu,C)Ba2Ca3Cu4O11+δ.

One of the key factors that limit the high-power applications for a type II superconductor is the irreversibility line H irr(T), which reflects the very boundary of resistive dissipation in the phase diagram of magnetic field versus temperature. In cuprate family, the Y-, Bi-, Hg-, and Tl-based systems have superconducting transition temperatures exceeding the liquid nitrogen boiling temperature (~77 K). However, the toxic elements Hg and Tl in the latter two systems strongly constrain the applications. The best perspective so far is relying on the YBa2Cu3O7-δ (T c ≈ 90 K) system, which is nontoxic and has a relatively high irreversibility magnetic field. We report the study of a nontoxic superconductor (Cu,C)Ba2Ca3Cu4O11+δ with T c = 116 K. We found that the irreversibility magnetic field is extremely high, and it thus provides great potential for applications above the liquid nitrogen temperature.

Superconductivity with twofold symmetry in Bi2Te3/FeTe0.55Se0.45 heterostructures.

Topological superconductors are an interesting and frontier topic in condensed matter physics. In the superconducting state, an order parameter will be established with the basic or subsidiary symmetry of the crystalline lattice. In doped Bi2Se3 or Bi2Te3 with a basic threefold symmetry, it was predicted, however, that bulk superconductivity with order parameters of twofold symmetry may exist because of the presence of odd parity. We report the proximity effect-induced superconductivity in the Bi2Te3 thin film on top of the iron-based superconductor FeTe0.55Se0.45. By using the quasiparticle interference technique, we demonstrate clear evidence of twofold symmetry of the superconducting gap. The gap minimum is along one of the main crystalline axes following the so-called Δ4y notation. This is also accompanied by the elongated vortex shape mapped out by the density of states within the superconducting gap. Our results provide an easily accessible platform for investigating possible topological superconductivity in Bi2Te3/FeTe0.55Se0.45 heterostructures.