Rational Regulation of High-Voltage Stability in Potassium Layered Oxide Cathodes.

Layered oxide cathode materials may undergo irreversible oxygen loss and severe phase transitions during high voltage cycling and may be susceptible to transition metal dissolution, adversely affecting their electrochemical performance. Here, to address these challenges, we propose synergistic doping of nonmetallic elements and in situ electrochemical diffusion as potential solution strategies. Among them, the distribution of the nonmetallic element fluorine within the material can be regulated by doping boron, thereby suppressing manganese dissolution through surface enrichment of fluorine. Furthermore, in situ electrochemical diffusion of fluorine from the surface into the bulk of the materials after charging reduces the energy barrier of potassium ion diffusion while effectively inhibiting irreversible oxygen loss under high voltage. The modified K0.5Mn0.83Mg0.1Ti0.05B0.02F0.1O1.9 layered oxide cathode exhibits a high capacity of 147 mAh g-1 at 50 mA g-1 and a long cycle life of 2200 cycles at 500 mA g-1. This work demonstrates the efficacy of synergistic doping and in situ electrochemical diffusion of nonmetallic elements and provides valuable insights for optimizing rechargeable battery materials.

Metasurface-Assisted Quantum Nonlocal Weak-Measurement Microscopy.

In standard quantum weak measurements, preselection and postselection of quantum states are implemented in the same photon. Here we go beyond this restrictive setting and demonstrate that the preselection and postselection can be performed in two different photons, if the two photons are polarization entangled. The Pancharatnam-Berry phase metasurface is incorporated in the weak measurement system to perform weak coupling between probe wave function and spin observable. By introducing nonlocal weak measurement into the microscopy imaging system, it allows us to remotely switch different microscopy imaging modes of pure-phase objects, including bright-field, differential, and phase reconstruction. Furthermore, we demonstrate that the nonlocal weak-measurement scheme can prevent almost all environmental noise photons from detection and thus achieves a higher image contrast than the standard scheme at a low photon level. Our results provide the possibility to develop a quantum nonlocal weak-measurement microscope for label-free imaging of transparent biological samples.

Cascaded transflective liquid crystal planar lenses enable multi-plane augmented reality.

In this Letter, we report and experimentally demonstrate the multi-plane augmented reality (AR) by combining the reflective polarization volume lens (PVL) and electrically controlled transmissive Pancharatnam-Berry (PB) liquid crystal (LC) lens. This strategy is based on the electrically controlled power-based approach, which significantly alleviates the challenge of vergence-accommodation conflict (VAC) of the current near-eye display (NED). As a proof of concept, a birdbath architecture dual-plane optical see-through (OST) display was implemented experimentally by changing the power of the lens. The proposed method is expected to be a novel, to the best of our knowledge, NED that is compact, light, and fatigue-free.

Multi-topological state via the Brillouin zone overlap for nonlinear frequency conversion.

Multiband topological edge states (TESs) or topological corner states (TCSs) in photonic crystals provide effective ways to manipulate the nonlinear frequency conversions. However, the deliberate design and the limited number of multibands lead to the difficulty of experimental realization of the topological nonlinear frequency conversion or higher harmonic generation. Here, we propose an effective method to achieve multiple TESs and TCSs by combining the Brillouin zones of multiple different systems. It is shown that the spectra of the subsystems disperse into different energy levels due to the inter-system hopping. Based on this approach, we construct a topological photonic crystal based on the Brillouin zone overlapped SSH model, which enables the overlapped TCSs to participate in nonlinear frequency conversion. Our scheme can provide a significant way to realize the topological nonlinear frequency conversion with double resonances or multiple resonances.

Selectively reflective edge detection system based on cholesteric liquid crystal: publisher's note.

This publisher's note contains corrections to Opt. Lett.48, 795 (2023)10.1364/OL.481980.

Second harmonic generation by matching the phase distributions of topological corner and edge states.

Second harmonic generation (SHG) in topological photonic crystals is chiefly concerned with frequency conversion between the same topological states. However, little attention has been paid to the effect of coupling between different topological states on the SHG. In this study, we propose a method for achieving optimal SHG in a topological cavity by matching the phase distributions of the electric fields of the topological corner state (TCS) and topological edge state (TES). Our results show that the intrinsic efficiency can be improved when the phase distributions of the fundamental wave within the TCS and the second harmonic wave within the TES have the same symmetry. Otherwise, conversion efficiency will be greatly inhibited. With this method, we achieved an optimal intrinsic efficiency of 0.165%. Such a platform may enable the development of integrated nanoscale light sources and on-chip frequency converters.

Optical imprinting subwavelength-period liquid crystal polarization gratings with dual-twist templates.

In this Letter, we report a dual-twist template imprinting method to fabricate subwavelength-period liquid crystal polarization gratings (LCPGs). In other words, the period of the template must be reduced to 800 nm-2 µm, or even smaller. To overcome the inherent problem that the diffraction efficiency shrinks as the period decreases, the dual-twist templates were optimized by rigorous coupled-wave analysis (RCWA). With the help of the rotating Jones matrix to measure the twist angle and thickness of the LC film, the optimized templates were fabricated eventually, and the diffraction efficiencies were up to 95%. Therefore, subwavelength-period LCPGs with a period of 400-800 nm were imprinted experimentally. Our proposed dual-twist template provides the possibility for fast, low-cost, and mass fabrication of large-angle deflectors and diffractive optical waveguides for near-eye displays.

Electronic and surface modulation of 2D MoS2nanosheets for an enhancement on flexible thermoelectric property.

Two-dimensional materials have potential applications for flexible thermoelectric materials because of their excellent mechanical and unique electronic transport properties. Here we present a functionalization method by a Lewis acid-base reaction to modulate atomic structure and electronic properties at surface of the MoS2nanosheets. By AlCl3solution doping, the lone pair electronics from S atoms would enter into the empty orbitals of Al3+ions, which made the Fermi level of the 1T phase MoS2move towards valence band, achieving a 1.8-fold enhancement of the thermoelectric power factor. Meanwhile, benefiting from the chemical welding effect of Al3+ions, the mechanical flexibility of the nanosheets restacking has been improved. We fabricate a wearable thermoelectric wristband based on this improved MoS2nanosheets and achieved 5 mV voltage output when contacting with human body. We think this method makes most of the transition metal chalcogenides have great potential to harvest human body heat for supplying wearable electronic devices due to their similar molecular structure.

Topological plasmons in stacked graphene nanoribbons.

In this Letter, we theoretically study the topological plasmons in Su-Schrieffer-Heeger (SSH) model-based graphene nanoribbon (GNR) layers. We find that for the one-dimensional (1D) stacked case, only two topological modes with the field localized in the top or bottom layer are predicted to exist by the Zak phase. When we further expand the stacked 1D GNR layers to two-dimensional (2D) arrays in the in-plane direction, the topology is then characterized by the 2D Zak phase, which predicts the emergence of three kinds of topological modes: topological edge, surface, and corner modes. For a 2D ribbon array with Nx × Ny units, there are 4(Ny - 1), 4(Nx - 1), and 4 topological edge, surface, and corner modes, and the field is highly localized at the edge/surface/corner ribbons. This work offers a platform to realize topological modes in GNRs and could be important for the design of topological photonic devices such as lasers and sensors.

Selectively reflective edge detection system based on cholesteric liquid crystal.

Optical analog computing has attracted extensive interest in image processing and optical engineering in recent decades. Here, we propose a reflective optical analog computing system based on a cholesteric liquid crystal (CLC), which simplifies the traditional optical analog computing system by taking advantage of the CLC reflecting the light with specified circular polarization and provides a new, to the best of our knowledge, idea for the integration of optical analog computing systems. Meanwhile, we present results in which a section of an insect foot is observed using the reflective optical analog computing system, which may develop valuable applications in biomedical imaging.

Phase-engineered cathode for super-stable potassium storage.

The crystal phase structure of cathode material plays an important role in the cell performance. During cycling, the cathode material experiences immense stress due to phase transformation, resulting in capacity degradation. Here, we show phase-engineered VO2 as an improved potassium-ion battery cathode; specifically, the amorphous VO2 exhibits superior K storage ability, while the crystalline M phase VO2 cannot even store K+ ions stably. In contrast to other crystal phases, amorphous VO2 exhibits alleviated volume variation and improved electrochemical performance, leading to a maximum capacity of 111 mAh g-1 delivered at 20 mA g-1 and over 8 months of operation with good coulombic efficiency at 100 mA g-1. The capacity retention reaches 80% after 8500 cycles at 500 mA g-1. This work illustrates the effectiveness and superiority of phase engineering and provides meaningful insights into material optimization for rechargeable batteries.

Computing metasurfaces enabled chiral edge image sensing.

Computing metasurfaces have shown the extraordinary ability to precisely perform optical analog operations to the input light wave, and therefore exhibit greater potentials toward sensing applications. Here, we propose a unique application of computing metasurface for chiral edge sensing by incorporating a weak-value amplification technique. The computing metasurface performs the spatial differentiation operations of phase objects and extracts the edge-enhanced images, because the phase gradient generally occurs at the edge. The chirality-induced polarization rotation acts as the preselection state and the spatial differentiation operations in the metasurface provide weak coupling. The amplified pointer shift related to the tiny polarization rotation will eventually lead to an asymmetric edge-enhanced image. Owing to the high sensitivity of the weak-value amplification, we experimentally demonstrate a high-contrast recognition of chirality by edge detection, which may have potential applications in real-time measurement and separation of chiral enantiomers.

Intrinsic Optical Spatial Differentiation Enabled Quantum Dark-Field Microscopy.

By solving the Maxwell's equations in Fourier space, we find that the cross-polarized component of the dipole scattering field can be written as the second-order spatial differentiation of the copolarized component. This differential operation can be regarded as intrinsic which naturally arises as consequence of the transversality of electromagnetic fields. By introducing the intrinsic spatial differentiation into heralded single-photon microscopy imaging technique, it makes the structure of pure-phase object clearly visible at low photon level, avoiding any biophysical damages to living cells. Based on the polarization entanglement, the switch between dark-field imaging and bright-field imaging is remotely controlled in the heralding arm. This research enriches both fields of optical analog computing and quantum microscopy, opening a promising route toward a nondestructive imaging of living biological systems.

Examining the optical model of graphene via the photonic spin Hall effect.

In modern optics, there are two general models to describe the behavior of light in graphene: the zero-thickness model and the slab model. The difference in physical phenomena predicted by the two models is very small, which is hardly distinguished by traditional measurement methods. Therefore, which model can describe the light-matter interaction in graphene more exactly is still a challenging issue. In this work, based on the sensitive optical phenomenon called the photonic spin Hall effect, the small difference can be magnified to a detectable level by the weak-value amplification. The experimental results show that the zero-thickness model can more accurately describe the interaction between light and monolayer or bilayer graphene, while the case of more than two layers, which can no longer be regarded as two-dimensional thickness, should be described by the slab model. Our results may provide information on light interacting with graphene for future investigation in photonics and optoelectronics.

Low-voltage-driven liquid crystal scattering-controllable device based on defects from rapidly varying boundary.

In this work, we disclose a method to fabricate an electronically tunable liquid crystal (LC) device that can switch between scattering and transparent state. The light scattering domain is attributed to defects from a rapidly varying boundary based on planar random photo-alignment. Distinct from the LC/polymer composite or haze-control LC elements based on patterned electrodes or a well-designed mask, there is no requirement for a complicated process or other auxiliary additives, as only positive dielectric nematic LCs are required. The device exhibits low driving voltage, small power consumption, and good ability to hide images, where the transparent state only needs a supply of 10 Vrms to offer 7.8% of haze, while with 1.1 Vrms, the device provides 58.7% of haze. The good performance and simple fabrication process reveal enormous promising applications in energy-conservation building, privacy protection, and transparent display.

Two-dimensional optical spatial differentiation and high-contrast imaging.

Optical analog signal processing technology has been widely studied and applied in a variety of science and engineering fields, with the advantages of overcoming the low-speed and high-power consumption associated with its digital counterparts. Much attention has been given to emerging metasurface technology in the field of optical imaging and processing systems. Here, we demonstrate, for the first time, broadband two-dimensional spatial differentiation and high-contrast edge imaging based on a dielectric metasurface across the whole visible spectrum. This edge detection method works for both intensity and phase objects simply by inserting the metasurface into a commercial optical microscope. This highly efficient metasurface performing a basic optical differentiation operation opens up new opportunities in applications of fast, compactible and power-efficient ultrathin devices for data processing and biological imaging.

Dynamically reconfigurable topological states in photonic crystals with liquid crystals.

Dynamically tunable and reconfigurable topological states are realized in higher-order topological insulators with the liquid crystal (LC). By changing the loading voltage of the LC, the eigenfrequency of the edge and corner states can be tuned, but even more important is that the edge state and corner state with the same frequency are realized. Based on this reconfigurability of topological states, optical routers and lasers with multiple topological states can be realized. Our results may be applied to topological optical circuits and provide new ideas for optical field localization and manipulation.

Metasurface enabled quantum edge detection.

Metasurfaces consisting of engineered dielectric or metallic structures provide unique solutions to realize exotic phenomena including negative refraction, achromatic focusing, electromagnetic cloaking, and so on. The intersection of metasurface and quantum optics may lead to new opportunities but is much less explored. Here, we propose and experimentally demonstrate that a polarization-entangled photon source can be used to switch ON or OFF the optical edge detection mode in an imaging system based on a high-efficiency dielectric metasurface. This experiment enriches both fields of metasurface and quantum optics, representing a promising direction toward quantum edge detection and image processing with remarkable signal-to-noise ratio.

Optical analog computing of two-dimensional spatial differentiation based on the Brewster effect.

Optical analog computing has attracted widespread attention in recent decades due to its advantages of lower consumption, higher efficiency, and real-time imaging in image processing. Here, we propose a two-dimensional optical analog computing scheme based on the Brewster effect. We experimentally demonstrate two-dimensional edge detection with high efficiency. By combining microscopy, our approach may develop some significant applications in cellular and molecular imaging.

Liquid crystal bifocal lens with adjustable intensities through polarization controls.

In this Letter, transverse and longitudinal liquid crystal bifocal lenses (LCBLs) are proposed to continuously control the relative intensity of two foci through a simple polarization control. The modulation of a LCBL comes from the geometric phase control and is designed through the principle of holography, where the object wave is a light field from two foci respectively formed by the left-circular polarized (LCP) and right-circular polarized (RCP) light, and the reference wave is the incident plane wave. Constructed millimeter-scale LCBLs are verified experimentally, and the foci are precisely formed at the preset plane. Besides, the relative intensity can be easily controlled with different weights of LCP and RCP light. The proposed strategy overcomes the shortcomings of previous bifocal lenses, such as a complex design method, a long optimization time, and an unchangeable relative intensity, and it is expected to find potential applications in parallel optical processing and optical interconnections.