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1.
Spectrochim Acta A Mol Biomol Spectrosc ; 271: 120918, 2022 Apr 15.
Artigo em Inglês | MEDLINE | ID: mdl-35093820

RESUMO

In the context of the circular economy, the sorting process during recycling of polymers is essential as regards the efficiency of the process itself and the quality of the so-obtained recycled materials. In this paper, the application of Hyperspectral Imaging (HSI) is proposed for this purpose, providing additional insight into the state of aging and the polymer quality. The underlying study comprises HSI in the wavelength range of 1115-1678 nm considering artificially aged Styrene-Butadiene-Styrene (SBS), where aging is performed for 2, 5, 10, 15 and 20 days in a forced-draft oven at a temperature of 105 °C. The obtained HSI spectra are normalized using the Standard Normal Variate (SNV) method, with the normalized spectra as well as their first and second derivative entering the modeling attempt for SBS aging. For the latter, different partial least squares regression (PLSR) models are evaluated, where the original spectra achieved a correlation of R2=0.94 and a root mean squared error of prediction (RMSEP) of 1.83 days, showing the suitability of HSI for the proper identification of the state of aging of SBS and its potential use for other polymers.


Assuntos
Butadienos , Estireno , Imageamento Hiperespectral , Análise dos Mínimos Quadrados
2.
Hist Psychol ; 25(4): 322-341, 2022 11.
Artigo em Inglês | MEDLINE | ID: mdl-35084913

RESUMO

This article presents a contextualization and revaluation of competing narratives concerning the history of psychology in Nazi Germany. Since the 1980s, this debate revolves around the supposed "professionalization" of the discipline from Hitler's rise to power until the end of World War II. The question whether or not academic psychology has profited from collaborating with the Nazi regime during the war is not just of historical interest, but also carries strong political and moral implications. Recently, the established narrative concerning the professionalization of German psychology under National Socialism was called into question by Wolfgang Schönpflug. According to his argumentation, psychology did not benefit from the war, but had to suffer considerable losses on terms of personnel and quality in teaching and research. After reconstructing the historical context and the political implications of the debate, we propose to take a different perspective on the question of "professionalization." Three case examples of psychologists from Austria whose career advanced significantly during the war are provided to shed light on the multitude of opportunities that emerged for those who offered their psychological expertise during the war. In conclusion, it is argued that professionalization should be understood as a theoretical framework that stimulates further historical research on a local level, not as a dogmatic judgment about the state of the discipline as a whole. (PsycInfo Database Record (c) 2022 APA, all rights reserved).


Assuntos
Socialismo Nacional , II Guerra Mundial , História do Século XX , Socialismo Nacional/história , Alemanha , Princípios Morais , Áustria
3.
Materials (Basel) ; 14(5)2021 Mar 08.
Artigo em Inglês | MEDLINE | ID: mdl-33800143

RESUMO

The aim of this work is to determine the influence of the bitumen chemistry on the rheological performance of bitumen and polymer modified bitumen (PmB), as well as the polymer distribution and storage stability. Six different bitumens and their 5 wt.% SBS mixtures are considered in this work. The bitumen composition was determined by SARA fractioning, which was then correlated with the glass transition temperature, complex modulus |G*|, and phase angle, which were obtained by parallel-plate dynamic shear rheology in the temperature range of -25 to 65 °C. The polymer distribution, which was derived from fluorescence microscopy images and the storage stability (determined by tube test) also correlated with the SARA fractions. It was found that the saturates decrease |G*| and Tg and increase the phase angle in crude bitumen, while the asphaltenes increase |G*| and the phase angle. For PmB, the amount of swelling was determined by the saturate content of bitumen. The glass transition temperature of PmBs increases for low saturate and decreases for high saturate contents. |G*| and the phase angle of PmBs correlates with the saturate content, with a varying influence depending on a high or low saturate content and the temperature range due to saturate depletion in the bitumen-rich phase and the varying vol% polymer-rich phase. The aromatic and resin fractions show no correlation in the considered bitumens and PmBs.

4.
Hist Psychol ; 22(1): 107-109, 2019 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-30714787

RESUMO

Forty years after the end of World War II, historians and psychologists finally began to thoroughly investigate the involvement of psychological theory and practice with the National-Socialist regime. After this first wave of critical self-reflection, however, very little systematic work has been done to expand our historical knowledge of the darkest chapter in the history of German psychology. As part of a running project on the history of psychology during National Socialism in Austria, the Sigmund Freud Private University (SFU) Berlin hosted a 2-day conference about this topic that was open to the general public. (PsycINFO Database Record (c) 2019 APA, all rights reserved).

5.
Hist Psychol ; 21(1): 1-32, 2018 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-28650182

RESUMO

This article presents a historical analysis of the origins, rise, and demise of theories of stratification (Schichtentheorien). Following their roots in the ancient metaphysical idea of the "great chain of being," Aristotle's scala naturae, the medieval "Jacob's ladder," and Leibniz's concept of the lex continua, I argue that theories of stratification represent the modern heir to the ancient cosmological idea of a harmonious, hierarchical, and unified universe. Theories of stratification reached their heyday during the interwar period within German academia, proliferating over a vast number of disciplines and rising to special prominence within personality psychology, feeding the hope for a unitary image of the world and of human beings, their biological and mental development, their social organization and cultural creations. This article focuses on the role of visuality as a distinct mode of scientific knowledge within theories of stratification as well as the cultural context that provided the fertile ground for their flowering in the Weimar Republic. Finally, the rapid demise of theories of stratification during the 1950s is discussed, and some reasons for their downfall during the second half of the 20th century are explored. (PsycINFO Database Record

6.
J Hist Behav Sci ; 54(1): 43-61, 2018 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-29244200

RESUMO

This paper presents a historical analysis of the genesis, context, and function of "Operative Psychology," a little-known branch of applied psychology developed by employees of the Ministry of State Security in the German Democratic Republic. For 25 years, theories and practices of Operative Psychology were taught to elite agents at the Juridical Academy in Potsdam, introducing them to various "silent" psychological techniques of persuasion, interrogation, and repression. After highlighting the economic and political context that increased the need for "silent" techniques of observation and repression, an overview of the topics that were taught and researched at the chair for Operative Psychology is given. Examples of how these techniques were put into practice are provided and the consequences for the victims of Operative Psychology are discussed. Furthermore, commonalities and differences between Operative Psychology and the use of psychological torture by the CIA during the "war on terror" are discussed and questions regarding the relation between methodological and moral strategies of justification are addressed.


Assuntos
Comunicação Persuasiva , Psicologia/história , Tortura/história , Alemanha Oriental , História do Século XX , Humanos , Pesquisa , Estados Unidos
7.
Front Plant Sci ; 7: 222, 2016.
Artigo em Inglês | MEDLINE | ID: mdl-26973668

RESUMO

The goal of the study was to determine circadian movements of silver birch (Petula Bendula) branches and foliage detected with terrestrial laser scanning (TLS). The study consisted of two geographically separate experiments conducted in Finland and in Austria. Both experiments were carried out at the same time of the year and under similar outdoor conditions. Experiments consisted of 14 (Finland) and 77 (Austria) individual laser scans taken between sunset and sunrise. The resulting point clouds were used in creating a time series of branch movements. In the Finnish data, the vertical movement of the whole tree crown was monitored due to low volumetric point density. In the Austrian data, movements of manually selected representative points on branches were monitored. The movements were monitored from dusk until morning hours in order to avoid daytime wind effects. The results indicated that height deciles of the Finnish birch crown had vertical movements between -10.0 and 5.0 cm compared to the situation at sunset. In the Austrian data, the maximum detected representative point movement was 10.0 cm. The temporal development of the movements followed a highly similar pattern in both experiments, with the maximum movements occurring about an hour and a half before (Austria) or around (Finland) sunrise. The results demonstrate the potential of terrestrial laser scanning measurements in support of chronobiology.

8.
Integr Psychol Behav Sci ; 50(3): 359-67, 2016 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-26910038

RESUMO

This paper discusses the need for contextualization and reflection of psychological theorizing within its respective cultural and historical context. By acknowledging the anthropological assumptions which form a key part of every psychological theory and connect psychological thinking with broader cultural values, norms, ideals and meanings, psychologists can gain a deeper understanding of the limits of their own theories. It is argued that the prolonged debate within academic psychology concerning its status and methodology which became famous as "psychology's crisis" is an effect of the neglect of these implicit anthropological assumptions. Especially as cultural and cultural-historical psychologists, we should avoid the improper universalization of particular models of what defines a human being.


Assuntos
Antropologia Cultural/normas , Teoria Psicológica , Psicologia/normas , Antropologia Cultural/tendências , Humanos , Psicologia/tendências
9.
Science ; 347(6220): aaa0571, 2015 Jan 23.
Artigo em Inglês | MEDLINE | ID: mdl-25613894

RESUMO

The Rosetta mission shall accompany comet 67P/Churyumov-Gerasimenko from a heliocentric distance of >3.6 astronomical units through perihelion passage at 1.25 astronomical units, spanning low and maximum activity levels. Initially, the solar wind permeates the thin comet atmosphere formed from sublimation, until the size and plasma pressure of the ionized atmosphere define its boundaries: A magnetosphere is born. Using the Rosetta Plasma Consortium ion composition analyzer, we trace the evolution from the first detection of water ions to when the atmosphere begins repelling the solar wind (~3.3 astronomical units), and we report the spatial structure of this early interaction. The near-comet water population comprises accelerated ions (<800 electron volts), produced upstream of Rosetta, and lower energy locally produced ions; we estimate the fluxes of both ion species and energetic neutral atoms.

10.
Hist Psychol ; 17(2): 83-104, 2014 May.
Artigo em Inglês | MEDLINE | ID: mdl-24818739

RESUMO

It is argued that Frederic Bartlett's views on the social and cultural determinants of remembering and recognition provide a useful background for analyzing the transformations of psychological concepts and images when they are introduced into new academic collectives. An example of a "Bartlettian" view on the history of psychology is given by reconstructing and contextualizing the transformation of the "lens," a model of human perception that was invented by Fritz Heider in the 1920s and adopted by Egon Brunswik from the 1930s onwards. Heider's early work suggested a new perspective on the epistemological relation between subject, media, and object that was devised to create a new conceptual foundation for academic psychology. Brunswik, on the other hand, transformed Heider's "lens" into a clear-cut experimental framework that was based on the physicalist and operationalist demands of logical empiricism, the movement for the "unity of science," and, after his migration to Berkeley, neobehaviorism. This episode provides many similarities with Bartlett's theory of the social determinants of knowledge and the shaping power of collective presuppositions, norms, and ideals.


Assuntos
Formação de Conceito/fisiologia , Psicologia/história , Percepção Visual/fisiologia , História do Século XX , Humanos
11.
Med Biol Eng Comput ; 52(1): 53-64, 2014 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-24096595

RESUMO

Cardiovascular deconditioning has long been recognized as a characteristic of the physiological adaptation to long-term bed rest in patients. The process is thought to contribute to orthostatic intolerance and enhance secondary complications in a significant way. Mobilization is a cost-effective and simple method to maintain the cardiovascular parameters (i.e., blood pressure, heart rate) stable, counter orthostatic intolerance and reduce the risk of secondary problems in patients during long-term immobilization. The aim of this project is to control the cardiovascular parameters such as heart rate and blood pressure of bed rest patients via automated leg mobilization and body tilting. In a first step, a nonlinear model predictive control strategy was designed and evaluated on five healthy subjects and 11 bed rest patients. In a next step, a clinically feasible study was conducted on two patients. The mean values differed on average less than 1 bpm from the predetermined heart rate and less than 2.5 mmHg from the desired blood pressure values. These results of the feasibility study are promising, although heterogeneous disease etiologies and individual medication strongly influence the mechanically induced reactions. The long-term goal is an automation of the control of physiological signals and the mobilization of bed rest patients in an early phase of the rehabilitation process. Therefore, this new approach could help to strengthen the cardiovascular system and prevent secondary health problems arising from long-term bed rest.


Assuntos
Repouso em Cama/efeitos adversos , Sistema Cardiovascular/fisiopatologia , Adulto , Idoso , Idoso de 80 Anos ou mais , Leitos , Pressão Sanguínea/fisiologia , Descondicionamento Cardiovascular/fisiologia , Feminino , Frequência Cardíaca/fisiologia , Humanos , Masculino , Pessoa de Meia-Idade , Adulto Jovem
12.
J Hist Behav Sci ; 49(3): 259-80, 2013.
Artigo em Inglês | MEDLINE | ID: mdl-23696225

RESUMO

While numerous historiographical works have been written to shed light on Freud's early theoretical education in biology, physiology, and medicine and on the influence of that education on psychoanalysis, this paper approaches Freud's basic comprehension of science and methodology by focusing on his early research practice in physiology and neuranatomy. This practice, taking place in the specific context of Ernst Brücke's physiological laboratory in Vienna, was deeply concerned with problems of visuality and the revelation of hidden organic structures by use of proper preparation techniques and optical instruments. The paper explores the connection between such visualizing practices, shaped by a physiological context as they were, and Freud's later convictions of the scientific status of psychoanalysis and the function of its method as means to unveil the concealed structure of the "psychical apparatus".


Assuntos
Psicanálise/história , Áustria , História do Século XX , Humanos , Microscopia/história , Neuroanatomia/história , Fisiologia/história
13.
J Neuroeng Rehabil ; 9: 30, 2012 May 30.
Artigo em Inglês | MEDLINE | ID: mdl-22647145

RESUMO

Clinical scores represent the gold standard in characterizing the clinical condition of patients in vegetative or minimally conscious state. However, they suffer from problems of sensitivity, specificity, subjectivity and inter-rater reliability.In this feasibility study, objective measures including physiological and neurophysiological signals are used to quantify the clinical state of 13 low-responsive patients. A linear regression method was applied in nine patients to obtain fixed regression coefficients for the description of the clinical state. The statistical model was extended and evaluated with four patients of another hospital. A linear mixed models approach was introduced to handle the challenges of data sets obtained from different locations.Using linear backward regression 12 variables were sufficient to explain 74.4% of the variability in the change of the clinical scores. Variables based on event-related potentials and electrocardiogram account for most of the variability.These preliminary results are promising considering that this is the first attempt to describe the clinical state of low-responsive patients in such a global and quantitative way. This new model could complement the clinical scores based on objective measurements in order to increase diagnostic reliability. Nevertheless, more patients are necessary to prove the conclusions of a statistical model with 12 variables.


Assuntos
Testes Neuropsicológicos , Estado Vegetativo Persistente/diagnóstico , Estado Vegetativo Persistente/fisiopatologia , Adulto , Estudos de Viabilidade , Feminino , Humanos , Masculino , Pessoa de Meia-Idade , Adulto Jovem
14.
Isotopes Environ Health Stud ; 46(3): 299-311, 2010 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-20812118

RESUMO

(3)H-(3)He measurements constitute a well-established method for the determination of the residence time of young groundwater. However, this method has rarely been applied to karstified aquifers and in particular to drip water in caves, despite the importance of the information which may be obtained. Besides the determination of transfer times of climate signals from the atmosphere through the epikarst to speleothems as climate archives, (3)H-(3)He together with Ne, Ar, Kr, Xe data may also help to give new insights into the local hydrogeology, e.g. the possible existence of a perched aquifer above a cave. In order to check the applicability of (3)H-(3)He dating to cave drips, we collected drip water samples from three adjacent caves in northwestern Germany during several campaigns. The noble gas data were evaluated by inverse modelling to obtain recharge temperature and excess air, supporting the calculation of the tritiogenic (3)He and hence the (3)H-(3)He age. Although atmospheric noble gases were often found to be close to equilibrium with the cave atmosphere, several drip water samples yielded an elevated (3)He/(4)He ratio, providing evidence for the accumulation of (3)He from the decay of (3)H. No significant contribution of radiogenic (4)He was found, corresponding to the low residence times mostly in the range of one to three years. Despite complications during sampling, conditions of a perched aquifer could be confirmed by replicate samples at one drip site. Here, the excess air indicator ΔNe was about 10 %, comparable to typical values found in aquifers in mid-latitudes. The mean (3)H-(3)He age of 2.1 years at this site presumably refers to the residence time in the perched aquifer and is lower than the entire transit time of 3.4 years estimated from the tritium data.


Assuntos
Sedimentos Geológicos , Hélio/análise , Trítio/análise , Movimentos da Água , Poluentes Químicos da Água/análise , Abastecimento de Água/análise , Atmosfera/química , Cronologia como Assunto , Clima , Isótopos/análise , Medição de Risco , Temperatura , Abastecimento de Água/normas
15.
Artigo em Inglês | MEDLINE | ID: mdl-19963765

RESUMO

We implemented a model for prediction of heart rate during Lokomat walking. Using this model, we can predict potential overstressing of the patient and adapt the physical load accordingly. Current models for treadmill based heart rate control neglect the fact that the interaction torques between Lokomat and human can have a significant effect on heart rate. Tests with five healthy subjects lead to a model of sixth order with walking speed and power expenditure as inputs and heart rate prediction as output. Recordings with five different subjects were used for model validation. Future work includes model identification and predictive heart rate control with spinal cord injured and stroke patients.


Assuntos
Frequência Cardíaca , Modelos Teóricos , Caminhada , Humanos , Reprodutibilidade dos Testes
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