Complex Dielectric Permittivity Spectra of Rapeseed in the 20 MHz-3 GHz Frequency Range.

Rapeseed is one of the most important sources of vegetable oil worldwide. Knowledge of the dielectric properties of rapeseed may be beneficial for moisture content determination and the optimization of microwave treatment processes. The aim of this research was to examine the complex dielectric permittivity spectra of rapeseed of moisture content from 8.3% to 16.1%. The measurements were performed in the 20 MHz-3 GHz frequency range with the use of a vector network analyzer and a coaxial transmission-line cell. The real part of dielectric permittivity significantly depended on the water content of the seeds. The obtained spectra were modeled with the use of a three-pole Debye model with bulk electrical conductivity. Because the highest-frequency pole was found near the high-frequency measurement band limit, the spectra were additionally modeled with the use of an approximate ABC model with two in-band Debye poles. The determined model parameters were found to be highly dependent on the water content of the seeds. The relations between these parameters and water content were analyzed.

Analysis of the need for soil moisture, salinity and temperature sensing in agriculture: a case study in Poland.

Efficient use of scarce water resources is both a marketing objective and an environmental obligation for sustainable agriculture. In modern agricultural production, which is intensive and should at the same time be environmentally friendly, there is a need to monitor soil moisture, salinity and temperature. The aim of the study was to determine the demand of producers of agricultural and horticultural plants for equipment and systems for monitoring soil properties at an individual farm level in regions with highly developed agriculture. A questionnaire survey was conducted among 1087 respondents, also direct interviews in Poland were undertaken. According to the producers' responses, it is important to know soil moisture, salinity and temperature, although currently only about 4% of the surveyed farmers have the equipment to evaluate these soil parameters. In their view cost is not the most important obstacle to the purchase of the necessary probes. More important is that the devices should be easy to install and use, and have an easy to use application for data collection, processing and transfer. The current market does not offer solutions that meet these producers expectations. The demand for suitable probes is very high as over 80% of the farmers declared their willingness to purchase such probes. Technical problems related to the operation and servicing of such equipment were the most frequently mentioned impediments in their use. However, farmers and horticulturists believe that knowledge of their soil properties would allow them to optimize the elements of cultivation technology, including the use of plant irrigation systems, the use of mineral fertilizers and plant protection products.

Dielectric Properties of Glass Beads with Talc as a Reference Material for Calibration and Verification of Dielectric Methods and Devices for Measuring Soil Moisture.

This paper presents dielectric measurements of talc, glass beads, and their mixtures under different moisture and salinity levels. The measurements were conducted using a prototype seven-rod probe (15 mm long central rod) connected to a single port of vector network analyzer. The samples were moistened with distilled water and KCl solutions in order to obtain six different moisture content levels. The complex dielectric permittivity was determined from vector network analyzer reflection-coefficient measurements based on the open-water-liquid calibration procedure. Next, the fitting of volumetric water content-real part of dielectric permittivity calibration curves was performed for each material at selected frequencies, and the obtained relations were compared with well-known calibration equations. Additionally, a salinity index for the tested materials was calculated. It was concluded that pure talc is not an optimal material for the calibration and verification of dielectric methods. The calibration curves obtained for glass beads and the mixtures of glass beads with talc gave results close to well-known reference calibration functions. Additionally, the addition of talc caused the data points to be less scattered. Moreover, the values of the salinity index for the tested materials were in a good agreement with literature data for sand. The obtained results indicated that glass beads with the addition of talc can be used as a reference material for the calibration and verification of dielectric methods and devices for soil moisture measurement.

Application of a Monopole Antenna Probe with an Optimized Flange Diameter for Tdr Soil Moisture Measurement.

Soil volumetric water content (θ) is a parameter describing one of the most important factors conditioning proper plant growth. Monitoring soil moisture is of particular importance in the rational use of water resources for irrigation, especially during periods of water scarcity. This paper presents a method of measuring soil moisture in the vicinity of the plant root system by means of a probe designed to be mounted on a mobile device used for precise plant irrigation. Due to the specific field conditions of the measurement, the design of the probe was proposed as a monopole antenna. Electromagnetic simulations of the probe were carried out with Ansys HFSS software to optimise its dimensions. Then a prototype of the probe was manufactured to conduct laboratory measurements with the use of a vector network analyser (VNA) working in the 20 kHz to 8 GHz frequency range. The VNA analyser was configured to work in the time-domain reflectometry (TDR) mode. From measurements of the time distance between reflections from the probe's elements it is possible to calculate the bulk dielectric permittivity of the soil surrounding the probe. Next, based on commonly used soil moisture dielectric calibrations one can determine θ of the soil sample. The paper presents simulation results and laboratory tests of an antenna probe. Due to its tough and durable design, this type of probe gives the possibility of easy application in field conditions, which makes it especially suitable for mechanically demanding measurement systems. As the sensitivity zone is comparatively large, this probe is well-suited to measuring soil moisture in the vicinity of the plant root system.

Penetration Depth of a Soil Moisture Profile Probe Working in Time-Domain Transmission Mode.

Soil moisture is one of the most important soil parameters. Knowledge of volumetric water content (VWC) of the root zone as well as the VWC dynamics in the soil profile is especially important for agriculture. Monitoring VWC at several depths in the soil profile can be performed using several soil moisture sensors placed at various depths. However, the use of a profile probe is more convenient, because the installation of a single probe is less disturbing to the soil, as well as less laborious and more cost-effective. The objective of the paper is to present the design and performance of a novel profile probe working in the time-domain transmission mode (P-TDT probe) with emphasis put on the penetration depth and sensitivity zone. The performance of the probe was assessed with the use of finite element method (FEM) simulations in the frequency domain, transient simulations in the time domain and laboratory experiments with the use of a vector network analyzer (VNA) working in the 10 MHz-10 GHz frequency range. It was concluded that the effective soil volume measured by the profile probe of a given geometry is equivalent to a soil thickness of about 20 mm around the tested probe. The internal part of the probe body had a negligible effect on the measurement results, as it does not change with soil moisture. Moreover, the transmitted signal amplitude was related to the soil electrical conductivity.

A Seven-Rod Dielectric Sensor for Determination of Soil Moisture in Well-Defined Sample Volumes.

This paper presents a novel seven-rod sensor used for time-domain reflectometry (TDR) and frequency-domain reflectometry (FDR) measurements of soil water content in a well-defined sample volume. The probe directly measures the complex dielectric permittivity spectrum and for this purpose requires three calibration media: air, water, and ethanol. Firstly, electromagnetic simulations were used to study the influence of the diameter of a container on the sensitivity zone of the probe with respect to the measured calibration media and isopropanol as a verification liquid. Next, the probe was tested in three soils-sandy loam and two silt loams-with six water contents from air-dry to saturation. The conversion from S 11 parameters to complex dielectric permittivity from vector network analyzer (VNA) measurements was obtained using an open-ended liquid procedure. The simulation and measurement results for the real part of the isopropanol dielectric permittivity obtained from four containers with different diameters were in good agreement with literature data up to 200 MHz. The real part of the dielectric permittivity was extracted and related to the moisture of the tested soil samples. Relations between the volumetric water content and the real part of the dielectric permittivity (by FDR) and apparent dielectric permittivity (by TDR) were compared with Topp's equation. It was concluded that the best fit to Topp's equation was observed in the case of a sandy loam. Data calculated according to the equation proposed by Malicki, Plagge, and Roth gave results closer to Topp's calibration. The obtained results indicated that the seven-rod probe can be used to accurately measure of the dielectric permittivity spectrum in a well-defined sample volume of about 8 cm³ in the frequency range from 20 MHz to 200 MHz.

Evaluation of Apple Maturity with Two Types of Dielectric Probes.

The observed dielectric spectrum of ripe apples in the last period of shelf-life was analyzed using a multipole dielectric relaxation model, which assumes three active relaxation processes: primary α-process (water relaxation) and two secondary processes caused by solid-water-ion interactions α' (bound water relaxations), as well as ß' (Maxwell-Wagner effect). The performance of two designs of the dielectric probe was compared: a classical coaxial open-ended probe (OE probe) and an open-ended probe with a prolonged central conductor in a form of an antenna (OE-A-probe). The OE-A probe increases the measurement volume and consequently extends the range of applications to other materials, like granulated agricultural products, soils, or liquid suspensions. However, its measurement frequency range is limited as compared to the OE probe because, above 1.5 GHz, the probe with the antenna generates higher propagation modes and the applied calibrations and calculations are not sufficient. It was shown that data from measurements using the OE-A probe gave slightly stronger correlations with apples' quality parameters than using the typical OE probe. Additionally, we have compared twelve multipole fitting models with different combinations of poles (eight three-pole and four two-pole models). It was shown that the best fit is obtained using a two-pole model for data collected for the OE-A probe and a three-pole model for the OE probe, using only Cole-Cole poles in both cases.

A Time-Domain Reflectometry Method with Variable Needle Pulse Width for Measuring the Dielectric Properties of Materials.

Time-domain reflectometry (TDR) methods used for measuring the dielectric properties of materials mostly utilize step or needle electrical pulses of constant amplitudes and shapes. Our novel approach enables determining the dielectric relaxation time of a sample using the analysis of the amplitudes of reflected pulses of two widths, in addition to bulk dielectric permittivity and electrical conductivity commonly obtained by the TDR technique. The method was developed for various values of electrical conductivity and relaxation time using numerical simulations of a five-rod probe placed in a material with complex dielectric permittivity described by the Debye model with an added electrical conductivity term. The characterization of amplitudes of two pulses of selected widths was done with regard to the dielectric parameters of simulated materials. The required probe parameters were obtained solely from numerical simulations. Verification was performed for the probe placed in aqueous KCl solutions with 14 different electrical conductivity values. The determined relaxation time remained roughly constant and independent of electrical conductivity. The obtained electrical conductivity agreed with the reference values. Our results indicate that the relaxation time, dielectric permittivity and electrical conductivity of the tested solutions can be simultaneously determined using a simple analysis of the amplitude and reflection time of two needle pulses of different widths.

TDR Technique for Estimating the Intensity of Evapotranspiration of Turfgrasses.

The paper presents a method for precise estimation of evapotranspiration of selected turfgrass species. The evapotranspiration functions, whose domains are only two relatively easy to measure parameters, were developed separately for each of the grass species. Those parameters are the temperature and the volumetric moisture of soil at the depth of 2.5 cm. Evapotranspiration has the character of a modified logistic function with empirical parameters. It assumes the form ETR(θ (2.5 cm), T (2.5 cm)) = A/(1 + B · e (-C · (θ (2.5 cm) · T (2.5 cm)), where: ETR(θ (2.5 cm), T (2.5 cm)) is evapotranspiration [mm · h(-1)], θ (2.5 cm) is volumetric moisture of soil at the depth of 2.5 cm [m(3) · m(-3)], T (2.5 cm) is soil temperature at the depth of 2.5 cm [°C], and A, B, and C are empirical coefficients calculated individually for each of the grass species [mm · h(1)], and [-], [(m(3) · m(-3) · °C)(-1)]. The values of evapotranspiration calculated on the basis of the presented function can be used as input data for the design of systems for the automatic control of irrigation systems ensuring optimum moisture conditions in the active layer of lawn swards.

Detection of atmospheric water deposits in porous media using the TDR technique.

Investigating the intensity of atmospheric water deposition and its diurnal distribution is essential from the ecological perspective, especially regarding dry geographic regions. It is also important in the context of monitoring the amount of moisture present within building materials in order to protect them from excessive humidity. The objective of this study was to test a constructed sensor and determine whether it could detect and track changes in the intensity of atmospheric water deposition. An operating principle of the device is based on the time-domain reflectometry technique. Two sensors of different plate volumes were manufactured. They were calibrated at several temperatures and tested during field measurements. The calibration turned out to be temperature independent. The outdoor measurements indicated that the upper limits of the measurement ranges of the sensors depended on the volumes of the plates and were equal to 1:2 and 2:8 mm H2O. The respective sensitivities were equal to 3.2 x 10(-3) and 7.5 x 10(-3) g∙ps(-1). The conducted experiments showed that the construction of the designed device and the time-domain reflectometry technique were appropriate for detecting and tracing the dynamics of atmospheric water deposition. The obtained outcomes were also collated with the readings taken in an actual soil sample. For this purpose, an open container sensor, which allows investigating atmospheric water deposition in soil, was manufactured. It turned out that the readings taken by the porous ceramic plate sensor reflected the outcomes of the measurements performed in a soil sample.

Application of a coaxial-like sensor for impedance spectroscopy measurements of selected low-conductivity liquids.

The paper presents a coaxial-like sensor operating in the 20 Hz-2 MHz frequency range used to determine the electrical properties of selected liquids of low electrical conductivity. Examined materials included low-concentrated aqueous solutions of potassium chloride, sodium chloride and trisodium citrate, which are common food additives. Impedance spectra of the measurement cell filled with particular liquids were obtained and analyzed using the electrical equivalent circuit approach. The values of physical quantities and parameters describing the equivalent circuit components, including a constant phase element, were calculated for each sample. The applied sensor was also calibrated for electrical conductivity measurements up to 8 mS/m. The constant phase element parameters differed among the studied solutions and concentrations. This may provide a basis for a detection method of small amounts of compounds, such as food additives in low-concentrated aqueous solutions. To demonstrate the potential of the presented method, samples of purchased mineral water and a flavored drink containing various additives were tested.

A TDR-based soil moisture monitoring system with simultaneous measurement of soil temperature and electrical conductivity.

Elements of design and a field application of a TDR-based soil moisture and electrical conductivity monitoring system are described with detailed presentation of the time delay units with a resolution of 10 ps. Other issues discussed include the temperature correction of the applied time delay units, battery supply characteristics and the measurement results from one of the installed ground measurement stations in the Polesie National Park in Poland.

Determination of soil pore water salinity using an FDR sensor working at various frequencies up to 500 MHz.

This paper presents the application of a frequency-domain reflectometry (FDR) sensor designed for soil salinity assessment of sandy mineral soils in a wide range of soil moisture and bulk electrical conductivity, through the determination of soil complex dielectric permittivity spectra in the frequency range 10-500 MHz. The real part of dielectric permittivity was assessed from the 380-440 MHz, while the bulk electrical conductivity was calculated from the 165-325 MHz range. The FDR technique allows determination of bulk electrical conductivity from the imaginary part of the complex dielectric permittivity, without disregarding the dielectric losses. The soil salinity status was determined using the salinity index, defined as a partial derivative of the soil bulk electrical conductivity with respect to the real part of the soil complex dielectric permittivity. The salinity index method enables determining the soil water electrical conductivity value. For the five sandy mineral soils that have been tested, the relationship between bulk electrical conductivity and the real part of dielectric permittivity is essentially linear. As a result, the salinity index method applied for FDR measurements may be adapted to field use after examination of loam and clayey soils.

Rapid UHPLC method for simultaneous determination of vancomycin, terbinafine, spironolactone, furosemide and their metabolites: application to human plasma and urine.

The ultra high performance liquid chromatography (UHPLC)-UV method for the simultaneous determination of furosemide, saluamine (furosemide metabolite), spironolactone, carnenone (spironolactone active metabolite), terbinafine, N-desmethylcarboxy terbinafine (terbinafine metabolite) and vancomycin in human plasma and urine is proposed. Good separation of the analytes was achieved with the gradient RP-UHPLC-UV with the mobile phase composed as acetonitrile and 0.1% formic acid. The determined substances were eluted from a Hypersil GOLD C(18)e (50 mm x 2.1 mm, 1.7 microm particles) column in 3.3 min. Good linear relationships were observed for all of the analytes (R(2) higher than 0.994). The limit of detection (LOD) values varied from 0.01 to 0.07 microg ml(-1), with vancomycin as an exception (0.11 microg ml(-1)). After protein precipitation and solid-phase extraction, samples of plasma and urine were analyzed. Thanks to the short analysis time and small quantities of urine or plasma needed, this method can be applied to routine clinical analysis.

A FDR sensor for measuring complex soil dielectric permittivity in the 10-500 MHz frequency range.

Mechanical details as well as electrical models of FDR (frequency domain reflectometry) sensors for the measurement of the complex dielectric permittivity of porous materials are presented. The sensors are formed from two stainless steel parallel waveguides of various lengths. Using the data from VNA (vector network analyzer) with the connected FDR sensor and selected models of the applied sensor it was possible obtain the frequency spectrum of dielectric permittivity from 10 to 500 MHz of reference liquids and soil samples of various moisture and salinity. The performance of the analyzed sensors were compared with TDR (time domain reflectometry) ones of similar mechanical construction.

Simultaneous RP-HPLC determination of sotalol, metoprolol, alpha-hydroxymetoprolol, paracetamol and its glucuronide and sulfate metabolites in human urine.

The HPLC method for the determination of sotalol (SOT), metoprolol (MET) and alpha-hydroxymetoprolol metabolite (MET-H), paracetamol (PAR), paracetamol glucuronide (PAR-G) and paracetamol sulfate (PAR-S) in human urine is described. Analyses were carried out on a reversed-phase LiChroCART Purospher C18e column (125 mm x 3 mm, 5 microm particles) (Merck) with gradient elution as well as spectrophotometric and fluorometric detection. Good resolution of the analyzed substances was obtained within a time range of no longer than 15 min. The linearity ranges of the callibration curves in human urine (as matrix) were: 3.25-45 microg ml(-1) (SOT), 0.75-40 microg ml(-1) (MET), 0.6-40 microg ml(-1) (MET-H), 4.6-60 microg ml(-1) (PAR-G), 4.95-50 microg ml(-1) (PAR-S), 1.95-45 microg ml(-1) (PAR). An application to human urine samples was performed.