Observation of pseudogap in MgB2.

We investigate the electronic structure of a specially prepared highly dense conventional high temperature superconductor, MgB2, employing high resolution photoemission spectroscopy. The spectral evolution close to the Fermi energy is commensurate to BCS descriptions as expected. However, the spectra in the wider energy range reveal the emergence of a pseudogap much above the superconducting transition temperature indicating an apparent departure from the BCS scenario. The energy scale of the pseudogap is comparable to the energy of the [Formula: see text] phonon mode responsible for superconductivity in MgB2 and the pseudogap can be attributed to the effect of electron-phonon coupling on the electronic structure. These results reveal a scenario of the emergence of the superconducting gap within an electron-phonon coupling induced pseudogap and have significant implications in the study of high temperature superconductors.

Crystal and magnetic structure of the R15Si9C compounds (R = Ho, Er, Tb).

The synthesis of the new compounds R(15)Si(9)C with R = Sm, Gd-Er, Y and R(15)Ge(9)C with R = Ce, Pr and Nd has been recently reported; these compounds crystallize in the hexagonal La(15)Ge(9)Fe structure type, hP50-P6(3)mc, Z = 2 (ordered superstructure of La(5)Ge(3) (Mn(5)Si(3)-type, hP 16-P6(3)/mcm, Z = 2)). Here we report the results of a neutron diffraction investigation that we have performed to study the crystal and magnetic structures of the R(15)Si(9)C compounds with R = Tb, Ho and Er. All three compounds see the establishment of commensurate magnetic order with a predominantly ferromagnetic interaction. Details of mixed antiferro-ferromagnetic spin arrangements (κ = [000]) (for Tb(15)Si(9)C and Ho(15)Si(9)C) or of purely ferromagnetic ordering (Er(15)Si(9)C), and of their temperature dependence, are given and linked to the different coordination of the four dissimilar rare earth sites. In the Tb and Ho compounds the thermal evolution of the magnetic moment values strongly differs between the different R sites. The position occupied by the principal carbon has been determined (Wyckoff site 2b) and the existence of a second position available for the interstitial carbon (Wyckoff site 2a) has been revealed for R = Ho, Tb. Moreover, in the Tb and Ho compounds the magnetic moment value of the rare earth site R4, surrounding the second interstitial carbon site, is strongly reduced if compared to the value on the other rare earth sites. The magnetic transition temperatures of all three compounds, i.e. T(C) = 130, 43 and 45 K for Tb(15)Si(9)C, Ho(15)Si(9)C and Er(15)Si(9)C, are remarkably high compared to those of the parent R(5)Si(3) compounds. The magnetic behaviour of the partly filled Tb(5)Si(3)C(0.25) is reported.

The Yb(2)Al(1-x)Mg(x)Si(2) series from a spin fluctuation (x = 0) to a magnetically ordered ground state (x = 1).

The structural and magnetic properties of Yb(2)Al(1-x)Mg(x)Si(2) (x = 0, 0.5 and 1), crystallizing in the tetragonal Mo(2)FeB(2)-type structure, are reported in this work. Yb(2)AlSi(2) exhibits a Pauli paramagnetic ground state arising due to spin/valence fluctuations induced by a significant Yb 4f conduction band hybridization. High-field magnetization (up to 120 kOe) indicates a nearly temperature-independent susceptibility of 8.6 × 10(-3) emu/Yb mol below 10 K. On the other hand, Yb ions in Yb(2)MgSi(2) order antiferromagnetically at a relatively high temperature T(N) of 9.5 K. The intermediate composition alloy Yb(2)Al(0.5)Mg(0.5)Si(2) is a Kondo lattice, antiferromagnet with T(N) = 5.5 K. The coefficient of the linear term of the electronic heat capacity, γ, of Yb(2)AlSi(2) is found to be 305 mJ mol(-1) K(-2), indicating a significant electronic mass enhancement due to strong electronic correlations. Below 12 K, an additional contribution to the heat capacity of the form T(3)lnT is observed. The (170)Yb Mössbauer spectra in the ordered state of Yb(2)MgSi(2) indicate a strong coupling of the 4f quadrupolar moment with the magnetic moment through a magneto-elastic coupling.