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1.
PLoS One ; 17(7): e0271452, 2022.
Artigo em Inglês | MEDLINE | ID: mdl-35819956

RESUMO

Route development programs have become popular with airports worldwide to enhance air connectivity. Enhanced air connectivity of an airport has been found to have a positive and significant impact on the competitiveness and attractiveness of the airport and the regional economy in which the airport is located. However, the drivers behind route development programs and their performance are not always clear; this has been less explored in the literature. In this paper, a dynamic performance management approach is taken to build a modeling framework in which key drivers affecting route development performance and strategic resources affecting key drivers are identified. Route-level planning is used in an empirical study to demonstrate the dynamic mechanism of airport route development initiatives and performance measurements. The proposed framework can not only provide performance monitoring, but also suggest suitable indicators to evaluate the performance for policymakers in future airport route development.


Assuntos
Aeroportos
2.
J Air Transp Manag ; 89: 101886, 2020 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-33013010

RESUMO

Air Transportation is a major contributor to international mobility and has high requirements to ensure safe and secure operations. Aircraft ground operations are impacted significantly by the current pandemic situation so that standard operating procedures need a redesign to incorporate the upcoming sanitation requirements. In particular, the passenger boarding process is challenged with requirements for physical distances between passengers, while in addition to standard cleaning, the cabin has to be disinfected after each flight. We evaluate potential alterations of these two aircraft cabin processes with respect to a pre-pandemic reference aircraft turnaround. The implementation of microscopic approaches allows to consider individual interactions and a step-wise process adaptation aiming for an efficient operational design. We find a significant extension of boarding times (more than doubled) if the physical distance rule is applied. The new disinfection process further extends the critical path of the turnaround, so we see a high impact on airport and airline operations. To compensate for the increased workload and process times, we provide an integrated cleaning and disinfection procedure with additional personnel. Our results indicate that the pre-pandemic turnaround times cannot be maintained for the same seat load, even if the process adaptations are being implemented. However, a seat allocation scheme with empty middle-seats (seat load of 67%) and the use of an apron position (additional use of rear aircraft door for boarding) enable pre-pandemic turnaround times without additional cleaning personnel. Aircraft turnarounds at terminal positions require between 10% (with additional personnel) and 20% (without additional personnel) more ground time.

3.
Des Monomers Polym ; 21(1): 55-63, 2018.
Artigo em Inglês | MEDLINE | ID: mdl-29706848

RESUMO

In this study, 4,4'-diphenylmethane diisocyanate and polytetramethylene glycol were used to prepare a prepolymer; N,N'-bis(4-hydroxybenzylidene)-2,6-diaminopyridine (BHBP) was used as a chain extender; and these elements were combined to prepare a novel polyurethane, BHBP/PU. Gel permeation chromatography revealed that the molecular weight of the BHBP/PU samples increased as the BHBP content was increased. Fourier transform infrared spectroscopy demonstrated that high BHBP content facilitated strong hydrogen bonding in the samples. Differential thermogravimetry indicated that the initial decomposition temperature of BHBP/PU-3 was approximately 10 °C higher than that of BHBP/PU-1. Differential scanning calorimetry and dynamic mechanical analysis revealed that increasing the BHBP content substantially increased both the glass transition and dynamic glass transition temperatures of the BHBP/PU samples. The tensile strengths of BHBP/PU-1, BHBP/PU-2, and BHBP/PU-3 were 7.7, 10.9, and 21.6 MPa, respectively, with corresponding Young's moduli of 0.7, 1.9, and 3.3 MPa. These results demonstrated that both the tensile strength and Young's modulus of the BHBP/PU samples increased as the BHBP content was increased. Moreover, the BHBP/PU samples exhibited excellent shape recovery of >90%.

4.
Molecules ; 21(10)2016 Sep 30.
Artigo em Inglês | MEDLINE | ID: mdl-27706060

RESUMO

We have overcome the synthetic difficulty of 9,9',9'',9''',9'''',9'''''-((phenylsilanetriyl)tris(benzene-5,3,1-triyl))hexakis(9H-carbazole) (SimCP3) an advanced homologue of previously known SimCP2 as a solution-processed, high triplet gap energy host material for a blue phosphorescence dopant. A series of organic light-emitting diodes based on blue phosphorescence dopant iridium (III) bis(4,6-difluorophenylpyridinato)picolate, FIrpic, were fabricated and tested to demonstrate the validity of solution-processed SimCP3 in the device fabrication.


Assuntos
Carbazóis , Substâncias Luminescentes , Semicondutores , Carbazóis/síntese química , Carbazóis/química , Substâncias Luminescentes/síntese química , Substâncias Luminescentes/química
5.
Org Lett ; 16(8): 2114-7, 2014 Apr 18.
Artigo em Inglês | MEDLINE | ID: mdl-24720531

RESUMO

Pure 2-iodo-9,9'-spirobifluorene was synthesized by an efficient method without troublesome iodination of 9,9-spirobifluorene (SP) or the Sandmeyer reaction of 2-amino-9,9'-spirobifluorene. A series of main group element-bridged bis-9,9'-spirobifluorene derivatives were synthesized via coupling reactions of 2-iodo-9,9'-spirobifluorene and main group element-containing precursors. These heteroatom-bridged bis-spirobifluorenes show large triplet state energy gaps, high glass transition temperatures, and varied charge-transporting properties advantageous to the host materials for blue phosphorescence organic light-emitting diodes.

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