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1.
Guang Pu Xue Yu Guang Pu Fen Xi ; 34(2): 505-9, 2014 Feb.
Artigo em Chinês | MEDLINE | ID: mdl-24822429

RESUMO

The spectral absorption features are very similar between some minerals, especially hydrothermal alteration minerals related to mineralization, and they are also influenced by other factors such as spectral mixture. As a result, many of the spectral identification approaches for the minerals with similar spectral absorption features are prone to confusion and misjudgment. Therefore, to solve the phenomenon of "same mineral has different spectrums, and same spectrum belongs to different minerals", this paper proposes an accurate approach to hyperspectral mineral identification based on naive bayesian classification model. By testing and analyzing muscovite and kaolinite, the two typical alteration minerals, and comparing this approach with spectral angle matching, binary encoding and spectral feature fitting, the three popular spectral identification approaches, the results show that this approach can make more obvious differences among different minerals having similar spectrums, and has higher classification accuracy, since it is based on the position of absorption feature, absorption depth and the slope of continuum.

2.
Talanta ; 105: 379-85, 2013 Feb 15.
Artigo em Inglês | MEDLINE | ID: mdl-23598034

RESUMO

A non-enzymatic electrochemical method was developed for glucose detection using a glassy carbon electrode modified with platinum nanoflowers supported on graphene oxide (PtNFs-GO). PtNFs-GO was synthesized using a nontoxic, rapid, one-pot and template-free method. Low-cost, green solvent ethanol acted as the reductant, and the advanced and effective 2D carbon material-GO nanosheet acted as the stabilizing material. Their morphologies were characterized using transmission electron microscopy. Cyclic voltammetry and amperometric methods were used to evaluate the electrocatalytic activity towards glucose in neutral media. The modified electrode exhibited strong and sensitive amperometric responses to glucose even in the presence of a high concentration of chloride ions. The response time was within 5s. The interference effects from ascorbic acid and uric acid were comparatively small when operated at suitable potential. Under optimal detection potential (0.47 V with a saturated calomel reference electrode) the PtNFs-GO modified electrode performed a current response towards glucose at a broad concentration range from 2 µM to 20.3mM. Two linear regions could be observed at 2 µM to 10.3mM with a sensitivity of 1.26 µA mM(-1)cm(-2) (correlation coefficient 0.9968), and at 10.3mM to 20.3mM with a sensitivity of 0.64 µA mM(-1)cm(-2)(correlation coefficient 0.9969). The LOD of 2 µM was lower than many non-enzymatic electrochemical glucose sensors. The modified electrode was also applied to the determination of glucose in glucose injection solutions, and the satisfactory results obtained indicated that it was promising for the development of a novel non-enzymatic electrochemical glucose sensor.

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