CoFe-Layered Double Hydroxide Coupled with Pd Particles for Electrocatalytic Ethanol Oxidation.

Electrocatalytic efficiency and stability have emerged as critical issues in the ethanol oxidation reaction (EOR) of direct ethanol fuel cells. In this paper, Pd/Co1Fe3-LDH/NF as an electrocatalyst for EOR was prepared by a two-step synthetic strategy. Metal-oxygen bonds formed between Pd nanoparticles and Co1Fe3-LDH/NF guaranteed structural stability and adequate surface-active site exposure. More importantly, the charge transfer of the formed Pd-O-Co(Fe) bridge could effectively modulate the electrical structure of hybrids, improving the facilitated absorption of OH- radicals and oxidation of COads. Benefiting from the interfacial interaction, exposed active sites, and structural stability, the observed specific activity for Pd/Co1Fe3-LDH/NF (17.46 mA cm-2) was 97 and 73 times higher than those of commercial Pd/C (20%) (0.18 mA cm-2) and Pt/C (20%) (0.24 mA cm-2), respectively. Besides, the jf/jr ratio representing the resistance to catalyst poisoning was 1.92 in the Pd/Co1Fe3-LDH/NF catalytic system. These results provide insights into optimizing the electronic interaction between metals and the support of electrocatalysts for EOR.

A three-dimensional flower-like NiCo-layered double hydroxide grown on nickel foam with an MXene coating for enhanced oxygen evolution reaction electrocatalysis.

Electrolysis of water is currently one of the cleanest and most efficient ways to produce high-purity hydrogen. The oxygen evolution reaction (OER) at the anode of electrolysis is the key factor affecting the reaction efficiency, which involves the transfer of four electrons and can slow down the overall reaction process. In this work, using nickel foam coated with MXene (Ti3C2T x ) as the carrier, a three-dimensional flower-shaped layered double hydroxide (NiCo-LDH) is grown on Ti3C2T x by a hydrothermal method to fabricate a NiCo-LDH/Ti3C2T x /NF hybrid electrocatalyst for enhanced OER performance. The results reveal that the hybrid electrocatalyst has excellent OER activity in alkaline solution, in which a low overpotential of 223 mV and a small Tafel slope of 47.2 mV dec-1 can be achieved at a current density of 100 mA cm-2. The interface interaction and charge transfer between Ti3C2T x and NiCo-LDH can accelerate the electron transfer rate during the redox process and improve the catalytic activity of the overall reaction. This NiCo-LDH/Ti3C2T x /NF hybrid electrocatalyst may have important research significance and great application potential in catalytic electrolysis of water.