Molecularly imprinted polymer-coated hybrid optical waveguides for sub-aM fluorescence sensing.

The sensitivity of fluorescent sensors is crucial for their applications. In this study, we propose a molecularly imprinted polymer (MIP)-coated optical fibre-hybrid waveguide-fibre sensing structure for ultrasensitive fluorescence detection. In such a structure, the MIP coated-hybrid waveguide acts as a sensing probe, and the two co-axially connected optical fibres act as a highly efficient probing light launcher and a fluorescence signal collector, respectively. For the dual-layered waveguide sensing probe, the inner hybrid waveguide core was fabricated using a hollow quartz nanoparticle-hybridized polymer composite with a low refractive index, and the outer MIP coating layer possesses a high refractive index. Simulations showed that this dual-layer configuration can cause light propagation from the waveguide core to the MIP sensing layer with an efficiency of 98%, which is essential for detection. To validate this concept, we adopted a popular fluorescent dye, rhodamine B, to evaluate the sensing characteristics of the proposed system. We achieved an extremely low limit of detection of approximately 1.3 × 10-19 g ml-1 (approximately 0.27 aM).

Front-face synchronous fluorescence spectroscopy: a rapid and non-destructive authentication method for Arabica coffee adulterated with maize and soybean flours.

This article describes a novel front-face synchronous fluorescence spectroscopy (FFSFS) method for the fast and non-invasive authentication of ground roasted Arabica coffee adulterated with roasted maize and soybean flours. The detection was based on the different composition of fluorescent Maillard reaction products and caffeine in roasted coffee and cereal flours. For each roasted maize or soybean adulterant flour (5-40 wt%), principal component analysis coupled with linear discriminant analysis (PCA-LDA) was used for qualitative discrimination. Quantitative prediction models were constructed based on the combination of unfolded total synchronous fluorescence spectra and partial least square regression (PLSR), followed by fivefold cross-validation and external validation. The PLSR models produced suitable results, with the determination coefficient of prediction (R p 2) > 0.9, root mean square error of prediction (RMSEP) < 5%, relative error of prediction (REP) < 25% and residual predictive deviation (RPD) > 3. The limits of detection (LOD) were both 10% for roasted maize and soybean flours. Most relative errors for the prediction of simulated blind samples were between -30% and + 30%. The benefits of this strategy are simplicity, rapidity, and non-destructive detection. However, owing to the high similarity between roasted coffee and roasted cereal flours and the influence of the roasting degree on fluorescent Maillard reaction products, its application is limited to the preliminary screening of roasted coffee with the same roasting degree, adulterated with relatively large amounts of roasted cereal flours which are roasted to analogous color to the coffee. Supplementary Information: The online version contains supplementary material available at 10.1007/s00003-022-01396-8.

Fluorescence quenching by competitive absorption between solid foods: Rapid and non-destructive determination of maize flour adulterated in turmeric powder.

Fluorescence quenching induced by competitive absorption between different components of solid foods was observed for the first time. By using front-face synchronous fluorescence spectroscopy (FFSFS) and fluorescence titration, competitive absorption between maize flour and turmeric powder was proven to occur between phenolic acids in maize flour and curcumin in turmeric powder. FFSFS was applied for the rapid and non-destructive determination of maize flour adulterated in turmeric powder. Prediction models were constructed by partial least square (PLS) regression based on unfolded total synchronous fluorescence spectra, and were validated by five-fold cross-validation and external validation, with the determination coefficient of prediction (Rp2) greater than 0.95, root mean square error of prediction (RMSEP) < 6%, relative error of prediction (REP) < 15% and residual predictive deviation (RPD) greater than 5. The limit of detection (LOD) of maize flour was approximately 9%. In addition, most relative errors for test samples were from -20% to 20%.

A Review on Terahertz Technologies Accelerated by Silicon Photonics.

In the last couple of decades, terahertz (THz) technologies, which lie in the frequency gap between the infrared and microwaves, have been greatly enhanced and investigated due to possible opportunities in a plethora of THz applications, such as imaging, security, and wireless communications. Photonics has led the way to the generation, modulation, and detection of THz waves such as the photomixing technique. In tandem with these investigations, researchers have been exploring ways to use silicon photonics technologies for THz applications to leverage the cost-effective large-scale fabrication and integration opportunities that it would enable. Although silicon photonics has enabled the implementation of a large number of optical components for practical use, for THz integrated systems, we still face several challenges associated with high-quality hybrid silicon lasers, conversion efficiency, device integration, and fabrication. This paper provides an overview of recent progress in THz technologies based on silicon photonics or hybrid silicon photonics, including THz generation, detection, phase modulation, intensity modulation, and passive components. As silicon-based electronic and photonic circuits are further approaching THz frequencies, one single chip with electronics, photonics, and THz functions seems inevitable, resulting in the ultimate dream of a THz electronic-photonic integrated circuit.

Critical Factors for In Vivo Measurements of Human Skin by Terahertz Attenuated Total Reflection Spectroscopy.

Attenuated total reflection (ATR) geometry is a suitable choice for in vivo measurements of human skin due to the deep penetration of the field into the sample and since it makes it easy to measure the reference spectrum. On the other hand, there are several critical factors that may affect the terahertz (THz) response in these kinds of experiments. Here, we analyse in detail the influence of the following factors: the contact positions between the thumb and the prism, the contact pressure, the contact duration, and the materials of the prism. Furthermore, we use the THz-ATR technology to evaluate different types of handcream and also establish the theoretical model to investigate the reflectivity after interacting with the skin. The results agree well with experimental ones. Our analysis makes it clear the importance of controlling the above factors during measurements to enable reliable THz response and results which, in turn, may be used to monitor water motion in human skin and to predict possible diseases.

Terahertz-frequency temporal differentiator enabled by a high-Q resonator.

Terahertz (THz) fundamental "building blocks" equivalent to those used in multi-functional electronic circuits are very helpful for actual applications in THz data-processing technology and communication. Here, we theoretically and experimentally demonstrate a THz temporal differentiator based on an on-chip high-quality (Q) factor resonator. The resonator is made of low-loss high-resistivity silicon material in a monolithic, integrated platform, which is carefully designed to operate near the critical coupling region. The experiment demonstrates that the device can perform the first-order time derivative of the input signal electric field complex envelope at 214.72 GHz. Our investigation provides an effective approach for terahertz pulse re-shaping and real-time differential computing units.

Broadband achromatic metalens in terahertz regime.

Achromatic focusing is essential for broadband operation, which has recently been realised from visible to infrared wavelengths using a metasurface. Similarly, multi-terahertz functional devices can be encoded in a desired metasurface phase profile. However, metalenses suffer from larger chromatic aberrations because of the intrinsic dispersion of each unit element. Here, we propose an achromatic metalens with C-shaped unit elements working from 0.3 to 0.8 THz with a bandwidth of approximately 91% over the centre frequency. The designed metalens possesses a high working efficiency of more than 68% at the peak and a relatively high numerical aperture of 0.385. We further demonstrate the robustness of our C-shaped metalens, considering lateral shape deformations and deviations in the etching depth. Our metalens design opens an avenue for future applications of terahertz meta-devices in spectroscopy, time-of-flight tomography and hyperspectral imaging systems.

High-Temperature Continuous-Wave Pumped Lasing from Large-Area Monolayer Semiconductors Grown by Chemical Vapor Deposition.

The realization of low-energy-consumption lasers based on atomically thin two-dimensional (2D) transition metal dichalcogenides (TMDCs) is crucial for the development of optical communications, flexible displays, and lasers on the chip level. However, among the as-demonstrated TMDC-based lasers so far, the gain materials are mainly achieved by a mechanical exfoliation approach accompanied by poor reproducibility and controllability. In this work, we report a controllable design for generating large-scale lasing from chemical vapor deposition (CVD)-derived high-quality monolayer MoS2 film. Strong continuous-wave optically driven whispering-gallery-mode lasing is achieved in a wide temperature range from 77 to 400 K. The eminent lasing performances result from the strong spatial confinement of carriers and the enhanced efficiency of spontaneous emission owing to the lensing and screening effects of silica microsphere cavities. These findings not only advance the fundamental understanding of 2D lasing effects but also provide solutions to fabricate low-cost, scalable, and integratable TMDC-based lasers.

Fano-resonance in one-dimensional topological photonic crystal heterostructure.

We theoretically realize the Fano resonance with a high quality factor of 106 using a structure, which is constructed from three one-dimensional photonic crystals and a defect layer. The emerged Fano resonance can be attributed to the weak coupling between a Fabry-Perot cavity mode and a topological edge state mode provided by the topological photonic crystal heterostructure. Moreover, we experimentally reproduce this Fano resonance in the optical communication range with a high quality of 104. This may be useful reference for the study of applications of photonic topological states in integrated photonic devices and information processing chips.

Flexibly designed spoof surface plasmon waveguide array for topological zero-mode realization.

We propose a flexibly designed photonic system based on ultrathin corrugated metallic "H-bar" waveguide that supports spoof surface plasmon polariton (SPP) at microwave frequencies. Five designs were presented, in order to demonstrate flexibility according to varying height, period, core width, rotation, and shifting on the "H-bar" unit of the waveguide. The propagation constant between two hybrid designs of period and height structure was then shown in order to study the coupling effect. Next, we constructed a coupled waveguide array that followed the Su-Schrieffer-Heeger (SSH) model. This model was constructed by a hybrid design with the identical propagation constant of each waveguide, except it had dimerized spacing. The propagation feature of topological zero mode was then observed as theoretically expected in the dimerized array. Our proposed spoof SPP waveguide array has great flexibility to be used as a powerful experiment platform, particularly in photonic simulation of the quantum or topological phenomena described by Schrödinger equation in condensed matters.

High extinction ratio electromagnetically induced transparency analogue based on the radiation suppression of dark modes.

A high extinction ratio (ER) electromagnetically induced transparency (EIT) analogue based on single-layer metamaterial is designed and experimentally demonstrated in this paper. This design involves four mirror-like symmetrically coupled split ring resonators (SRRs) that exhibit a bright-dark-dark-bright mode configuration. The EIT-like effect is realized by coupling between the bright resonators and dark resonators. The high ER feature is achieved from the suppression of radiative losses, due to opposite directions of electric and magnetic dipoles of two dark modes in the unit cell. Classical coupled resonator model is used to theoretically analyze the device transmission performances and to characterize parameter influence of the ER. Both numerical simulation and experiment results demonstrate that the ER of this device can reach more than 21 dB, which is 11 dB higher than that of conventional bright-dark coupling SRR arrangement. Finally, the potential multi-channel sensing utility of this device is demonstrated to show the importance of high ER feature.

Optimization of adiabatic microring resonators with few-mode and high-Q resonances.

We present the theoretical analysis and experimental demonstration of adiabatic microring resonators. The resonators are halfway between microdisk and microring preserving the good properties of both the microdisk (high Q-factor) and the microring (internal mode rejection). Device modeling based on the coupled-mode theory suggests that both the internal and external decay rates should be low in order to obtain high-Q and high extinction ratio resonances. The internal decay is modal-order-dependent and significantly affected by the adiabatic tapering rate of the ring waveguide. The external delay is determined by the modal effective index difference between the bus and ring waveguides at the coupling point under a fixed gap. Upon optimization of the resonator system, two resonance modes in the measured device are measured with one possessing a high Q-factor.

Seven-bit reconfigurable optical true time delay line based on silicon integration.

We design, fabricate, and characterize a 7-bit reconfigurable optical true time delay line consisting of Mach-Zehnder interferometer (MZI) switches on the silicon photonics platform. Variable optical attenuators (VOAs) are embedded to suppress the inter-symbol crosstalk caused by the finite extinction ratio of switches. The device can provide a maximum of 1.27 ns delay with a 10 ps resolution over a wide wavelength range. Eye diagram measurement of a 25 Gbps 2(51)-1 pseudo-random bit sequence (PRBS) signal reveals the power penalties only increase 0.17 dB and 0.77 dB after transmission through the shortest (reference) and the longest (1.27 ns delay) paths, respectively.

Selective excitation of microring resonances using a pulley-coupling structure.

We explore the selective excitation of resonances in microring resonators with a pulley-coupling structure. Due to the wavelength dispersion of coupling coefficient, only the resonances near critical coupling exhibit pronounced sharp notches in the transmission spectrum. Experimental results show that the resonance extinction ratio is a strong function of wavelength. Theoretical analysis further predicts that it is possible to highly suppress the neighboring resonances to effectively enlarge the free spectral range (FSR). With a proper design, the FSR can be increased by more than 1 order for a 10 µm radius microring resonator using the pulley-coupling structure.

Continuously tunable reflective-type optical delay lines using microring resonators.

We present a reflective-type optical delay line using waveguide side-coupled 13 microring resonators terminated with a sagnac loop reflector. Light passes through the microring resonator sequence twice, doubling the delay-bandwidth product. Group delay is tuned by p-i-p type microheaters integrated directly in the microring waveguides. Experiment demonstrates that the delay line can potentially buffer 18 bits and the delay can be continuously tuned for 100 ps with a power tuning efficiency of 0.34 ps/mW. Eye diagrams of a 20-Gbps PRBS signal after 10 and 110 ps delays are also examined.

CMOS-compatible temperature-independent tunable silicon optical lattice filters.

We present a CMOS-compatible athermal tunable silicon optical lattice filter composed of 10 cascaded 2 × 2 asymmetric Mach-Zehnder interferometers. Active tuning experiments show that the filter central wavelength can be red-/blue-shifted by 13.1/21.3 nm with power consumption of 77/96 mW on top/bottom arms. Temperature shift measurements show that the thermal-sensitivity of the filter central wavelength before active tuning is as low as -1.465 pm/°C. The thermal-sensitivity is varied within 26.5 pm/°C to -27.1 pm/°C when the filter central wavelength is tuned in the wavelength range of 1534 nm to 1551 nm. We use the transfer matrix method to theoretically model the lattice filter and its thermal-sensitivity before and after tuning is analyzed and discussed.

Tunable two-stage self-coupled optical waveguide resonators.

We report tunable two-stage self-coupled optical waveguide (SCOW) resonators composed of a pair of mirror-imaged single SCOW resonators connected by a phase shifter in between. Experimental results show that the coupled-resonator-induced-transparency and high-order bandstop filtering characteristics can be obtained in the transmission spectra of the devices with two different configurations. The resonance spectrum can be tuned by using either a p-i-p microheater or a p-i-n diode in the phase shifter. Our theoretical modeling based on the transfer matrix method has a good agreement with the experimental results.

Tunable silicon Fabry-Perot comb filters formed by Sagnac loop mirrors.

We experimentally demonstrate tunable silicon comb filters based on Fabry-Perot (FP) resonators composed of two Sagnac loop mirrors. The comb filter resolves up to 54 comb lines with a 115 GHz channel spacing over a spectral range from 1510 to 1560 nm. The comb line extinction ratio is ~26.3 dB and the quality factor is ~57,000 around 1550 nm wavelength. Electrical tuning is enabled via periodically interleaved PN junctions embedded inside the FP resonator. The comb lines are blue shifted by ~0.92 nm (one channel spacing) with a 5 mA forward-bias current and red-shifted by ~0.05 nm with a -10 V reverse-bias voltage.