RESUMO
Recovering chemical energy embedded in pollutants is significant in achieving carbon-neutral industrial wastewater treatment. Considering that industrial wastewater is usually treated in a decentralized manner, in situ utilization of chemical energy to achieve waste-to-treasure should be given priority. Herein, the chemical energy released by the electroreduction of Cr(VI) was used to enhance on-site H2O2 generation in a stacked flow-through electrochemical system. The driving force of water flow efficiently coupled O2 evolution with 2-e O2 reduction to facilitate H2O2 generation by transporting anode-produced O2 to the cathode. Meanwhile, the chemical energy released by Cr(VI) promoted O2 evolution and impeded H2 evolution by regulating the electrode potentials, accounting for the enhanced H2O2 generation. The system could completely reduce 10-100 ppm of Cr(VI), reaching the maximum H2O2 concentration of 2.41 mM. In particular, the H2O2 concentrations in the Cr(VI)-containing electrolyte were 10.6-88.1% higher than those in the Cr(VI) free electrolyte at 1.8-2.5 V. A 24-day continuous experiment demonstrated the high efficiency and stability of the system, achieving a 100% reduction efficiency for 100 ppm of Cr(VI) and producing â¼1.5 mM H2O2 at 1.8 V. This study presents a feasible strategy for Cr(VI) detoxification and synchronous on-site H2O2 generation, providing a new perspective for innovative Cr(VI) wastewater treatment toward resource utilization.
RESUMO
Revealing the dynamic processes at the electrode-solution interface is imperative for understanding electrochemical phenomena. Most techniques have been developed to sense the electrode surface changes at the nanoscale, but provide limited information on potential-induced interfacial ion redistribution at the mesoscale. Herein, we present an in operando visualization method utilizing a microfabricated electrochemical cell combined with a laser scanning confocal microscope to observe high-resolution and fast-response interfacial processes. We report potential-induced formation and transformation of the Nernst diffusion layer, demonstrating that pulsed voltage dynamically perturbs the interface and promotes ion diffusion. This provides an additional insight into developing a dynamic manipulation method to control the electrochemical process. Our novel visualization method can easily be applied to monitor different ionic behaviors in electrochemical reactions at the mesoscale.
RESUMO
The vast majority of studies measure the toxic effect of organisms exposed to nanoparticles (NPs) while there is still a lack of knowledge about the influence of NPs on the aquatic environment. It is unknown whether or not the interaction between NPs and algae will result in the variation of algal organic matter (AOM) and stimulate the production of more algal toxins. In this study, zinc oxide nanoparticles (nano-ZnO) as a typical representative of metal oxide NPs were used to evaluate the toxic effects and environmental feedback of Microcystis aeruginosa. Reactive oxygen species (ROS) and malondialdehyde (MDA) were measured to explain the toxicity mechanism. Changes of AOM, including the production of toxins, the molecular weight distribution and the excitation-emission matrices of algal solution were also studied as environmental feedback indicators after nano-ZnO destroyed the algae. As the nano-ZnO exceeded the comparable critical concentration (1.0 mg/L), the algae were destroyed and intracellular organic matters were released into the aquatic environment, which stimulated the generation of microcystin-LR (MC-LR). However, it is worth noting that the concentration of nano-ZnO would need to be high (at mg/L range) to stimulate more MC-LR production. These findings are expected to be beneficial in interpreting the toxicity and risks of the releasing of NPs through the feedback between algae and the aquatic environment.