RESUMO
Current improvement in perovskite solar cells (PSCs) has been achieved by interface engineering and fine-tuning of charge-selective contacts. In this work, we report three novel molecules that can form self-assembled layers (SAMs) as an alternative to the most commonly used p-type contact material, PTAA. Two of these molecules have bidentate anchoring groups (MC-54 and MC-55), while the last one is monodentate (MC-45). Besides the PTAA comparison, we also compared those two types of molecules and their effect on the solar cell's performance. Devices fabricated with MC-54 and MC-55 showed a remarkable field factor (about 80%) and a better current density, leading to higher efficient solar cells in comparison to MC-45 and PTAA. Moreover, mono- and bidentate present higher stability and reproducibility in comparison to PTAA.
RESUMO
We demonstrate the development and application of a low-cost smartphone turbidimeter system to be used on water samples collected from natural resources. The proposed system depends on the spectroscopic measurements of both forward- and side-scattered light. A custom-designed cradle was fabricated using 3D printing, and plastic optical fibers were used to couple light from the smartphone's built-in flash and transmit the collected scattered light to the camera sensor. The performance parameters of the smartphone turbidimeter were investigated and compared to commercial systems, and the lowest limit of detection was found to be 5.58 NTU for forward-scattered detection. The results obtained in the proposed scattered-light-based spectroscopic turbidimeter and the practicality achieved by this extremely low-cost device will have a great impact on water science and technology.
