The highly improved hydrogen evolution performance of a 0D/0D MoP-modified P-doped Mn0.5Cd0.5S photocatalyst.

In this paper, we present a MoP/P-Mn0.5Cd0.5S photocatalytic material (PMOMCS-Px). A novel catalyst can efficiently split water into hydrogen without precious metals. In the sacrificial agent environment, the HER (hydrogen evolution rate) of PMOMCS-P5 was 4368.25 µmol g-1 h-1 which was 11.4 times greater than the HER of Mn0.5Cd0.5S (383.19 µmol g-1 h-1), and its hydrogen production performance was better than that of Pt/Mn0.5Cd0.5S (2.0 wt% Pt). Furthermore, the hydrogen evolution performance of PMOMCS-P5 under pure water conditions was also examined, and the HER of PMOMCS-P5 was 209.76 µmol g-1 h-1, which was 20.4 times that of Mn0.5Cd0.5S (10.29 µmol g-1 h-1). Its characterization proved that the introduction of the co-catalyst MoP and P doping inhibited the recombination of e- and h+, enhanced the reduction capacity, and reduced the hydrogen precipitation reaction overpotential of PMOMCS-Px, thus enhancing the hydrogen production performance of PMOMCS-Px. Therefore, an efficient and economical photocatalyst was prepared.

Covalent organic frameworks bearing pillar[6]arene-reduced Au nanoparticles for the catalytic reduction of nitroaromatics.

While tremendous advancements in 2D materials anchoring Au nanoparticles have been made, it is an urgent challenge to explore a green and facile approach for obtaining small-size Au nanoparticles. The rise of 2D covalent organic framework (COF) presents more-promising candidates for constructing excellent sites for loading metal nanoparticles. In this study, a novel 2D heterogeneous hybrid nanomaterial (P6-Au-COF) based on COF and pillar[6]arene (P6) reduced Au nanoparticles (P6-Au) is prepared by a simple and green procedure. The Au nanoparticles with an average small diameter of 2-3 nm are homogeneously dispersed on the surface of the COF. The P6-Au-COF hybrid material shows highly catalytic performance for the reduction of nitrophenol isomers when compared with commercial Pd/C catalyst and other reported materials. The P6-Au-COF hybrid material exhibits durable recyclablility and stability during the catalytic reaction. Considering the outstanding merits of the heterogeneous 2D catalyst of P6-Au-COF as well as the simple and green preparation, this research might not only present enormous opportunities for stabilized, high-performance and sustainable catalysts, but be applied in other frontier study of sustainable functionalized nanocomposites and advanced materials.