Dual-Sensing, Stretchable, Fatigue-Resistant, Adhesive, and Conductive Hydrogels Used as Flexible Sensors for Human Motion Monitoring.

Hydrogel-based sensors serve as an ideal platform for developing personalized wearable electronics due to their high flexibility and conformability. However, the weak stretchability and inferior conductivity of hydrogels have severely restricted their large-scale application. Herein, a natural polymer-based conductive hydrogel integrated with favorable mechanical properties, good adhesive performance, and excellent fatigue resistance was fabricated via interpenetrating tannic acid (TA) into a chitosan (CS) cross-linked network in an acidic aqueous solution. The hydrogel was composed of a regular hierarchical porous structure, which was built by the hydrogen bonding between TA and CS. In addition, the hydrogels exhibited adjustable mechanical properties (maximum yield stress of 7000 Pa) and good stretchability (strain up to 320%). Benefiting from the abundant catechol groups of TA, the proposed hydrogels could repeatedly adhere to various material surfaces and could be easily peeled off without residue. Moreover, the hydrogel exhibited stable conductivity, high stretching sensitivity (gauge factor of 2.956), rapid response time (930 ms), and excellent durability (>300 cycles), which can be assembled as a strain sensor to attach to the human body for precise monitoring of human exercise behavior, distinguishing physiological signals, and recognizing speech. Furthermore, the prepared hydrogels also exhibited stable sensing performance to temperature. As a result, the hydrogels exhibited dual sensory performance for both temperature and strain deformation. It is anticipated that the incorporation of strain sensors and thermal sensors will provide theoretical guidance for developing multifunctional conductive hydrogels and pave a way for the versatile application of hydrogel-based flexible sensors in wearable devices and soft actuators.

Carbohydrate degradation contributes to the main bioheat generation during kitchen waste biodrying process: A pilot study.

Biodrying is a promising method for processing kitchen waste (KW) with high moisture content into reusable solid recovered fuels (SRFs). During biodrying, a large amount of bioheat generated from biodegradation of biochemical components results in KW dehydration. However, the degradation rules of these components and their contribution to the bioheat in KW biodrying have not been systematically clarified. Here, a pilot experiment was performed to investigate the variations in biochemical components, hydrolase activities, and bioheat generation during three successive cycles of biodrying processes. Results showed that KW could be rapidly converted into SRFs with low calorific values of 6705-7062 kJ/kg and moisture content of 31.26%-35.21%. Analyses of hydrolase activities and mean fluorescence intensity suggested that the biodrying process pioneered the degradation of lipids and proteins in the warming stages, while carbohydrates (i.e. amylum, celluloses, etc.) underwent rapid decomposition in a large extent in the high-temperature and cooling stages. Carbohydrates with minimal difficulty in degradation, contributed 73.37%-89.92% to the total degradation mass and 59.23%-60.80% to the bioheat source during the three-cycle biodrying process. The generated bioheat was 4.32-4.56 times the amount of the theoretical heat used for water removal, indicating that internal bioheat could significantly enhance water evaporation and was sufficient for the expected water removal mass. Therefore, the evaluation of the main components to bioheat generation and its utilization efficiency makes a prominent contribution that can greatly clarify the conversion of KW biodrying into SRFs in order to efficiently promote renewable bioenergy and support the bioeconomy.

Specific surface area and electron donating capacity determine biochar's role in methane production during anaerobic digestion.

The addition of biochar derived from different materials can have varying effects on anaerobic digestion (AD), depending on its physicochemical properties. Physicochemical properties of biochars, biomethanization performance and microbial communities were examined to evaluate the effectiveness of biochars made from different plant wastes on AD in this study. Results showed that all biochars significantly reduce the lag phases during AD, compared with a control treatment (CK). Woody biochars particularly performed much better than herbal ones. Correlation analysis revealed that specific surface area (SSA) and electron donating capacity (EDC) were the key properties of the plant-feedstock-derived biochar in AD enhancement. Microbial community structure analysis showed that higher SSA and EDC are conducive for the growth of bacteria decomposing glucose, further promoting daily methane production in the early AD stage. The results indicate that it is important to select biochar with higher SSA and EDC to enhance biomethanization in AD systems.