Advances in molecularly imprinted materials for selective adsorption of phenolic pollutants from the water environment: Synthesis, applications, and improvement.

The application of molecularly imprinted material (MIM) is widely employed as a material for removing phenolic pollutants from the water environment, owing to its exceptional capacity for selective adsorption and high sensitivity. In this paper, the preparation principle, bonding types, and preparation methods of MIM have been comprehensively introduced. Meanwhile, according to the binding type of MIM with phenolic pollutants, three categories of hydroxyl bonding, hydroxyl carboxyl bonding, and hydroxyl nitro bonding were carried out to explain its application to phenolic pollutants. Strategies for addressing the challenges of selective instability, high regeneration costs, and template leakage in MIM applications were summarized. These strategies encompassed the introduction of superior carriers, enhancements in preparation processes, and the utilization of molecular dynamics simulation-assisted technology. Finally, the prospects in the three aspects of material preparation, process coupling, and recycling. In summary, this paper has demonstrated the potential of utilizing MIM for the selective treatment of phenolic pollutants from the water environment.

Regulation methods and enhanced mechanism on the efficient degradation of aromatics in biochemical treatment system of coal chemical wastewater.

In order to address the problems of poor treatment effect of coal chemical wastewater (CCW) biochemical treatment system resulting in non-compliance with effluent standards and unstable operation, a combination regulation method of co-substrate metabolism and predominant flora enhancement was constructed, and the performance and mechanism of enhanced degradation of aromatics in CCW was also investigated in this study. The results showed that when the influent concentration of chemical oxygen demand (COD) and aromatics was less than 600 mg/L and 180 mg/L respectively, there was no significant effect of the combined regulation method on the enhanced treatment of aromatics, the removal rate of total organic carbon (TOC) in the system could all more than 73%; while when the influent concentration of COD increased to 800 mg/L and the aromatics concentration increased to more than 240 mg/L, the ordinary activated sludge system had collapsed. Compared with the regulation method of co-substrate metabolism alone, the combination regulation method increased the removal rate of TOC by 21%. The analysis of antioxidant enzyme activity showed that under the combination regulation method, the antioxidant enzyme activity of microorganisms was higher and their resistance to adverse environments was stronger. EPS and dehydrogenase analysis indicated that the combination regulation method was more conducive to microbial degradation of aromatics. Meanwhile, the analysis of microbial community structure showed that the aromatics degradation bacteria genera Rhodococcus, Luteococcus, etc. were enriched under the combination regulation method. The study provides a theoretical basis and technical guidance for solving the problems of unstable operation of CCW biochemical treatment systems and non-compliance with effluent standards.

Insight into the effect of particulate organic matter on sludge granulation at the low organic load: Sludge characteristics, extracellular polymeric substances and microbial communities response.

This paper investigated the effect of particulate organic matter (POM) on sludge granulation under low organic load. The results showed that POM promoted the formation of aerobic granular sludge (AGS) with a chemical oxygen demand (COD) fraction of 25%, and POM also enhanced the sludge settleability and biomass retention. However, when the COD fraction of POM increased to 50% and 75%, the AGS performance deteriorated. The analysis of extracellular polymeric substances revealed that the POM (accounted for ≤ 50% of COD in the influent) suppressed the secretion of extracellular protein. Analysis of the microbial community showed that species diversity was lower in the POM-fed system, with Rhodocyclaceae being the predominant bacteria responsible for carbon source degradation. Additionally, molecular ecological network analysis demonstrated that when the COD fraction of the POM exceeded 50%, the connectivity and modularity between microbial species decreased, which may explain the sludge performance deterioration.

Role of cycle duration on the formation of quinoline-degraded aerobic granules in the aspect of sludge characteristics, extracellular polymeric substances and microbial communities.

This study investigated the culture and characteristics of quinoline-degraded aerobic granular sludge (AGS) under 8-h and 12-h cycle duration. According to results, the cultivation of an 8-h cycle duration enhanced the growth of quinoline-degraded AGS, as well as the settleability of sludge and the retention of biomass. Quinoline can be removed from mature AGS at a rate of more than 90%, but it is removed at a rate slightly higher when the AGS are cultured for 12-h. Compared to 12-h cycle duration, 8-h cycle duration result in a greater increase in the production of extracellular polymeric substances, particularly extracellular proteins. In these two systems, Acidovorax and Paracoccus dominated the quinoline degrading bacteria. In addition, analysis by non-metric multidimensional scaling (based on Bray-curtis distance) showed significant differences of community structure between the two reactors. Clostridia and Acidaminobacter are different bacteria with an 8-h cycle duration compared to 12 h. Relative abundance of nitrogen metabolism genes based on PICRUSt2 prediction, which explain the better total nitrogen removal for an 8-h cycle duration compared to a 12-h cycle duration. Finally, the KEGG pathway was analyzed in order to confirm the results of the microbial analysis.