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1.
Philos Trans A Math Phys Eng Sci ; 381(2245): 20220079, 2023 Apr 17.
Artigo em Inglês | MEDLINE | ID: mdl-36842983

RESUMO

We present an experimental and two-phase computational study of convection in a liquid bridge ([Formula: see text]) that develops under the action of a parallel gas flow. The study focuses on tracking the evolution of hydrothermal waves by increasing the applied temperature difference [Formula: see text] and the temperature of gas moving at the velocity [Formula: see text]. Our experiments revealed certain regularity in the change of oscillatory states with an increase in the control parameters. Above the instability threshold, the nonlinear dynamics passes through three oscillatory regimes, which are repeated in a somewhat similar way at higher values of the control parameters. They are periodic, quasi-periodic with two or three frequencies and multi-frequency state when the Fourier spectrum is filled with clusters of duplex, triplex or higher numbers of frequencies. Three-dimensional numerical simulation, complemented by a deep spectral analysis, sheds light on the evolution of the flow pattern observed in experiments. The developed methodology identified conditions for the existence of a multi-frequency regime such as the presence of a weak low-frequency mode that can modulate strong high-frequency modes, the existence of strong azimuthal modes with different wavenumbers and the [Formula: see text] mode, and the structured combination of peaks in the Fourier spectrum. This article is part of the theme issue 'New trends in pattern formation and nonlinear dynamics of extended systems'.

2.
Soft Matter ; 11(42): 8221-4, 2015 Nov 14.
Artigo em Inglês | MEDLINE | ID: mdl-26365134

RESUMO

We explore the peculiar behaviour of an interface between two miscible liquids of similar (but non-identical) viscosities and densities under horizontal vibration with a frequency less than 25 Hz. Significant differences in the structure of the formed patterns were found between microgravity and ground experiments. In a gravity field, a spatially periodic saw-tooth frozen structure is generated in the interface which dissipates at long times. By contrast, under the low gravity conditions of a parabolic flight, the long lived pattern consists of a series of vertical columns of alternating liquids.


Assuntos
Soluções/química , Vibração , Ausência de Peso , Propriedades de Superfície , Viscosidade
3.
Eur Phys J E Soft Matter ; 38(4): 27, 2015 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-25916232

RESUMO

We have determined the Soret (ST), diffusion (D, and thermodiffusion (DT) coefficients in a ternary mixture of tetralin-isobutylbenzene-n-dodecane with a composition of 0.80/0.10/0.10 by mass fraction at a temperature of 298K. The Soret coefficients were measured in the microgravity experiment DCMIX1 and on the ground by optical digital interferometry (ODI) using two lasers with different wavelengths. The values of the Soret coefficients were determined from the stationary separation of the components using two- and six-parameter fits. The diffusion coefficients were independently measured using the Taylor Dispersion Technique in the ground laboratory, and the thermodiffusion coefficients were derived from known ST and matrix D. The processing of the data from the DCMIX experiment conducted on the International Space Station is discussed in detail. The multi-user design of the on-board instrument causes perturbations in the component separation. Several recommendations are suggested for improving the quality of the microgravity results. For example, we demonstrated that the tomography reconstruction of the 3-D concentration field allows to restore the underestimated component separation resulting from the spatial non-linearity of the temperature field. Furthermore, to avoid errors in component separation due to mass exchange between the working liquid volume and the expansion volume at the top of the cell, we suggest considering the evolution of the separation only in the lower half of the cell. The results of this study displayed reasonable quantitative agreement between the microgravity and ground experiments.

4.
J Chem Phys ; 138(11): 114503, 2013 Mar 21.
Artigo em Inglês | MEDLINE | ID: mdl-23534645

RESUMO

We have measured the Soret (S(T)), diffusion (D), and thermal diffusion (D(T)) coefficients of the three binary benchmark mixtures of dodecane (C12), isobutylbenzene, and 1,2,3,4-tetrahydronaphthalene at T = 25°C for at least five different concentrations each, covering the entire binary composition range. The two different optical techniques employed, optical beam deflection and optical digital interferometry, are in good to excellent agreement. Additionally, we have carefully measured the optical contrast factors (∂n/∂c)(p, T) and (∂n/∂T)(p, c). If the temperature and composition dependence of the mixture density is taken into account, both the Lorentz-Lorenz (LL) and the Looyenga (LO) equations give reasonable predictions of (∂n/∂c)(p, T). In case of (∂n/∂T)(p, c), only the LO equation yields good predictions in case of constant molecular polarizabilities α(i) of the pure compounds. If the apparent temperature dependence of α(i) is explicitly taken into account, excellent predictions are obtained both from the LL and the LO equations.

5.
J Chem Phys ; 136(24): 244512, 2012 Jun 28.
Artigo em Inglês | MEDLINE | ID: mdl-22755592

RESUMO

We report on the measurement of diffusion (D), thermodiffusion (D(T)), and Soret (S(T)) coefficients in water-isopropanol mixtures by three different instrumental techniques: thermogravitational column in combination with sliding symmetric tubes, optical beam deflection, and optical digital interferometry. All the coefficients have been measured over the full concentration range. Results from different instruments are in excellent agreement over a broad overlapping composition (water mass fraction) range 0.2 < c < 0.7, providing new reliable benchmark data. Comparison with microgravity measurements (SODI/IVIDIL (Selected Optical Diagnostic Instrument/Influence of VIbration on DIffusion in Liquids)) onboard the International Space Station and with literature data (where available) generally gives a good agreement. Contrary to theoretical predictions and previous experimental expectations we have not observed a second sign change of S(T) at low water concentrations.

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