Immobilizing Polysulfide by In Situ Topochemical Oxidation Derivative TiC@Carbon-Included TiO2 Core-Shell Sulfur Hosts for Advanced Lithium-Sulfur Batteries.

The performance of lithium-sulfur (Li-S) batteries is greatly hindered by the notorious shuttle effect of lithium polysulfides (LiPSs). To address this issue, in situ topochemical oxidation derivative TiC@carbon-included TiO2 (TiC@C-TiO2 ) core-shell composite is designed and proposed as a multifunctional sulfur host, which integrates the merits of conductive TiC core to facilitate the redox reaction kinetics of sulfur species, and porous C-TiO2 shell to suppress the dissolution and shuttling of LiPSs through chemisorption. A unique dual chemical mediation mechanism is demonstrated for the proposed TiC@C-TiO2 composite that synergistically entraps LiPSs through thiosulfate/polythionate conversion coupled with strong polar-polar interaction. The morphological characterization reveals that the TiC@C-TiO2 -based cathode can well regulate the distribution of electrode materials to retard their accumulation inside the electrode, ensuring effective contact between the active materials and electrolyte. Based on its unique function and structure, the cathode delivers an improved capacity of 1256 mAh g-1 at 0.2C, a remarkable rate capability of 643 mAh g-1 , and an ultralow capacity decay rate of 0.065% per cycle at 2C over 900 cycles. This work not only demonstrates a dual chemical mediation mechanism to immobilize LiPSs, but also provides a universal strategy to construct multifunctional sulfur hosts for advanced Li-S batteries.

Silicon-nanoparticle-based composites for advanced lithium-ion battery anodes.

Lithium-ion batteries (LIBs) play an important role in modern society. The low capacity of graphite cannot meet the demands of LIBs calling for high power and energy densities. Silicon (Si) is one of the most promising materials instead of graphite, because of its high theoretical capacity, low discharge voltage, low cost, etc. However, Si shows low conductivity of both ions and electrons and exhibits a severe volume change during cycles. Fabricating nano-sized Si and Si-based composites is an effective method to enhance the electrochemical performance of LIB anodes. Using a small size of Si nanoparticles (SiNPs) is likely to avoid the cracking of this material. One critical issue is to disclose different types and electrochemical effects of various coupled materials in the Si-based composites for anode fabrication and optimization. Hence, this paper reviews diverse SiNP-based composites for advanced LIBs from the perspective of composition and electrochemical effects. Almost all kinds of materials that have been coupled with SiNPs for LIB applications are summarized, along with their electrochemical influences on the composites. The integrated materials, including carbon materials, metals, metal oxides, polymers, Si-based materials, transition metal nitrides, carbides, dichalcogenides, alloys, and metal-organic frameworks (MOFs), are comprehensively presented.