Terahertz communication: Detection and signal processing.

The development of 6G networks has promoted related research based on terahertz communication. As submillimeter radiation, signal transportation via terahertz waves has several superior properties, including non-ionizing and easy penetration of non-metallic materials. This paper provides an overview of different terahertz detectors based on various mechanisms. Additionally, the detailed fabrication process, structural design, and the improvement strategies are summarized. Following that, it is essential and necessary to prevent the practical signal from noise, and methods such as wavelet transform, UM-MIMO and decoding have been introduced. This paper highlights the detection process of the terahertz wave system and signal processing after the collection of signal data. .

An infrared photothermoelectric detector enabled by MXene and PEDOT:PSS composite for noncontact fingertip tracking.

Photothermoelectric (PTE) detectors functioning on the infrared spectrum show much potential for use in many fields, such as energy harvesting, nondestructive monitoring, and imaging fields. Recent advances in low-dimensional and semiconductor materials research have facilitated new opportunities for PTE detectors to be applied in material and structural design. However, these materials applied in PTE detectors face some challenges, such as unstable properties, high infrared reflection, and miniaturization issues. Herein, we report our fabrication of scalable bias-free PTE detectors based on Ti3C2 and poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) composites and characterization of their composite morphology and broadband photoresponse. We also discuss various PTE engineering strategies, including substrate choices, electrode types, deposition methods, and vacuum conditions. Furthermore, we simulate metamaterials using different materials and hole sizes and fabricated a gold metamaterial with a bottom-up configuration by simultaneously combining MXene and polymer, which achieved an infrared photoresponse enhancement. Finally, we demonstrate a fingertip gesture response using the metamaterial-integrated PTE detector. This research proposes numerous implications of MXene and its related composites for wearable devices and Internet of Things (IoT) applications, such as the continuous biomedical tracking of human health conditions.

System design of large-area vertical photothermoelectric detectors based on carbon nanotube forests with MXene electrodes.

Photothermoelectric (PTE) detectors that combine photothermal and thermoelectric conversion have emerged in recent years. They can overcome bandgap limitations and achieve effective infrared detection. However, the development of PTE detectors and the related system design are in the early phases. Herein, we present vertical PTE detectors utilizing the active layer of carbon nanotube forests with MXenes acting as top electrodes. The detector demonstrates its capacity for sensitive infrared detection and rapid infrared response. We also investigated the relationship between photoresponse and different MXene electrode types as well as their thickness, which guides the PTE detector configuration design. Furthermore, we packed the PTE detectors with a polytetrafluoroethylene (PTFE, Teflon) cavity. The photoresponse is improved and the degradation is significantly delayed. We also applied this PTE detector system for non-destructive tracking (NDT) applications, where the photovoltage mapping pattern proves the viability of the imaging track. This work paves the way toward infrared energy harvesters and customized industrial NDT measurement.

Flexible Multi-Element Photothermoelectric Detectors Based on Spray-Coated Graphene/Polyethylenimine Composites for Nondestructive Testing.

Photothermoelectric (PTE) detectors receive much attention owing to the superiority of self-powered, non-bias input, and friendly ambient environments, facilitating abundant prospective applications in industrial inspection, medical diagnostics, homeland security, and wearable Internet of Things. However, many drawbacks of currently applicable PTE materials, involving unstable material oxidation, an uncontrollable fabrication process, and unscalable manufacturing, hinder the development of industrial productions. Herein, we demonstrate a vertical graphene/polyethylenimine composite PTE detector fabricated with an optimized spray-coating method in compact alignment on various surfaces, achieving a significant photovoltage detectivity and responsivity of 6.05 × 107 cm Hz1/2 W-1 and 2.7 V W-1 response at a 973 K blackbody temperature radiation (2.98 µm peak wavelength). In addition, the long-term stability and resistible concave and convex bending flexibility are presented. Furthermore, a nondestructive testing system is established and verified through high-spatial-resolution and high-penetration illustration. Overall, the spray-coated and flexible PTE graphene/polyethylenimine multi-elements with broadband infrared absorption compatibility and stable energy conversion are promising candidates for future health monitoring and wearable electronics.

A precise and rapid early pregnancy test: Development of a novel and fully automated electrochemical point-of-care biosensor for human urine samples.

Human chorionic gonadotropin (hCG), a glycoprotein hormone secreted from the placenta, is an important biomarker for pregnancy. In this study, we designed a precise, rapid and fully automatic device with an electrochemical point-of-care biosensor capable of quantitative hCG detection from human urine samples for early pregnancy detection. Gold and Ag/AgCl electrodes, whose structure with optimum isopotential region and current density, were simulated using COMSOL Multiphysics® software and custom-made from Flex Medical. The sensing surface was fabricated with DSP self-assembled monolayers (SAMs) and covalently immobilized anti-hCG-beta antibody. The detection method involved a sandwich assay using anti-hCG alpha-HRP. Based on an automated agitation design implemented in our device, the surface reaction rate is significantly improved comparing to routinely performed sandwich assays, and therefore a rapid detection of very low concentration can be achieved. Electrochemical impedance spectroscopy (EIS) and chronoamperometry (CA) measurements were used to characterize the immobilization of the antibodies and to determine the sensor activities respectively. The sensors displayed a limit of detection (LOD) of 2.17 mIU/ml within established clinical hCG levels for early detection of pregnancy. They responded very well to hCG, but not to luteinizing hormone (LH), which has a high degree of cross-reactivity with hCG. The results showed that the immunosensor has high specificity, good reproducibility, and long-term stability for the detection of hCG in urine samples.

Improvement of field emission performances by DMSO and PEDOT:PSS treated freestanding CNT clusters.

In this paper, we present two methods to improve the field emission (FE) performance of vertically aligned carbon nanotube emitters that are treated with dimethyl sulfoxide (DMSO) solution and poly(3,4-ethylene dioxythiophene):polystyrene sulfonate (PEDOT:PSS) solution, respectively, and compared their performances. Both treatments force CNTs to be bundled into clusters, but the formed structures are very different. After treatment, both methods reduced the threshold electric field due to the reduction in screening effects, whereas the PEDOT:PSS treatment significantly reduced the threshold field to far lower than that of DMSO treatment. In addition, the FE efficiency and lifetime of treated CNT emitters are significantly improved. For both treated emitters, there is only slight degradation of the emission current after 80 hours of continuous FE at around 50 µA. In addition, the uniformity of both treated CNT emitters is improved which enables more CNTs to contribute to the overall current emission. This, in turn, lowers the current emitted by individual CNTs, and thereby increases the lifetime of the emitters. Therefore, this study demonstrates that these simple treatment methods of bundling CNTs into unique cluster-structures significantly improve the lifetime of FE and make them excellent candidates for large currents and long-term FE.

Simulation of a Miniature Linear Ion Trap with Half-Round Rod Electrodes.

The miniaturization of ion trap mass analyzers is an important direction in the development of mass spectrometers. In this work, we proposed two models of miniaturized HreLIT with a field radius of about 2 mm based on the existing research on conventional HreLIT and other ion traps, one with ions ejection slits on one pair of electrodes only (2-slit model) and the other with the same slits on all electrodes (4-slit model). The relationship of mass resolution with r/rx and the "stretch" distance of electrodes in the ejection direction is investigated by theoretical simulations. Trends of electric fields inside the ion traps were discussed as well. The comparable maximum resolution is observed at r/rx = 2/1.4 in both models, but stretching simulations revealed that the peak resolution of the 2-slit model was higher than that of the other model by about 8%. The highest value of 517 was obtained when stretching 1.1 mm. Furthermore, the resolution of ions with m/z = 119 could exceed 1000 when the scan rate was reduced to 800 Th/s. The mass spectrometry capability of miniature HreLIT has been confirmed theoretically, and it laid the foundation for the subsequent fabrication with MEMS technology.

Micro triboelectric ultrasonic device for acoustic energy transfer and signal communication.

As a promising energy converter, the requirement for miniaturization and high-accuracy of triboelectric nanogenerators always remains urgent. In this work, a micro triboelectric ultrasonic device was developed by integrating a triboelectric nanogenerator and micro-electro-mechanical systems technology. To date, it sets a world record for the smallest triboelectric device, with a 50 µm-sized diaphragm, and enables the working frequency to be brought to megahertz. This dramatically improves the miniaturization and chip integration of the triboelectric nanogenerator. With 63 kPa@1 MHz ultrasound input, the micro triboelectric ultrasonic device can generate the voltage signal of 16.8 mV and 12.7 mV through oil and sound-attenuation medium, respectively. It also achieved the signal-to-ratio of 20.54 dB and exhibited the practical potential for signal communication by modulating the incident ultrasound. Finally, detailed optimization approaches have also been proposed to further improve the output power of the micro triboelectric ultrasonic device.

Capacitive micromachined ultrasound transducers for intravascular ultrasound imaging.

Intravascular ultrasound (IVUS) is a burgeoning imaging technology that provides vital information for the diagnosis of coronary arterial diseases. A significant constituent that enables the IVUS system to attain high-resolution images is the ultrasound transducer, which acts as both a transmitter that sends acoustic waves and a detector that receives the returning signals. Being the most mature form of ultrasound transducer available in the market, piezoelectric transducers have dominated the field of biomedical imaging. However, there are some drawbacks associated with using the traditional piezoelectric ultrasound transducers such as difficulties in the fabrication of high-density arrays, which would aid in the acceleration of the imaging speed and alleviate motion artifact. The advent of microelectromechanical system (MEMS) technology has brought about the development of micromachined ultrasound transducers that would help to address this issue. Apart from the advantage of being able to be fabricated into arrays with lesser complications, the image quality of IVUS can be further enhanced with the easy integration of micromachined ultrasound transducers with complementary metal-oxide-semiconductor (CMOS). This would aid in the mitigation of parasitic capacitance, thereby improving the signal-to-noise. Currently, there are two commonly investigated micromachined ultrasound transducers, piezoelectric micromachined ultrasound transducers (PMUTs) and capacitive micromachined ultrasound transducers (CMUTs). Currently, PMUTs face a significant challenge where the fabricated PMUTs do not function as per their design. Thus, CMUTs with different array configurations have been developed for IVUS. In this paper, the different ultrasound transducers, including conventional-piezoelectric transducers, PMUTs and CMUTs, are reviewed, and a summary of the recent progress of CMUTs for IVUS is presented.

Large-Area and Broadband Thermoelectric Infrared Detection in a Carbon Nanotube Black-Body Absorber.

Room-temperature mid- and far-infrared photodetectors and energy harvesters meet diverse upcoming demands including health condition monitoring, industrial inspection, and miniaturized power-source for Internet of Things. However, the cryogenic cooling requirement for III-V semiconductors and the inefficient light absorption in two-dimensional (2D) materials, for example, graphene (2.3%) and black phosphorus (∼3%), have hindered mid- and far-infrared optoelectronics from widespread applications. Here, we demonstrate a self-powered infrared photodetector as well as energy harvester via employing vertical photothermoelectric (PTE) effect of a carbon nanotube forest (CNTF). In the self-assembled anti-reflecting CNTF, 99.4% reflection suppression is observed, resulting in a broadband detectivity of 1.9 × 107 cm Hz1/2 in 2.5-25 µm spectral range and peak detectivity of 2.3 × 109 cm Hz1/2 at 4.3 THz via nonlithography fabrication. By virtue of vertical architecture, this photodetector exhibits enhanced sensitivity to weak and unfocused infrared illumination, which mitigates the high actuating power density in conventional PTE or field-effect detectors and renders practical infrared detection in the real life.

Photoacoustic Imaging with Capacitive Micromachined Ultrasound Transducers: Principles and Developments.

Photoacoustic imaging (PAI) is an emerging imaging technique that bridges the gap between pure optical and acoustic techniques to provide images with optical contrast at the acoustic penetration depth. The two key components that have allowed PAI to attain high-resolution images at deeper penetration depths are the photoacoustic signal generator, which is typically implemented as a pulsed laser and the detector to receive the generated acoustic signals. Many types of acoustic sensors have been explored as a detector for the PAI including Fabry-Perot interferometers (FPIs), micro ring resonators (MRRs), piezoelectric transducers, and capacitive micromachined ultrasound transducers (CMUTs). The fabrication technique of CMUTs has given it an edge over the other detectors. First, CMUTs can be easily fabricated into given shapes and sizes to fit the design specifications. Moreover, they can be made into an array to increase the imaging speed and reduce motion artifacts. With a fabrication technique that is similar to complementary metal-oxide-semiconductor (CMOS), CMUTs can be integrated with electronics to reduce the parasitic capacitance and improve the signal to noise ratio. The numerous benefits of CMUTs have enticed researchers to develop it for various PAI purposes such as photoacoustic computed tomography (PACT) and photoacoustic endoscopy applications. For PACT applications, the main areas of research are in designing two-dimensional array, transparent, and multi-frequency CMUTs. Moving from the table top approach to endoscopes, some of the different configurations that are being investigated are phased and ring arrays. In this paper, an overview of the development of CMUTs for PAI is presented.

Wrist and Finger Gesture Recognition With Single-Element Ultrasound Signals: A Comparison With Single-Channel Surface Electromyogram.

With the ability to detect volumetric changes of contracting muscles, ultrasound (US) was a potential technique in the field of human-machine interface. Compared to the US imaging (B-mode US), the signal from a static single-element US transducer, A-mode US, was a more cost-effective and convenient way toward the real-world application, particularly the wearables. This study compared the performance of the single-channel A-mode US with single-channel surface electromyogram (sEMG) signals, one of the most popular signal modalities for wrist and finger gesture recognition. We demonstrated that A-mode US outperformed sEMG in six out of nine gestures recognition, while sEMG was superior to A-mode US on the detection of the rest state. We also demonstrated that, through feature space analysis, the advantage of A-mode US over sEMG for gesture recognition was due to its superior ability in detecting information from deep musculature. This study presented the clear complementary advantages between A-mode US and sEMG, indicating the possibility of fusing two signal modalities for the gesture recognition applications.

Flexible Polymer-Carbon Nanotube Composite with High-Response Stability for Wearable Thermal Imaging.

In this work, we report a wearable thermal detector based on poly(vinyl alcohol) and carbon nanotube (CNT) composite via photo-thermoelectric effect. Passive room-temperature human body thermal imaging is demonstrated with optimum detectivity up to 4.9 × 106 cm Hz1/2 W-1. Highly stable photoresponse (variation < 4%) is obtained under a bending radius down to 3.5 mm. We also found that the detector photoresponse is influenced by the composite channel length because of Seebeck effect. This flexible, self-powered, and sensitive detector opens up opportunities for wearable thermal imaging and real-time health monitoring.

Compensated Row-Column Ultrasound Imaging System Using Multilayered Edge Guided Stochastically Fully Connected Random Fields.

The row-column method received a lot of attention for 3-D ultrasound imaging. By reducing the number of connections required to address the 2-D array and therefore reducing the amount of data to handle, this addressing method allows for real time 3-D imaging. Row-column still has its limitations: the issues of sparsity, speckle noise inherent to ultrasound, the spatially varying point spread function, and the ghosting artifacts inherent to the row-column method must all be taken into account when building a reconstruction framework. In this research, we build on a previously published system and propose an edge-guided, compensated row-column ultrasound imaging system that incorporates multilayered edge-guided stochastically fully connected conditional random fields to address the limitations of the row-column method. Tests carried out on simulated and real row-column ultrasound images show the effectiveness of our proposed system over other published systems. Visual assessment show our proposed system's potential at preserving edges and reducing speckle. Quantitative analysis shows that our proposed system outperforms previously published systems when evaluated with metrics such as Peak Signal-to-Noise Ratio, Coefficient of Correlation, and Effective Number of Looks. These results show the potential of our proposed system as an effective tool for enhancing 3-D row-column imaging.

An Optimization and Comparative Study of Air-Coupled CMUT Cells With Circular and Annular Geometries.

Air-coupled capacitive micromachined ultrasonic transducers (CMUTs) with annular cell geometry have recently been reported to have a promising transmit sensitivity. This paper reports three optimization schemes, which further improve the transmit sensitivity and also help achieve a reasonable comparison between the novel annular and conventional circular cells. Lumped element models of both cell types with laminate plate structures are presented. Based on these models, a design optimization flowchart was constructed to facilitate analytical optimization on the three schemes. Circular and annular CMUTs with a common 97-kHz natural resonance frequency were fabricated and characterized to verify the efficacy of the optimization principle. Using the optimization flowchart, annular and circular cells with frequencies ranging from 100 to 300 kHz were analytically optimized and then compared. The comparison results demonstrate that, given the same dc bias and ac excitation voltage, the output power density at the plate surface of the optimized annular cell is double that of the optimized circular cell. Additionally, when generating the same surface power density, an optimized annular cell requires either half the dc bias or half the ac excitation voltage of an optimized circular cell. This paper provides a practical optimization framework for CMUT cell design and demonstrates the superiority of annular cells for air-coupled applications.

Internal Model-Based Robust Tracking Control Design for the MEMS Electromagnetic Micromirror.

The micromirror based on micro-electro-mechanical systems (MEMS) technology is widely employed in different areas, such as scanning, imaging and optical switching. This paper studies the MEMS electromagnetic micromirror for scanning or imaging application. In these application scenarios, the micromirror is required to track the command sinusoidal signal, which can be converted to an output regulation problem theoretically. In this paper, based on the internal model principle, the output regulation problem is solved by designing a robust controller that is able to force the micromirror to track the command signal accurately. The proposed controller relies little on the accuracy of the model. Further, the proposed controller is implemented, and its effectiveness is examined by experiments. The experimental results demonstrate that the performance of the proposed controller is satisfying.

Numerical and experimental study of radiation induced conductivity change of carbon nanotube filled polymers.

Measuring the conductivity changes of sensing materials to detect a wide range of radiation energy and dosage is one of the major sensing mechanisms of radiation sensors. Carbon nanotube (CNT) filled composites are suitable for sensing radiation because of the extraordinary electrical properties of CNTs and the CNT-network formed inside the polymer matrix. Although the use of CNT-based nanocomposites as potential radiation sensing materials has been widely studied, there is still a lack of theoretical models to analyze the relationship between electrical conductivity and radiation dosages. In this article, we propose a 3D model to describe the electrical conductivity of CNT-based nanocomposites when being irradiated by ionizing radiation. The Monte Carlo method has been employed to calculate radiation intensity, CNT concentration and alignment's influence on the electrical conductivity. Our simulation shows a better agreement when CNT loading is between the percolation threshold and 3% volume fraction. Radiation experiments have been performed to verify the reliability of our model to illustrate a power function relationship between the electrical conductivity of a CNT-filled polymer and radiation intensity. In addition, the predicted alignment to obtain the best sensitivity for radiation sensing has been discussed to help with CNT-network building in the fabrication process.

A novel field emission microscopy method to study field emission characteristics of freestanding carbon nanotube arrays.

Field emission (FE) uniformity and the mechanism of emitter failure of freestanding carbon nanotube (CNT) arrays have not been well studied due to the difficulty of observing and quantifying FE performance of each emitter in CNT arrays. Herein a field emission microscopy (FEM) method based on poly(methyl methacrylate) (PMMA) thin film is proposed to study the FE uniformity and CNT emitter failure of freestanding CNT arrays. FE uniformity of freestanding CNT arrays and different levels of FE current contributions from each emitter in the arrays are recorded and visualized. FEM patterns on the PMMA thin film contain the details of the CNT emitter tip shape and whether multiple CNT emitters occur at an emission site. Observation of real-time FE performance and the CNT emitter failure process in freestanding CNT arrays are successfully achieved using a microscopic camera. High emission currents through CNT emitters causes Joule heating and light emission followed by an explosion of the CNTs. The proposed approach is capable of resolving the major challenge of building the relationship between FE performance and CNT morphologies, which can significantly facilitate the study of FE non-uniformity, the emitter failure mechanism and the development of stable and reliable FE devices in practical applications.

Influence of zeolite shape and particle size on their capacity to adsorb uremic toxin as powders and as fillers in membranes.

Membranes with zeolites are promising for performing blood dialysis because zeolites can eliminate uremic toxins through molecular sieving. Although the size and the shape of zeolite particles can potentially influence the performance of the membranes with respect of creatinine uptake level, it is not clear what sizes and shapes lead to better performance. In this paper, we carry out experiments to answer this question. Spherical microparticle 840, spherical nanoparticle P-87 and rod-like nanoparticle P-371 zeolites were chosen to be used in all the experiments. Their creatinine uptake levels were first measured as powders in creatinine solutions with different concentrations, volumes and adsorption times. Then, nanofibrous membranes with zeolites were electrospun and their ability to adsorb creatinine was measured and compared against their respective powders' creatinine uptake level. The experiment shows that the zeolites have similar creatinine uptake ability as powders. However, they have significantly different creatinine uptake ability after being incorporated inside the membranes. Spherical microparticle 840 in the membrane presented the best creatinine uptake ability, at 8957 µg g-1 , which was half of its powders'. On the other hand, P-87 presented largely decreased, while P-371 presented even lower creatinine uptake ability in membranes when compared to respective powders'. The results shows that microparticle and sphere shaped particles perform better inside the membranes. © 2016 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 105B: 1594-1601, 2017.