Dataset comparing the growth of fodder crops and soil structure dynamics in an industrial biosludge amended arid soil.

The dataset in this work compares the response of two fodder crops, alfalfa (Medicago sativa) and buffel grass (Cenchrus ciliaris), to industrial biosludge amendment of an arid soil in the State of Qatar. It also evaluates the response of soil structure parameters in the biosludge-amended soils containing the different fodder crops. The dataset relates to our previously published works detailed subsequently. The underlying data comparing the water storage capacity and pore structure evolution of the planted soils treated with 0.75, 1.5, and 3% biosludge contents, which showed good outcomes in the companion articles, alongside soil only and soil-fertilizer controls, are presented. These are shown in terms of the percentage of irrigation water leached, and variations in the logarithmic mean T2 (i.e., T2LM - a proxy for mean pore size) and cumulative porosity, respectively. Data on plant growth parameters such as the number of days to flowering, plant height, and aboveground fresh biomass weight in individual replicates of the different treatments as a percentage of the soil-fertilizer control are also shown. The dataset shows the different responses of both plants and the planted soils to amendments with industrial biosludge from the wastewater treatment plant of a gas-to-liquid (GTL) plant.

Recycling industrial biosludge for buffel grass production in Qatar: Impact on soil, leachate and plant characteristics.

The agricultural industry in Qatar is highly dependent on using soil enhancing materials due to challenging soil and climatic conditions. Hence, this work investigated the potential of industrial biosludge from the wastewater treatment plant (WWTP) of a Gas-to-Liquids (GTL) plant to enhance an arid soil compared to fertilizer and compost. A fodder crop, buffel grass (Cenchrus ciliaris), was grown in semi-controlled pots containing a typical Qatari agricultural soil and admixtures over a 12-month period. The treatments included soil plus five biosludge percentage contents: 0.75, 1.5, 3, 6 and 12%. These were compared with soil only, soil plus 20-20-20 NPK fertilizer and soil plus 3% compost controls. Analyses of soil physical and chemical properties, the resulting leachate, and plant growth characteristics were conducted at set periods. The results indicate that up to 3% biosludge content led to better plant growth compared to the controls, with the optimum at 1.5% biosludge content for all growth characteristics studied. Biosludge addition to soil increased the volume of different pore types, especially micropores, which enhanced water retention and influenced plant growth. Regression modelling identified leachate Si and Fe concentrations, and biomass K content as the most influential variables for fresh biomass weight, plant height and the number of tillers, respectively. Biosludge addition to the soil around the optimum level did not cause detrimental changes to the resulting leachate and plant biomass. The findings of this work could lead to minimization of biosludge landfilling and allow for savings in fertilizers and irrigation water in arid regions.

Dataset on the influence of gas-to-liquid biosludge on arid soil properties and growth performance of alfalfa.

The dataset presented here is related to our research article entitled "Effect of gas-to-liquid biosludge on soil properties and alfalfa yields in an arid soil" [1]. It relates to selected performance parameters of alfalfa grown in an arid soil amended with five different (0.75-12%) gas-to-liquid biosludge contents, and selected properties of the soil determined using several material characterization techniques. A detailed description of the raw data relating to figures on alfalfa performance parameters such as fresh biomass weight, plant height, the number of tillers, and biomass elemental content in the companion article is provided alongside additional data on the number of days to flowering. The underlying data for leachate from the soil and underlying spectra and diffractograms for the proton nuclear magnetic resonance (1H-NMR) and X-ray diffraction (XRD) data, respectively, shown in the companion article are presented. These show changes in the pore structure characteristics and the mineralogical composition of the soil, soil-fertilizer, soil-biosludge, and soil-compost mixtures tested over time. Additional data showing the effect of the amendments on the bulk and particle densities of the soil is presented. The dataset demonstrates the influence of the industrial biosludge on arid soil properties and alfalfa yields (Kogbara et al., [1]).

A flexible Ti3C2T x (MXene)/paper membrane for efficient oil/water separation.

The scalable fabrication of flexible membranes for efficient oil/water separation is in high demand but still significantly underdeveloped. Here, we present a flexible membrane using Ti3C2T x (MXene) as the functional layer on conventional print paper as the substrate. With a simple coating process using MXene ink, we developed a highly hydrophilic and oleophobic membrane with an underwater oil contact angle of 137°. Such a simple membrane shows outstanding flexibility and robustness, and demonstrates a facile approach for membrane scale-up using MXene ink on low-cost print paper. The membrane shows high separation efficiency for oil/water emulsions, of over 99%, and a high water permeation flux of over 450 L per m2 per h per bar. We demonstrate the excellent anti-fouling property of this membrane by cleaning the membranes without chemicals. These low-cost, highly efficient, anti-fouling membranes can provide new opportunities for industrial oil/water separation applications.

Recyclable and Reusable Heteroleptic Nickel Catalyst Immobilized on Metal-Organic Framework for Suzuki-Miyaura Coupling.

Metal-organic frameworks (MOFs) provide highly versatile platforms to stabilize molecular catalysts that are not readily accessible under homogeneous conditions, thus enabling access to a new set of catalytic materials. Herein, we describe a recyclable and highly active nickel catalyst immobilized on MOF for Suzuki-Miyaura coupling reaction, which operates under mild conditions. This mixed ligand catalyst forms from the combination of 1 equiv of MOF-immobilized ligand, 1 equiv of nickel source, and 1 equiv of PPh3. The nature of the catalyst was verified through a series of analytical tests and catalysis experiments. The immobilized catalyst was reusable for at least up to 7 cycles without decrease in the yield of the coupled product. We also verified that this reaction does not work under homogeneous conditions and that the reaction is truly heterogeneous through "hot filtration" experiments. We identified that the reaction is first order in arylborane concentration and negative order in arylbromide concentration through the effect of substrate concentrations on the initial rate. This informed us to conduct the catalysis under slow addition of the arylbromide and reduce the catalyst loading to 1% from 3%, without detriment to the yield or rate of the reaction. The catalyst gave good to excellent isolated yields with a range of functionalities, including heterocycles on aryl bromide with widely varying electronic properties.

A Novel Architecture for Carbon Nanotube Membranes towards Fast and Efficient Oil/water Separation.

Carbon nanotubes (CNT) are robust and proven as promising building blocks for oil/water separating membranes. However, according to classic fluid dynamic theory, achieving high permeation flux without sacrificing other membrane properties is a formidable challenge for CNT membranes, because of the trade-off nature among key membrane parameters. Herein, to relieve the trade-off between permeation fluxes, oil rejection rate, and membrane thickness, we present a new concept to engineer CNT membranes with a three-dimensional (3D) architecture. Apart from achieving high oil separation efficiency (>99.9%), these new oil/water separating membranes can achieve water flux as high as 5,500 L/m2.h.bar, which is one order of magnitude higher than pristine CNT membranes. Most importantly, these outstanding properties can be achieved without drastically slashing membrane thickness down to nanoscale. The present study sheds a new light for the adoption of CNT-based membranes in oil/water separation industry.

A windable and stretchable three-dimensional all-inorganic membrane for efficient oil/water separation.

There is strong interest in windable and stretchable membranes to meet the technological demands of practical water treatments. Oil/water separating membranes of this type is still significantly underdeveloped. Here, we reported a windable and stretchable membrane with three-dimensional structure for efficient oil/water separation. This membrane is made of ZnO nanorods arrays conformally grown on woven carbon microfibers. This three-dimensional architecture endows the fabricated membrane with highly windable and stretchable properties, at the same time ensures ZnO nanorods fully exposed outwards on the membrane surface. Due to its superior hydrophilicity and oleophobicity of ZnO nanorods, this all-inorganic membrane exhibits outstanding antifouling property, with the foulants on membrane surfaces easily removed by simple physical cleaning without chemicals. The membrane can effectively separate both oil/saline-water mixtures and oil-in-water emulsions, solely driven by gravity, with extremely high permeation flux of 20933.4 L m-2 h-1 and high separation efficiency over 99%.

Improved Self-cleaning Properties of an Efficient and Easy to Scale up TiO2 Thin Films Prepared by Adsorptive Self-Assembly.

Transparent titania coatings have self-cleaning and anti-reflection properties (AR) that are of great importance to minimize soiling effect on photovoltaic modules. In this work, TiO2 nanocolloids prepared by polyol reduction method were successfully used as coating thin films onto borosilicate glass substrates via adsorptive self-assembly process. The nanocolloids were characterized by transmission electron microscopy and x-ray diffraction. The average particle size was around 2.6 nm. The films which have an average thickness of 76.2 nm and refractive index of 1.51 showed distinctive anti soiling properties under desert environment. The film surface topography, uniformity, wettability, thickness and refractive index were characterized using x-ray diffraction, atomic force microscopy, scanning electron microscopy, water contact angle measurements and ellipsometry. The self-cleaning properties were investigated by optical microscopy and UV-Vis spectroscopy. The optical images show 56% reduction of dust deposition rate over the coated surfaces compared with bare glass substrates after 7 days of soiling. The transmission optical spectra of these films collected at normal incidence angle show high anti-reflection properties with the coated substrates having transmission loss of less than 6% compared to bare clean glass.

A flexible, robust and antifouling asymmetric membrane based on ultra-long ceramic/polymeric fibers for high-efficiency separation of oil/water emulsions.

Polymeric and ceramic asymmetric membranes have dominated commercial membranes for water treatment. However, polymeric membranes are prone to becoming fouled, while ceramic membranes are mechanically fragile. Here, we report a novel concept to develop asymmetric membranes based on ultra-long ceramic/polymeric fibers, with the combined merits of good mechanical stability, excellent fouling resistance and high oil/water selectivity, in order to meet the stringent requirements for practical oil/water separation. The ultra-long dimensions of ceramic nanofibers/polymeric microfibers endow this novel membrane with mechanical flexibility and robustness, due to the integrated and intertwined structure. This membrane is capable of separating oil/water emulsions with high oil-separation efficiency (99.9%), thanks to its nanoporous selective layer made of ceramic nanofibers. Further, this membrane also displays superior antifouling properties due to its underwater superoleophobicity and ultra-low oil adhesion of the ceramic-based selective layer. This membrane exhibits high water permeation flux (6.8 × 104 L m-2 h-1 bar-1) at low operation pressures, which is attributed to its 3-dimensional (3D) interconnected fiber-based structure throughout the membrane. In addition, the facile fabrication process and inexpensive materials required for this membrane suggest its significant potential for industrial applications.