Novel photocatalyst gold nanoparticles with dumbbell-like structure and their superiorly photocatalytic performance for ammonia borane hydrolysis.

Gold nanoparticles (Au NPs) have attracted remarkable research interests in heterogeneous catalysis due to their unique physical and chemical properties. However, only small-size Au NPs (<7 nm) exhibit promising catalytic activity. In this work, dumbbell-like Au NPs (D-Au NPs) with average size of 37 × 11 nm were prepared by a secondary seed-mediated growth method to serve as novel photocatalyst for ammonia borane (AB) hydrolysis in the solution with specific pH value. Our results demonstrate that ⅰ) the strengthened LSPR compensation effect could effectively remedy the loss of catalytic activity resulting from the size enlarging of D-Au NPs, proven by that the heating power of a single Au nanoparticle (Ps) and turnover frequency of AB molecules within 10 minutes of D-Au NPs are 52.5 and 3.89 times higher than that of spherical Au NPs; ⅱ) the extinction coefficient and Ps of D-Au NPs are almost 2.72 and 2.42 times as high as that of rod-like Au NPs, demonstrating the promoting structure-property relationship of dumbbell-like structure.; ⅲ) when the pH value of AB solution was lower than 6.0, the hydrolysis rate was highly promoted, indicating that H+ ions play an active role in the hydrolysis process. This work greatly extends the application of noble metals and provides a new insight into AB hydrolysis.