Deseasonalized trend of ground-level ozone and its precursors in an industrial city Kaohsiung, Taiwan.

Mitigating ground-level ozone (GLO) remains challenging due to its highly nonlinear formation process. Thus, understanding GLO pollution trends is crucial for developing effective control strategies, especially Kaohsiung industrial city, Taiwan. Based on the long-term monitoring data set of 2011-2022, temporal analysis reveals that monthly mean GLO peaks in autumn (40.66 ± 5.10 ppb), carbon monoxide (CO) and major precursors such as nitrogen oxides (NOx), nonmethane hydrocarbons (NMHC) reach their highest levels in winter. The distinct seasonal variation of air pollutants in Kaohsiung is primarily influenced by the unique blocking effect of the mountainous area under the northeasterly wind, as the city is situated downwind, causing high GLO levels during autumn due to the accumulation of stagnant air hindering the dispersion of pollutants. Over the 12 years (2011-2022), the deseasonalized trend analysis was conducted with p < 0.001, revealing a stabilization trend of GLO (+0.04 ppb/yr) from a previous sharp increase. The observed improvement is credited to a drastic decrease in total oxidants (Ox) at -0.63 ppb/yr due to significantly reducing their precursors. Furthermore, the effectiveness of precursor reduction is also supported by GLO daily maximum profile changes. While high GLO events (>120 ppb) decrease, days within midrange (60-80 ppb) rise from 24.4% to 33.3%. A notable difference emerges when comparing daytime and nighttime GLO. While daytime GLO decreased at -0.22 ppb/yr, nighttime GLO increased at +0.34 ppb/yr. Weakened nocturnal titration effects accounted for the nighttime increase. The distinct spatial variations in GLO trends on a citywide scale underscore that areas with complicated industrial activities may not benefit from a continuing reduction of precursors compared to less-polluted areas. The findings of this study hold significant implications for improving GLO control strategies in heavily industrialized city and provide valuable information to the general public about the current state of GLO pollution.

Impacts of ship emissions and sea-land breeze on urban air quality using chemical characterization, source contribution and dispersion model simulation of PM2.5 at Asian seaport.

Fine particulate matter (PM2.5) emitted from marine transportation, bulk materials handling at the docks, and dust dispersion has garnered increased attention, particularly in the interface between port and urban areas. This study explored the inter-transport of PM2.5 between Kaohsiung Harbor and neighboring Metro Kaohsiung. Chemical analyses of PM2.5 samples from four sites include water-soluble ions, metallic elements, carbons, anhydrosugars, and organic acids to establish PM2.5's chemical fingerprints. The CALPUFF air dispersion model is employed to simulate the spatiotemporal distribution of PM2.5 in Kaohsiung Harbor and adjacent urban areas. A clear seasonal and diurnal variation of PM2.5 concentrations and chemical composition was observed in both harbor and urban areas. The high correlation of nighttime PM2.5 levels between the port and urban areas suggests inter-transport phenomena. Sea salt spray, ship emissions, secondary aerosols, and heavy fuel-oil boilers exhibit higher levels in the port area than in the urban area. In Metro Kaohsiung, mobile sources, fugitive dust, and waste incinerators emerge as major PM2.5 contributors. Furthermore, sea breeze significantly influences PM2.5 dispersion from Kaohsiung Harbor to Metro Kaohsiung, particularly in the afternoon. The average contribution of PM2.5 from ships' main engines in Kaohsiung Harbor ranges from 2.9% to 5.3%, while auxiliary engines contribute 3.8%-8.3% of PM2.5 in Metro Kaohsiung.

Identification of potential source regions and long-range transport routes/channels of marine PM2.5 at remote sites in East Asia.

Long-range transport (LRT) of air masses in East Asia and their impacts on marine PM2.5 were explored. Situated in the leeward region of East Asia, Taiwan Island marked by its elevated Central Mountain Range (CMR) separates air masses into two distinct air currents. This study aims to investigate the transport of PM2.5 from the north to the leeward region. Six transport routes (A-F) were identified and further classified them into three main channels (i.e. East, West, and South Channels) based on their transport routes and potential sources. Green Island (Site GR) and Hengchun Peninsula (Site HC) exhibited similarities in their transport routes, with Central China, North China, and Korean Peninsula being the major source regions of PM2.5, particularly during the Asian Northeastern Monsoons (ANMs). Dongsha Island (Site DS) was influenced by both Central China and coastal regions of East China, indicating Asian continental outflow (ACO) as the major source of PM2.5. The positive matrix factorization (PMF) analysis of PM2.5 resolved that soil dust, sea salts, biomass burning, ship emissions, and secondary aerosols were the major sources. Northerly Channels (i.e. East and West Channels) were primarily influenced by ship emissions and secondary aerosols, while South Channel was dominated by oceanic spray and soil dust. The results of W-PSCF and W-CWT analysis indicated that three remote sites experienced significant contributions from Central China in the highest PM2.5 concentration range (75-100%). In contrast, PM2.5 in the 0-25% and 25-50% ranges primarily originated from the open seas, with ship emissions being the prominent source. It suggested that northern regions with heavy industrialization and urbanization have impacts on high PM2.5 concentrations, while open seas are the main sources of low PM2.5 concentrations.

Epigenetic transgenerational effects of PM2.5 collected from southern Taiwan on sperm functions and DNA methylation in mouse offspring.

During respiration, particulate matter with a diameter of 2.5 µm or less (PM2.5) suspended in the atmosphere enters the terminal alveoli and blood. PM2.5 particles can attach to toxic substances, resulting in health problems. Limited information is available regarding the effects of prenatal exposure to water-soluble PM2.5 (WS-PM2.5) and water-insoluble PM2.5 (WI-PM2.5) on male reproduction. In addition, whether exposure to these particles has transgenerational effects remains unknown. We investigated whether prenatal exposure to WS-PM2.5 and WI-PM2.5 disrupts sperm function in generations F1, F2, and F3 of male mice. Pregnant BALB/c mice were treated using intratracheal instillation on gestation days 7, 11, and 15 with 10 mg of a water extract or insoluble PM2.5. On postnatal day 105, epididymal sperm count, motility, morphology, mitochondrial membrane potential (MMP), reactive oxygen species (ROS) production, the sperm chromatin DNA fragmentation index (DFI), and testicular DNA methyltransferase (Dnmt) levels were evaluated in all generations. Whole-genome bisulfite sequencing was used to analyze the DNA methylation status of generation F3. According to the results, exposure to WS-PM2.5 affected sperm morphology, ROS production, and mean DFI in generation F1; ROS production and mean DFI in generation F2; and sperm morphology and MMP in generation F3. Similarly, exposure to WI-PM2.5 affected sperm morphology, ROS production, mean DFI, %DFI, and Dnmt1 expression in generation F1; sperm morphology, MMP, and ROS production in generation F2; and sperm morphology, ROS, and %DFI in generation F3. Two hypermethylated genes, PRR16 and TJP2, were observed in the WS-PM2.5 and WI-PM2.5 groups, two hypomethylated genes, NFATC1 and APOA5, were observed in the WS-PM2.5 group, and two hypomethylated genes, ZFP945 and GSE1, were observed in the WI-PM2.5 group. Hence, prenatal exposure to PM2.5 resulted in transgenerational epigenetic effects, which may explain certain phenotypic changes in male reproduction.

Spatiotemporal variation and inter-transport of atmospheric speciated mercury between Kaohsiung Harbor and neighboring urban areas.

This study investigated the spatiotemporal variation, gas-particle partition, and source resolution of atmospheric speciation mercury (ASM) in Kaohsiung Harbor and neighboring Metro Kaohsiung. Four sampling sites were selected to determine the pollution characteristics and inter-transport of ASM between the port and urban areas. The yearly average GEM, GOM, and PBM concentrations were 7.13 ± 2.2 ng/m3, 331 ± 190 pg/m3, and 532 ± 301 pg/m3, respectively. Notably, GEM emerged as the predominant ASM species (85-94%), primarily originating from anthropogenic emissions from the harbor area and nearby industrial complex. The study revealed a distinct seasonal variation in ASM concentrations in the Kaohsiung Area in the following order: winter > fall > spring > summer. Concerning spatial distribution, ASM concentrations in the port areas were generally higher than those in the urban areas. This disparity was chiefly attributed to the influence of the prevailing winds, local sources, and atmospheric dispersion. Backward trajectory simulation revealed that polluted air masses blown from the northeast in winter and spring, moving along the western in-land part of Taiwan Island, were likely influenced by local sources and long-range transport (LRT). In summer, air pollutants originating from the south were likely transported from the coastal industrial sources. During fall, air masses blown from the western offshore waters transported air pollutants from Kaohsiung Harbor to neighboring Metro Kaohsiung. The results obtained from principle component analysis (PCA) indicated that primary sources in the port areas included ship emissions, vehicular exhausts, and nearby industrial complex, which align with the primary source factors identified by positive matrix factorization (PMF), which were mobile sources and coal-fired industrial boilers. Meanwhile, mobile sources and sulfur-containing fuel/waste combustion were identified as the primary sources in the urban areas.

Emission characteristics of naphthalene from ship exhausts under global sulfur cap.

The global sulfur limit regulation mandates the use of 0.5 % low sulfur fuel oil (LSFO) to reduce emissions of sulfur oxides (SOx), nitrogen oxides (NOx), and particulate matter (PM). However, the addition of naphthalene (Nap) to LSFO to stabilize its quality has led to an increase in polycyclic aromatic hydrocarbons (PAHs), with Nap being the main pollutant. This study investigates the effects of Nap in ship exhaust by analyzing the emission concentrations of volatile organic compounds (VOCs) and Nap in the exhaust of 16 ships, including 2 container ships, 6 bulk carriers, 1 tanker, 2 ferries, 3 fishing vessels, and 2 harbor crafts, based on USEPA method TO-15A. The results show that the percentage of Nap emissions in the exhaust gases of the 16 ship engines ranged from 77 % to 97 % of the total volatile organic compound (TVOC). The Nap concentration in the exhaust of fishing vessels, tanker, and harbor craft exceeded the occupational exposure limit of 50,000 µg/m3, with fishing vessels having the highest TVOC and Nap concentrations. The enhanced Nap emission in the air degrades air quality in port cities and poses an obvious potential public health risk. While the benefits of the global sulfur cap are being secured, additional efforts should be made to reduce the undetected side effects. Alternative stabilizers of LSFO should be considered, or Nap emission control should be boosted to mitigate the potential negative impact on harbor air quality.

Chemical characteristics and spatiotemporal variation of marine fine particles for clustered channels of air masses transporting toward remote background sites in East Asia.

This study investigated the chemical characteristics, spatiotemporal distribution, and source apportionment of marine fine particles (PM2.5) for clustered transport channels/routes of air masses moving toward three remote sites in East Asia. Six transport routes in three channels were clustered based on backward trajectory simulation (BTS) in the order of: West Channel > East Channel > South Channel. Air masses transported toward Dongsha Island (DS) came mainly from the West Channel, while those transported toward Green Island (GR) and Kenting Peninsula (KT) came mostly from the East Channel. High PM2.5 commonly occurred from late fall to early spring during the periods of Asian Northeastern Monsoons (ANMs). Marine PM2.5 was dominated by water-soluble ions (WSIs) which were predominated by secondary inorganic aerosols (SIAs). Although the metallic content of PM2.5 was predominated by crustal elements (Ca, K, Mg, Fe, and Al), enrichment factor clearly showed that trace metals (Ti, Cr, Mn, Ni, Cu, and Zn) came mainly from anthropogenic sources. Organic carbon (OC) was superior to elemental carbon (EC), while OC/EC and SOC/OC ratios in winter and spring were higher than those in other two seasons. Similar trends were observed for levoglucosan and organic acids. The mass ratio of malonic acid and succinic acid (M/S) was commonly higher than unity, showing the influences of biomass burning (BB) and secondary organic aerosols (SOAs) on marine PM2.5. We resolved that the main sources of PM2.5 were sea salts, fugitive dust, boiler combustion, and SIAs. Boiler combustion and fishing boat emissions at the site DS had higher contribution than those at the sites GR and KT. The highest/lowest contribution ratios of cross-boundary transport (CBT) were 84.9/29.6% in winter and summer, respectively.

Chemical fingerprints and source resolution of atmospheric fine particles in an industrial harbor based on one-year intermittent field sampling data.

This study investigated the spatiotemporal variation, chemical characteristics, and source resolution of PM2.5 in an East Asian seaport adjacent to industrial complex and urban area. Three representative harbor sites were selected to simultaneously sample 24-h PM2.5 once every 13 days in four seasons. A significant seasonal variation was observed with the highest and the lowest PM2.5 concentration in February (winter) and May (summer), respectively. High contribution of secondary inorganic aerosols (SIAs) showed that SO2 and NOx emitted from neighboring combustion sources burning coal and heavy fuel oil (HFO) were the major precursors forming secondary inorganic PM2.5. High ratios of V/Ni and V/Cu were observed in summer (June~August) since the prevailing west and southwest winds from outer port carried ship emissions to inter port. The correlation of chemical fingerprints (V, Ni, V/Ni, Zn, nss-SO42-, OC) and the number of ships were high at the Zhung-He Site and moderate at the Qi-Ho Site. The Cl-, Na+, V, Ni, nss-SO42-, OC, and V/Ni of PM2.5 were co-influenced by ship missions and oceanic spray in the Kaohsiung Harbor. The influences were relatively higher for winds blown from the harbor areas than those blown from the industrial areas. Oppositely, the Fe, Mn, Cr, Cu, Ca, Zn, and Al in PM2.5 were higher for winds blown from the industrial areas than those from the harbor areas. The CMB receptor modelling resolved that the major sources of PM2.5 were industrial missions, secondary aerosols, mobile sources, ship emissions, oceanic spray, fugitive dust, biomass burning, and organic carbon. Similar to Busan (South Korea), Brindisi (Italy), Lampedusa (Italy), and Barcelona (Spain), the contributions of ship emissions in the Kaohsiung Harbor were in the range of 7.4-7.8 %. Meanwhile, Kaohsiung Harbor was highly influenced by emissions from industrial areas and urban areas.

Volatile organic compounds in ambient air of a major Asian port: spatiotemporal variation and source apportionment.

This study investigated the spatiotemporal variation and source characteristics of volatile organic compounds (VOCs) in Kaohsiung Harbor, one of the busiest ports in the world. The VOCs' potential to form ozone (O3) and secondary organic aerosols (SOAs) was also examined. The temporal variation was studied in February, May, July, and November of 2020, while the spatial distribution was investigated in the export processing zone (KEPZ) and at the two port entrances (E1 and E2). The most polluted month in the harbor was November (37.7 ± 12.6 ppbv), while the most polluted site was the industrial area (KEPZ). A significant positive correlation was found between VOCs and O3 (r = 0.985). Meanwhile, a moderate positive correlation (r = 0.449) was observed between VOCs and secondary organic aerosol formation potential (SOAFP), mainly affected by the concentration of toluene in the study area. The diagnostic ratios indicated that the air parcels in the site were "fresh," and three possible ambient sources of VOC were identified by the positive matrix factorization (PMF): industrial emissions (53.6%), freight transport emissions (29.6%), and others (17.7%). The study highlights the current state of VOCs and their potential sources in the port city of Kaohsiung, which can be used to enhance the strategies for regulating and controlling industrial activities and improving air pollution control measures to reduce VOC emissions.

Long-range transport of atmospheric speciated mercury from the eastern waters of Taiwan Island to northern South China Sea.

This study explored the temporospatial distribution, gas-particle partition, and pollution sources of atmospheric speciated mercury (ASM) from the eastern offshore waters of the Taiwan Island (TI) to the northern South China Sea (SCS). Both gaseous and particulate mercury were simultaneously sampled at three remote sites in four seasons. The average concentrations of gaseous elemental mercury (GEM), gaseous oxidized mercury (GOM), and particulate bound mercury (PBM) were 2.05 ± 0.45 ng/m3, 19.17 ± 5.39 pg/m3, and 0.11 ± 0.06 ng/m3, respectively. The concentrations of GEM and PBM in the cold seasons were higher than those in the warm seasons, but those of GOM had an opposite trend. In terms of gas-solid partition, ASM was apportioned as 91.3-97.3% of GEM and 2.7-8.7% of GOM and PBM. The average concentrations of GEM, GOM, and PBM at the Green Island (GI) were 2.21 ± 0.47 ng/m3, 22.31 ± 5.35 pg/m3, and 0.12 ± 0.06 ng/m3; those at the Kenting Peninsula (KT) were 2.11 ± 0.43 ng/m3, 20.57 ± 4.38 pg/m3, and 0.11 ± 0.06 ng/m3; and those at the Dongsha Islands (DS) were 1.84 ± 0.40 ng/m3, 15.19 ± 3.58 pg/m3, and 0.08 ± 0.05 ng/m3, respectively. Overall, the spatial distribution of ASM concentrations showed the order as: GI > KT > DS. Air masses blown mainly from the West Pacific Ocean (WPO) and SCS in summer showed the lowest ASM concentrations. Oppositely, high ASM concentrations were commonly observed in spring and winter when polluted air masses were blown by Asian Northeastern Monsoons (ANMs). The transport routes of polluted air masses were originated mainly from North China, Central China, Northeast China, Korea and Japan, and mostly passed through the urban and industrial regions in the northeastern Asian countries.

Inter-comparison of chemical fingerprint and source apportionment of marine fine particles at two islands through the west and east passages of the Taiwan Island.

In this study, the concentrations of marine fine particles (PM2.5) and their chemical fingerprints were inter-compared at two islands located aside from the west and east waters of Taiwan Island and the variability of west and east passages (i.e., Routes A1 and A2) were explored. Marine PM2.5 was simultaneously sampled at the Green and Dongsha Islands and five chemical components (i.e., water-soluble ions, metallic elements, carbonaceous content, anhydrosugars, and organic acids) were further analyzed in PM2.5 to characterize their chemical fingerprints. The highest concentrations of chemical composition and PM2.5 were commonly observed during the Asian Northeastern Monsoons (ANMs) via long-range transport (LRT). Water-soluble ions (WSIs) were dominated by secondary inorganic aerosols (SIAs), and followed by oceanic spray. The major metallic content of PM2.5 was crustal elements, while trace metals originated from anthropogenic sources with an enrichment factor (EF) > 10. In terms of carbonaceous content in PM2.5, organic carbon (OC) was superior to elemental carbon (EC). High levoglucosan concentrations were also observed during the periods of ANMs. Secondary organic aerosols (SOAs) were formed by atmospheric chemical reactions during the LRT procedure. The PM2.5 concentration of Route A1 was 37.51 % higher than that of Route A2, and trace metals (V, Mn, Ni, Pb, Cr, and Cu) increased significantly by 96.16-325.83 %. Positive matrix factorization (PMF) results revealed that the dominant factor of PM2.5 for Route A1 was shipping emissions and vehicular exhausts (41.2 %), while that for Route A2 was oceanic spray (30.2 %). Route A1 was mainly attributed to highly industrialized regions, densely populated urbanized areas, and ship-intensive traffics in East Asia.

Kidney damage induced by repeated fine particulate matter exposure: Effects of different components.

BACKGROUND: Exposure to fine particulate matter with an aerodynamic diameter of ≤2.5 µm (PM2.5) is associated with adverse health effects. This study aimed to evaluate the toxic effects of the constituents of PM2.5 on mouse kidneys. METHODS: We collected PM2.5 near an industrial complex located in southern Kaohsiung, Taiwan, that was divided into water extract and insoluble particles. Male C57BL/6 mice were divided into five groups: control, low- and high-dose insoluble particle exposure, and low- and high-dose water extract exposure. Biochemical analysis, Western blot analysis, histological examination, and immunohistochemistry were performed to evaluate the impact of PM2.5 constituents on mice kidneys. RESULTS: PM2.5 was collected from January 1, 2021, to February 8, 2021, from an industrial complex in Kaohsiung, Taiwan. Metallic element analysis showed that Pb, Ni, V, and Ti were non-essential metals with enrichment factors >10. Polycyclic aromatic hydrocarbon and nitrate polycyclic aromatic hydrocarbon analyses revealed that the toxic equivalents are, in the order, benzo(a)pyrene (BaP), indeno(1,2,3-cd) pyrene (IP), dibenzo(a,h)anthracene (DBA), and benzo(b)fluoranthene (BbF), which are potential carcinogens. Both water extract and insoluble particle exposure induced inflammatory cytokine upregulation, inflammatory cell infiltration, antioxidant activity downregulation, and elevation of kidney injury molecule 1 (KIM-1) level in mouse kidneys. A dose-dependent effect of PM2.5 water extract and insoluble particle exposure on angiotensin converter enzyme 2 downregulation in mouse kidneys was observed. CONCLUSION: We found that water-soluble extract and insoluble particles of PM2.5 could induce oxidative stress and inflammatory reactions, influence the regulation of renin-angiotensin system (RAS), and lead to kidney injury marker level elevation in mouse kidneys. The lowest-observed-adverse-effect level for renal toxicity in mice was 40 µg water-soluble extract/insoluble particle inhalation per week, which was approximately equal to the ambient PM2.5 concentration of 44 µg/m3 for mice.

Surface design of g-C3N4 quantum dot-decorated TiO2(001) to enhance the photodegradation of indoor formaldehyde by experimental and theoretical investigation.

Formaldehyde (CHOH), a common volatile organic compound, causes many adverse effects on human health. The highly exposed TiO2(001) facet possesses a high photodegradation efficiency of CHOH due to its excellent ability to trap photogenerated holes and high density of surface unsaturated Ti atoms (Ti5c) to bind CHOH. However, the rapid recombination of photoinduced electron-hole pairs of TiO2(001) limits the photodegradation efficiency. We adopted a strategy of decorating TiO2(001) with g-C3N4 quantum dots (QDs), exploiting the quantum effect of g-C3N4QDs and their combined staggered band structure. This decoration improves the photocatalytic activity of TiO2(001). Moreover, the chemical configuration of g-C3N4QDs/TiO2(001) and the combination mode between the g-C3N4QDs and TiO2(001) support were explored in detail using high-resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS), and density functional theory (DFT) calculations. Following the physiochemical characteristic results, the transport mechanism of photoinduced carriers was further analyzed by ultraviolet photoelectron spectroscopy (UPS), electron paramagnetic resonance (EPR), and Heyd-Scuseria-Ernzerh (HSE) exchange-correlation functional calculations. Finally, the performance and reaction mechanism of the photodegradation of CHOH by TiO2(001) and g-C3N4QDs/TiO2(001) were thoroughly investigated. The results show that the g-C3N4QDs were composed of an N-defect tri-s-triazine supported by TiO2(001) via a strong C-O-Ti chemical bond, which accelerated the separation of photoinduced carriers through a Z-scheme route. The photodegradation and mineralization efficiencies of CHOH were significantly promoted by 30% and 60% for g-C3N4QDs/TiO2(001) compared with those of TiO2(001). The photodegradation mechanism proceeded as CHOH - dioxymethylene - formate - carbonate - CO2. This study provides a surface engineering means to design highly active modified TiO2 for CHOH photodegradation.

Seasonal variation and source identification of atmospheric speciated mercury in an industrial harbor area in East Asia.

In this study, the pollution characteristics, spatiotemporal variation, and potential sources of atmospheric speciated mercury (ASM) in an industrial harbor area were explored. Gaseous elemental mercury (GEM), gaseous oxidized mercury (GOM), and particle-bound mercury (PBM) were sampled by a self-designed manual system at three harbor sites in four seasons. The yearly average concentrations of GEM, GOM, and PBM were 6.7 ± 2.0 ng/m3, 244 ± 70 pg/m3, and 410 ± 105 pg/m3, respectively. The seasonal average ASM concentration was in the order of: winter > fall > spring > summer. In terms of species, GEM dominated ASM, while reactive mercury (RM = GOM + PBM) accounted for 6.0-15.7%of ASM, implying that ASM was governed by anthropogenic sources in the harbor area. The highest ASM concentrations were observed at Site Zhonghe (ZH), which is mainly influenced by both ship exhausts and industrial emissions, and positively correlated with CO, NOx, and SO2. In particular, GOM was positively correlated with O3, and negatively correlated with air temperature and relative humidity, showing high impact from atmospheric photochemical reactions. Air masses transporting westerly in spring were mainly from ship exhausts. In summer, air masses transporting from the south were from utility power plants and machinery exhausts. In fall and winter, air masses were transported mainly from the north, blowing by the long-range transport of polluted air masses originated from the north. Both principal component analysis and positive matrix factorization results indicate that coal burning, industrial emissions, and vehicular exhausts are the main contributors to ASM. Site Zhongdao (ZD) was close to the bulk carrier loading and unloading zones and was highly influenced by mobile sources, while Site ZH was mainly influenced by the neighboring industrial complex.

Size distributions and dry deposition fluxes of water-soluble inorganic nitrogen in atmospheric aerosols in Xiamen Bay, China.

Size-segregated aerosol particles were collected using a high volume MOUDI sampler at a coastal urban site in Xiamen Bay, China, from March 2018 to June 2020 to examine the seasonal characteristics of aerosol and water-soluble inorganic ions (WSIIs) and the dry deposition of nitrogen species. During the study period, the annual average concentrations of PM1, PM2.5, PM10, and TSP were 14.8 ± 5.6, 21.1 ± 9.0, 35.4 ± 14.2 µg m-3, and 45.2 ± 21.3 µg m-3, respectively. The seasonal variations of aerosol concentrations were impacted by the monsoon with the lowest value in summer and the higher values in other seasons. For WSIIs, the annual average concentrations were 6.3 ± 3.3, 2.1 ± 1.2, 3.3 ± 1.5, and 1.6 ± 0.8 µg m-3 in PM1, PM1-2.5, PM2.5-10, and PM>10, respectively. In addition, pronounced seasonal variations of WSIIs in PM1 and PM1-2.5 were observed, with the highest concentration in spring-winter and the lowest in summer. The size distribution showed that SO4 2-, NH4 + and K+ were consistently present in the submicron particles while Ca2+, Mg2+, Na+ and Cl- mainly accumulated in the size range of 2.5-10 µm, reflecting their different dominant sources. In spring, fall and winter, a bimodal distribution of NO3 - was observed with one peak at 2.5-10 µm and another peak at 0.44-1 µm. In summer, however, the fine mode peak disappeared, likely due to the unfavorable conditions for the formation of NH4NO3. For NH4 + and SO4 2-, their dominant peak at 0.25-0.44 µm in summer and fall shifted to 0.44-1 µm in spring and winter. Although the concentration of NO3-N was lower than NH4-N, the dry deposition flux of NO3-N (35.77 ± 24.49 µmol N m-2 d-1) was much higher than that of NH4-N (10.95 ± 11.89 µmol N m-2 d-1), mainly due to the larger deposition velocities of NO3-N. The contribution of sea-salt particles to the total particulate inorganic N deposition was estimated to be 23.9-52.8%. Dry deposition of particulate inorganic N accounted for 0.95% of other terrestrial N influxes. The annual total N deposition can create a new productivity of 3.55 mgC m-2 d-1, accounting for 1.3-4.7% of the primary productivity in Xiamen Bay. In light of these results, atmospheric N deposition could have a significant influence on biogeochemistry cycle of nutrients with respect to projected increase of anthropogenic emissions from mobile sources in coastal region. SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1007/s10874-021-09427-8.

Transport route-based cluster analysis of chemical fingerprints and source origins of marine fine particles (PM2.5) in South China Sea.

The fingerprints and source origins of marine PM2.5 at two background islands in the South China Sea were clustered via trajectory analysis and positive matrix factorization. High PM2.5 concentrations at the Dongsha Islands occurred for the north routes, while Nansha Islands had similar PM2.5 concentrations amongst the transport routes. However, the chemical characteristics of PM2.5 varied with the transport routes. Secondary inorganic aerosols (NO3-, SO42-, and NH4+) were abundant in water-soluble ions which dominated PM2.5. Crustal metals were the abundant metals in PM2.5, while trace metals were primarily originated from man-made sources. Organic carbon was superior to elemental carbon, and high concentrations of levoglucosan and organic acids were observed for the north routes. Overall, marine PM2.5 at the Dongsha Islands was highly influenced by long-range transport of Asian continental outflows, while particulate air quality at the Nansha Islands was mainly governed by clean air parcels blown from the SCS.

Spatiotemporal distribution characteristics and potential sources of VOCs at an industrial harbor city in southern Taiwan: Three-year VOCs monitoring data analysis.

Kaohsiung City is the largest harbor city in Taiwan. The Linhai Special Industrial Complex (LSIC), which is the largest heavy industrial zone in Taiwan, and other industrial zones and storage station of petrochemicals are adjacent to the Kaohsiung Port. Volatile organic compounds (VOCs), which are discharged from industrial processes in this large industrial area, are likely to cause the poor ambient air quality and atmospheric visibility in Kaohsiung City. This study uses the continuous monitoring data of 54 VOCs during 2018-2020 at eight air quality monitoring stations in the industrialized city to evaluate the spatiotemporal distributions and seasonal variations of VOC concentrations. Principal component analysis and ratios of benzene, toluene, ethylbenzene and xylenes (BTEX) are used to track the potential sources of VOCs for different stations. The highest average concentration of total volatile organic compounds (TVOC) was observed in winter (32.54 ppb), while the lowest TVOC concentration was observed in summer (25.84 ppb), which is related to the prevailing wind directions of monsoons. Kaohsiung is located in the weak monsoon wake area, and air pollutants are easily accumulated in the winter. The southwest wind prevailing in summer results in good diffusion and frequent rainfalls. However, the Qijin station close to the seashore has the highest average TVOC concentration among the eight stations. The seasonal prevailing winds caused the average TVOC concentrations in summer (41.3 ppb) to be higher than that in winter (31.62 ppb) at the Qijin station. It was attributed to the fact that the Qijin Peninsula is vulnerable to VOC emissions from ship sailing in the Taiwan Strait, the processing and export zone, and the shipbuilding yards nearby the Kaohsiung Harbor. Comparing the BTEX ratios of Kaohsiung City with the data of Hong Kong, we found that VOCs were mainly from industrial emissions in Kaohsiung City, which were significantly different from Hong Kong that VOCs were mainly emitted from traffic emissions. Overall, VOCs in Kaohsiung City have been decreased from 2018 to 2020; however, according to the analytical results of ozone formation potential, toluene and m,p-xylenes are the most potential photochemical precursors for ozone formation. The government should enforce and regulate aromatic hydrocarbons from industrial emission sources to reduce the potential formation of ozone.

Improvement of water resistance by Fe2O3/TiO2 photoelectrocatalysts for formaldehyde removal: experimental and theoretical investigation.

TiO2-based photocatalysts are a potential technology for removing indoor formaldehyde (CHOH) owing to their strong photooxidation ability. However, their photooxidation performance is generally weakened when suffering from the competitive adsorption of H2O. In a method inspired by the oxygen evolution reaction (OER) to generate intermediates with hydroxyl radicals on the anode electrode catalysts, an electric field was employed in this research and applied to the photooxidation of CHOH to prevent the competitive adsorption of H2O. Additionally, 0.5-5% Fe2O3 decorated TiO2 was employed to improve the photoelectrocatalytic activity. The influence of an electric field on hydroxyl-radical production was investigated by both density functional theory (DFT) with direct-imposed dipole momentum and photoelectrocatalytic experimental tests. The surface characterization of the photocatalysts, including transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and electron paramagnetic resonance (EPR), was conducted. DFT results show that a positive electric field with a strength of 0.05 Å/V was more favorable to produce hydroxyl on Fe2O3/TiO2(010) than was a negative electric field. Fe2O3 decoration can significantly boost hydroxyl formation, resulting from a decrease in the binding energy between the Fe of Fe2O3 and the oxygen and hydrogen atoms of H2O. The dissociated hydrogen atom of the H2O preferentially remained on the catalysts' surface rather than being released into the gas flow. The experimental results demonstrated that applying 150 V could not directly enhance the photooxidation of CHOH by either TiO2 or Fe2O3/TiO2 but that it could relieve the H2O inhibitory effect by more than 10% on the Fe2O3/TiO2.

Repeated exposure to fine particulate matter constituents lead to liver inflammation and proliferative response in mice.

BACKGROUND: Fine particulate matter (particulate matter with aerodynamic diameter of ≦2.5 µm, PM2.5) exposure cause adverse health effects, including lung inflammation. Through intra-tracheal instillation of PM2.5 components, the study aimed to evaluate the inflammatory and proliferative effects on mice liver. PM2.5 samples were collected near an industrial complex at southern Taiwan. Mice were exposed to water extracts or insoluble particles by intra-tracheal instillation. Male C57BL/6 mice were divided into five groups: control, low dose insoluble particle exposure (LP), high dose insoluble particle exposure (HP), low dose water extract exposure (LW), and high dose water extract exposure (HW). Biochemical analysis, western blotting, histological examination, and immunohistochemistry were employed to evaluate the results. RESULT: Enrichment factor (EF) of metallic elements showed that the EFs of trace elements (Ti, V, Ni, Zn, Pb, Cr, and Cu) in PM2.5 were above 10. Hematoxylin and Eosin (H&E) staining of the liver tissue showed inflammatory infiltration in particle exposure group; hepatocyte ballooning degeneration and karyomegaly were seen in the water extract exposure group. Upregulation of inflammatory signaling, p65 and p50, and caspase-3 (an important effector involved in apoptosis) positive hepatocytes was significantly increased in the HP group, followed by an elevation in protein levels of growth arrest and DNA damage-inducible protein 153 (GADD153). Increased protein expression of proliferating cell nuclear antigen (PCNA) was noted in the LW and HW groups. An increase in phosphorylation of regulators of cell proliferation, Akt and extracellular signal-regulated kinase (ERK) 1/2, were detected in the LW and HW groups. CONCLUSION: The present study shows that the insoluble particle composition of PM2.5 induced inflammatory signaling and cytokines upregulation in the liver, accompanied with inflammatory cell and macrophage infiltration and an abnormal liver function. Exposure of water extract to PM2.5 induced signals of upregulated cellular proliferation, elevated markers of cell proliferation in liver, hepatocyte ballooning degeneration and karyomegaly.

Inter-comparison of chemical characteristics and source apportionment of PM2.5 at two harbors in the Philippines and Taiwan.

This study inter-compared the concentration and chemical characteristics of PM2.5 at two harbors in East Asia, and identified the potential sources of PM2.5 and their contribution. Two sites located at the Kaohsiung (Taiwan) and Manila (the Philippines) Harbors were selected for simultaneous sampling of PM2.5 in four seasons. The sampling of 24-h PM2.5 was conducted for continuous seven days in each season. Water-soluble ions, metallic elements, carbonaceous content, anhydrosugars, and organic acids in PM2.5 were analyzed to characterize their chemical fingerprints. Receptor modeling and trajectory simulation were further applied to resolve the source apportionment of PM2.5. The results indicated that the Kaohsiung Harbor was highly influenced by long-range transport (LRT) of polluted air masses from Northeast Asia, while the Manila Harbor was mainly influenced by local emissions. Secondary inorganic aerosols were the most abundant ions in PM2.5. Crustal elements dominated the metallic content of PM2.5, but trace elements were mainly originated from anthropogenic sources. Higher concentrations of organic carbon (OC) than elemental carbon (EC) was found in PM2.5, with secondary OC (SOC) dominant to the former. Levoglucosan in PM2.5 at the Manila Harbor were superior to those at the Kaohsiung Harbor due to biomass burning surrounding the Manila Harbor. Additionally, high mass ratios of malonic and succinic acids (M/S) in PM2.5 indicated the formation of SOAs. Overall, the ambient air quality of Manila Harbor was more polluted than Kaohsiung Harbor. The Kaohsiung Harbor was more severely affected by LRT of polluted air masses from Northeast Asia, while those toward the Manila Harbor came from the oceans. The major sources resolved by CMB and PMF models at the Kaohsiung Harbor were secondary aerosols, ironworks, incinerators, oceanic spray, and ship emissions, while those at the Manila Harbor were secondary aerosols, soil dust, biomass burning, ship emissions, and oceanic spray.