RESUMO
Reclaiming kinetic energy from vibrating machines holds great promise for sustainable energy harvesting technologies. Nevertheless, the impulsive current induced by vibrations is incompatible with conventional energy storage devices. The energy-management system necessitates novel designs of soft materials for lightweight, miniaturized, and integrated high-frequency electrochemical devices. Here, this work develops a conductive hydrogel with an electro-responsive polymeric network. The electro-responsive breathing transition of the crosslinking points facilitates the expeditious formation of a localized electrolyte layer. This layer features an exceedingly high local charge density, surpassing that of a saturated electrolyte solution by an order of magnitude, and thus enabling rapid charge transport under the influence of an applied voltage. The micro-capacitor based on the gel exhibits record-high capacitance of ≈2 mF cm-2 when the frequency of energy input reaches up to 104 Hz. This work also demonstrates a prototype battery charger that harvests energy from a running car engine. This study presents a feasible strategy for waste energy recycling using integrated electrochemical devices, opening a new avenue for ambient energy management.
RESUMO
Transition metals can deliver high lithium storage capacity, but the reason behind this remains elusive. Herein, the origin of this anomalous phenomenon is uncovered by in situ magnetometry taking metallic Co as a model system. It is revealed that the lithium storage in metallic Co undergoes a two-stage mechanism involving a spin-polarized electron injection to the 3d orbital of Co and subsequent electron transfer to the surrounding solid electrolyte interphase (SEI) at lower potentials. These effects create space charge zones for fast lithium storage on the electrode interface and boundaries with capacitive behavior. Therefore, the transition metal anode can enhance common intercalation or pseudocapacitive electrodes at high capacity while showing superior stability to existing conversion-type or alloying anodes. These findings pave the way for not only understanding the unusual lithium storage behavior of transition metals but also for engineering high-performance anodes with overall enhancement in capacity and long-term durability.