RESUMO
Hydrogen energy has the potential to be a cost-effective and strong technology for brighter development. Hydrogen fuel production by water electrolyzers has attracted attention. 2D nanocomposites with distinctive properties have been extensively explored for various applications from hydrogen evolution reactions to improving the efficiency of water electrolyzer, which is the most eco-friendly, and high-performance for hydrogen production. Recently, typical 2D nanocomposites such as Metal-Free 2D, TMDs, Mxene, LDH, organic composites, and Heterostructure have recently been thoroughly researched for use in the HER. We discuss effective ways for increasing the HER efficiency of 2D catalysts in this paper, And the unique advantages and mechanisms for specific applications are highlighted. Several essential regulating strategies for developing 2D nanocomposite-based HER electrocatalysts are included such as interface engineering, defect engineering, heteroatom doping, strain & phase engineering, and hybridizing which improve HER kinetics, the electrical conductivity, accessibility to catalytic active sites, and reaction energy barrier can be optimized. Finally, the future prospects for 2D nanocomposites in HER are discussed, as well as a thorough overview of a variety of methodologies for designing 2D nanocomposites as HER electrocatalysts with excellent catalytic performance. We expect that this review will provide a thorough overview of 2D nanocatalysts for hydrogen production.
RESUMO
Production and utilization of grey and blue hydrogen is responsible for emission of millions of tons of carbon dioxide (CO2) across the globe. This increased emission of CO2 has severe repercussions on the planet earth and in particular on climate change. Here in, we explored advance bimetallic (BM) CuO/Ag and trimetallic (TM) CuO/Ag/NiO based nanoporous materials supported with silica nanoparticles (SiNPs) via sol-gel route. The explored nanocatalysts were characterized by Powder X-ray diffraction (P-XRD), scanning electron microscopy (SEM), transmittance electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), energy dispersive X-ray spectroscopy (EDX), and Raman spectroscopic techniques. These advance nanocatalysts were evaluated for the green hydrogen production through electrocatalysis and photocatalysis. The catalysts exhibited an exceptional catalytic performance, the onset potential for hydrogen evolution reaction (HER) was determined to be - 0.9 V BMSiNPs-GCE and - 0.7 V (vs Ag/AgCl) for TMSiNPs-GCE, whereas η@10 for BMSiNPs-GCE and TMSiNPs-GCE is - 1.26 and - 1.00 V respectively. Significantly, the TMSiNPs composite and the BMSiNPs composite exhibited superior photochemical H2 evolution rates of 1970.72 mmol h-1 g-1 and 1513.97 mmol h-1 g-1, respectively. The TMSiNPs catalyst presents a highly promising material for HER. This study reveals a cost-effective approach to develop sustainable and resourceful electrocatalysts for HER.
RESUMO
One of the best methods of extracting Vitamin A, as a helper of the immune body system and vision, was measured in supercritical carbon dioxide (SC-CO2); Mole fractions were gained at practical conditions in which the temperature was in the range of 303-323 K and the pressure range was 90-235 bar, respectively. Moreover, four Equation of States [Soave-Redlich-Kwong, Peng-Robinson, Stryjek-Vera and Dashtizadeh-Pazuki-Taghikhani-Ghotbi (DPTG)] were compared with the experimental data. Also, the mixing rules of Van der Waals (vdW1 and vdW2) selected to correlate the solubility data of vitamin A. The outcomes indicate that each of EOSs coupled with vdW2, as a method of estimating the physicochemical and critical properties, were correlated with the solubility data of vitamin A in SC-CO2 with more accuracy, in comparison with vdW1. Among the cubic EOSs, the DPTG model with vdW2 generated the most suitable correlation with the percentage average absolute relative deviation (Average Absolute Relative Deviation%) of 6.
