1.
Talanta
; 51(6): 1163-9, 2000 May 05.
Artigo
em Inglês
| MEDLINE
| ID: mdl-18967947
RESUMO
In this work a stainless steel electrode was prepared, characterised and used as indicator electrode in a potentiometric flow cell. Due to its versatility, it was possible to study different electrode geometries and flow cell arrangements. After optimising the system, mixtures of succinic and oxalic acids were determined by titration. Partial least squares (PLS) regression as multivariate calibration tool was applied for data treatment. The predicted results obtained in a test set showed a relative error of 4.3% for succinic acid and 5.5% for oxalic acid.