Thermal properties of novel phase change materials based on protic ionic liquids containing ethanolamines and stearic acid for efficient thermal energy storage.

In the field of energy harvesting, phase change materials (PCMs) hold great promise. 2-hydroxyethylammonium stearate ([HEA]Ste), bis(2-hydroxyethyl)ammonium stearate ([DHEA]Ste), and tris(2-hydroxyethyl)ammonium stearate ([THEA]Ste) ionic liquids (ILs) demonstrate promising capabilities to enhance thermal energy storage (TES) performance within the 30-100 °C temperature range. This research presents these ILs as PCMs for the first time, emphasizing their environmentally friendly characteristics, safety profile, and cost-effectiveness. The chemical composition and microstructure of these PCMs were investigated using scanning electron microscopy (SEM), and fourier transform infrared spectroscopy (FT-IR), while differential scanning calorimetry (DSC) was employed to assess their latent heat of fusion and specific heat capacity. Furthermore, thermal gravimetric analysis (TGA) was utilized to evaluate the thermal stability of these ILs. In addition, valuable insights into the surface properties and behavior of PCMs at the nanoscale are provided using atomic force microscopy (AFM). Results show that the latent heats of fusion for [HEA]Ste, [DHEA]Ste, and [THEA]Ste are about 171.12, 152.58, and 136.55 kJ kg-1, respectively. Also, thermal stability analysis shows the maximum stability (99.5%) for [HEA]Ste. Ultimately, a custom-built setup featuring a cell containing a PCM derived from synthesized ILs and a commercially available thermoelectric generator (TEG) was employed to measure live voltage (V) in the conversion of heat energy into electrical power. On the other hand, specifically in this measurement we recorded the output voltage (open circuit case) of the TEG device versus time and demonstrated that after turning off the thermal energy source, the proposed system provides the electrical energy for a while (more than 2 hours).

Novel protic ionic liquids-based phase change materials for high performance thermal energy storage systems.

Phase change materials (PCMs) are an important class of innovative materials that considerably contribute to the effective use and conservation of solar energy and wasted heat in thermal energy storage systems (TES). The performance of TES can be improved by using environmentally friendly PCMs called ionic liquids (ILs) based on ethanolamines and fatty acids. The 2-hydroxyethylammonium, bis(2-hydroxyethyl)ammonium, and tris(2-hydroxyethyl)ammonium palmitate ILs, which function is in the temperature range of 30-100 °C and provide a safe and affordable capacity, are introduced in this study for the first time as PCMs. PCMs' chemical composition and microstructure were examined using fourier transformation infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM), respectively. DSC was used to evaluate the ILs' latent heat of fusion and specific heat capacity, while TGA was used to establish their thermal stability. Finally, a home-made device with a PCMs (synthesized ILs) container cell and a commercial thermoelectric generator device to record the real-time voltage (V) was used to convert thermal energy into electrical energy.

Ag/ZnO core-shell NPs boost photosynthesis and growth rate in wheat seedlings under simulated full sun spectrum.

Breeding programs rely on light wavelength, intensity, and photoperiod for rapid success. In this study, we investigated the ability of Ag/ZnO nanoparticles (NPs) to improve the photosynthesis and growth of wheat under simulated full solar spectrum conditions. The world population is increasing rapidly, it is necessary to increase the number of crops in order to ensure the world's food security. Conventional breeding is time-consuming and expensive, so new techniques such as rapid breeding are needed. Rapid breeding shows promise in increasing crop yields by controlling photoperiod and environmental factors in growth regulators. However, achieving optimum growth and photosynthesis rates is still a challenge. Here, we used various methods to evaluate the effects of Ag/ZnO NPs on rice seeds. Using bioinformatics simulations, we evaluated the light-harvesting efficiency of chlorophyll a in the presence of Ag/ZnO NPs. Chemically synthesized Ag/ZnO nanoparticles were applied to rice grains at different concentrations (0-50 mg/L) and subjected to a 12-h preparation time. Evaluation of seed germination rate and growth response in different light conditions using a Light Emitting Diode (LED) growth chamber that simulates a rapid growth system. The analysis showed that the surface plasmon resonance of Ag/ZnO NPs increased 38-fold, resulting in a 160-fold increase in the light absorption capacity of chlorophyll. These estimates are supported by experimental results showing an 18% increase in the yield of rice seeds treated with 15 mg/L Ag/ZnO NPs. More importantly, the treated crops showed a 2.5-fold increase in growth and a 1.4-fold increase in chlorophyll content under the simulated full sun spectrum (4500 lx) and a 16-h light/8-h dark photoperiod. More importantly, these effects are achieved without oxidative or lipid peroxidative damage. Our findings offer a good idea to increase crop growth by improving photosynthesis using Ag/ZnO nanoparticle mixture. To develop this approach, future research should go towards optimizing nanoparticles, investigating the long-term effects, and exploring the applicability of this process in many products. The inclusion of Ag/ZnO NPs in rapid breeding programs has the potential to transform crops by reducing production and increasing agricultural productivity.

High-efficiency upconversion process in cobalt and neodymium doped graphene QDs for biomedical applications.

Multiphoton absorbing upconversion nanoparticles are emerging as bioimaging materials but are limited by the low quantum yield of their visible fluorescence. This article contains colloids of graphene quantum dots (GQDs), Neodymium, and Cobalt doped Graphene Quantum dots (Co-GQDs and Nd-GQDs) surrounded by carboxylic acids are synthesized which especially are suitable for bio applications; in this way, carboxylic acid groups exchanged by Amoxicillin as an antibiotic with bactericidal activity. The XRD diffraction method, TEM microscope, UV-Vis, and photoluminescence spectroscopies characterize the synthesized materials. The synthesized Quantum dots (QDs) exhibit upconversion properties and their emission is centered at 480 nm, but a red shift was observed with the increase of the excitation wavelength. In the emission spectra of synthesized QDs that can be related to the defect levels introduced by passivation of the QDs in the structure, the results show that with the interaction of the surface QDs with more carboxylic groups, the redshift is not observed. As the results indicate an increase in the intensity of upconversion emission is recorded for Co-GQDs and Nd-GQDs. The absolute quantum efficiency (QY) for Co-GQDs and Nd-GQDs were determined to be 41% and 100% more than GQDs respectively. DFT calculations indicate a strong bond between graphene and cobalt and Neodymium atoms. In doped materials, there are trap levels between the band gap of the GQDs which are responsible for increasing the intensity of the upconversion phenomenon.

High-Resolution Color Transparent Display Using Superimposed Quantum Dots.

In this paper, a high-resolution full-color transparent monitor is designed and fabricated using the synthesized quantum dots for the first time. For this purpose, about 100 compounds that had the potential to emit blue, green, and red lights were selected, and simulation was performed using the discrete dipole approximation (DDA) method, in which the shell layer was selected to be SiO2 or TiO2 in the first step. Among the simulated compounds with SiO2 or TiO2 shells, Se/SiO2 and BTiO3/SiO2 were selected as blue light emitters with high intensity and narrow bandwidth. Accordingly, CdSe/SiO2 nanoparticles were selected as green light emitters and Au/TiO2 for the red light. As the surface of the nanoparticles in their optical properties is important, reactivation of the nanoparticles' surface is required to reach the high-intensity peak and resolution. To this end, in the second step, the surface of Se and CdSe nanoparticles reacted with ethanolamine, which can make a strong bond with cadmium atoms. The band structure and optical properties were obtained by the density functional theory (DFT) method. The Se/Ethanolamine and CdSe/Ethanolamine were experimentally synthesized to evaluate the theoretical results, and their optical properties were measured. To fabricate a transparent monitor, Se/Ethanolamine, CdSe/SiO2, and Au/TiO2 nanoparticles were dispersed in polyvinyl alcohol (PVA) solved in water and deposited on the glass by the doctor blading technique. Finally, high-resolution videos and images were displayed on the fabricated monitor.

High-speed and high-precision PbSe/PbI2 solution process mid-infrared camera.

Infrared (IR) cameras based on semiconductors grown by epitaxial methods face two main challenges, which are cost and operating at room temperature. The alternative new technologies which can tackle these two difficulties develop new and facile material and methods. Moreover, the implementation of high speed camera, which makes high resolution images with normal methods, is very expensive. In this paper, a new nanostructure based on a cost-effective solution processed technology for the implementation of the high-speed mid-infrared light camera at room temperature is proposed. To this end, the chemically synthesized PbSe-PbI2 core-shell Quantum Dots (QDs) are used. In this work, a camera including 10 × 10 pixels is fabricated and synthesized QDs spin-coated on interdigitated contact (IDC) and then the fabricated system passivated by epoxy resin. Finally, using an electronic reading circuit, all pixels are converted to an image on the monitor. To model the fabricated camera, we solved Schrodinger-Poisson equations self consistently. Then output current from each pixel is modeled based on semiconductor physics and dark and photocurrent, as well as Responsivity and Detectivity, are calculated. Then the fabricated device is examined, and dark and photocurrents are measured and compared to the theoretical results. The obtained results indicate that the obtained theoretical and measured experimental results are in good agreement together. The fabricated detector is high speed with a rise time of 100 ns. With this speed, we can get 10 million frames per second; this means we can get very high-resolution images. The speed of operation is examined experimentally using a chopper that modulates input light with 50, 100, 250, and 500 Hz. It is shown that the fabricated device operates well in these situations, and it is not limited by the speed of detector. Finally, for the demonstration of the proposed device operation, some pictures and movies taken by the camera are attached and inserted in the paper.